Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity

Microstructurally flexible high entropy alloys (HEAs) can be tailored for strength via dual-phase strengthening mechanisms, which originate from the strain-induced phase transformation microstructural phenomena. One such alloy is a recently synthesized Fe42Mn28Co10Cr15Si5 (at%) HEA consisting of met...

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Main Authors: Zhangxi Feng, Brandon A. McWilliams, Rajiv S. Mishra, Marko Knezevic
Format: Article
Language:English
Published: Elsevier 2024-11-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424022634
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author Zhangxi Feng
Brandon A. McWilliams
Rajiv S. Mishra
Marko Knezevic
author_facet Zhangxi Feng
Brandon A. McWilliams
Rajiv S. Mishra
Marko Knezevic
author_sort Zhangxi Feng
collection DOAJ
description Microstructurally flexible high entropy alloys (HEAs) can be tailored for strength via dual-phase strengthening mechanisms, which originate from the strain-induced phase transformation microstructural phenomena. One such alloy is a recently synthesized Fe42Mn28Co10Cr15Si5 (at%) HEA consisting of metastable gamma austenite (γ), stable epsilon martensite (ε), and stable sigma (σ) phases. In this work, a crystal plasticity homogenization incorporating a physically based phase transformation and hardening models is used to interpret and better understand the effects of strain induced phase transformation phenomena on the overall hardening response of the alloy. The transformation model is conceived based on the grain-scale stress sensitive motion of partial dislocations forming shear bands, while the hardening model is an extended Kocks-Mecking-type dislocation density-based formulation sensitive to grain size and shape. The deformation of constituent grains per phase in the alloy is modeled as a combination of anisotropic elasticity, crystallographic glide, and γ→ε phase transformation. Parameters of the hardening and transformation models within the homogenization are calibrated and validated on a suite of data including flow stress curves and phase fractions measured under compression, while the corresponding texture evolution data is used solely for verification. Good predictions of the model elucidate that the transformation induced dynamic Hall-Petch-type barrier effect is the primary origin of strain hardening along with the increase in the ε-phase fraction and dislocation density, while the individual strength of the phases gives rise to the overall strength. The modeling framework described in the present work is expected to be applicable to other HEA systems.
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spelling doaj-art-261b5aeb52934da482bb73b9cb04cd742025-08-20T02:39:15ZengElsevierJournal of Materials Research and Technology2238-78542024-11-01332841285510.1016/j.jmrt.2024.09.258Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticityZhangxi Feng0Brandon A. McWilliams1Rajiv S. Mishra2Marko Knezevic3Department of Mechanical Engineering, University of New Hampshire, Durham, NH, 03824, USAArmy Research Directorate, DEVCOM Army Research Laboratory, Aberdeen Proving Ground, MD, 21005, USADepartment of Materials Science and Engineering, University of North Texas, Denton, TX, 76207, USADepartment of Mechanical Engineering, University of New Hampshire, Durham, NH, 03824, USA; Corresponding author.Microstructurally flexible high entropy alloys (HEAs) can be tailored for strength via dual-phase strengthening mechanisms, which originate from the strain-induced phase transformation microstructural phenomena. One such alloy is a recently synthesized Fe42Mn28Co10Cr15Si5 (at%) HEA consisting of metastable gamma austenite (γ), stable epsilon martensite (ε), and stable sigma (σ) phases. In this work, a crystal plasticity homogenization incorporating a physically based phase transformation and hardening models is used to interpret and better understand the effects of strain induced phase transformation phenomena on the overall hardening response of the alloy. The transformation model is conceived based on the grain-scale stress sensitive motion of partial dislocations forming shear bands, while the hardening model is an extended Kocks-Mecking-type dislocation density-based formulation sensitive to grain size and shape. The deformation of constituent grains per phase in the alloy is modeled as a combination of anisotropic elasticity, crystallographic glide, and γ→ε phase transformation. Parameters of the hardening and transformation models within the homogenization are calibrated and validated on a suite of data including flow stress curves and phase fractions measured under compression, while the corresponding texture evolution data is used solely for verification. Good predictions of the model elucidate that the transformation induced dynamic Hall-Petch-type barrier effect is the primary origin of strain hardening along with the increase in the ε-phase fraction and dislocation density, while the individual strength of the phases gives rise to the overall strength. The modeling framework described in the present work is expected to be applicable to other HEA systems.http://www.sciencedirect.com/science/article/pii/S2238785424022634High entropy alloysPhase transformationsCrystal plasticityTextureHardening
spellingShingle Zhangxi Feng
Brandon A. McWilliams
Rajiv S. Mishra
Marko Knezevic
Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity
Journal of Materials Research and Technology
High entropy alloys
Phase transformations
Crystal plasticity
Texture
Hardening
title Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity
title_full Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity
title_fullStr Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity
title_full_unstemmed Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity
title_short Modeling the effects of initial grain size, martensitic transformation induced dynamic grain refinement, phases, and texture on strength of a high entropy alloy using crystal plasticity
title_sort modeling the effects of initial grain size martensitic transformation induced dynamic grain refinement phases and texture on strength of a high entropy alloy using crystal plasticity
topic High entropy alloys
Phase transformations
Crystal plasticity
Texture
Hardening
url http://www.sciencedirect.com/science/article/pii/S2238785424022634
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