In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment
The current research seeks to introduce a new catalytic system called poly(N-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid sodium)- [Zn2(BDC)1.5(L)(DMF)], which refers to a thermo-responsive amphiphilic Zinc-MOF-paired ionic co-polymeric hydrogel, composed of poly(N-isopropylacry...
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| Format: | Article |
| Language: | English |
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Iranian Chemical Society
2024-06-01
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| Series: | Nanochemistry Research |
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| Online Access: | http://www.nanochemres.org/article_195697_a73b5cd34f3903526b2247bf51974925.pdf |
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| author | Faezeh Mousavi-Torkamani Massomeh Ghorbanloo Mitra Saffari Nastaran Maddahzadeh |
| author_facet | Faezeh Mousavi-Torkamani Massomeh Ghorbanloo Mitra Saffari Nastaran Maddahzadeh |
| author_sort | Faezeh Mousavi-Torkamani |
| collection | DOAJ |
| description | The current research seeks to introduce a new catalytic system called poly(N-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid sodium)- [Zn2(BDC)1.5(L)(DMF)], which refers to a thermo-responsive amphiphilic Zinc-MOF-paired ionic co-polymeric hydrogel, composed of poly(N-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid sodium) hydrogel and [Zn2(BDC)1.5(L)(DMF)] as a metal-organic framework. The catalytic system was constructed using free-radical polymerization at ambient temperature. Dynamic light scattering was then used to assess the temperature-responsiveness of the adsorbent and determine the hydrodynamic radii of the constructed compounds. LCST of the composite was around 56-58 ͌C. To determine the amounts of Zn metals in the prepared compound, atomic absorption spectroscopy (AAS) was used. The prepared composites were used to adsorb Methylene Blue from aqueous solutions. The results showed that p(NIPAM-co-NaAMPS)‐([Zn2(BDC)1.5(L)(DMF)]) composite had the potential to effectively adsorb the methylene blue in the solid-liquid biphasic reaction system. After the catalytic activity was completed, the adsorbent could be easily separated from the reaction media by manipulating temperature. It could also be reused without any loss in activity. |
| format | Article |
| id | doaj-art-2614f569d0ab4a96952dda89ef46de2a |
| institution | Kabale University |
| issn | 2538-4279 2423-818X |
| language | English |
| publishDate | 2024-06-01 |
| publisher | Iranian Chemical Society |
| record_format | Article |
| series | Nanochemistry Research |
| spelling | doaj-art-2614f569d0ab4a96952dda89ef46de2a2025-01-12T10:25:14ZengIranian Chemical SocietyNanochemistry Research2538-42792423-818X2024-06-019318319610.22036/ncr.2024.03.002195697In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water TreatmentFaezeh Mousavi-Torkamani0Massomeh Ghorbanloo1Mitra Saffari2Nastaran Maddahzadeh3Department of Chemistry, Faculty of Science, University of Zanjan, Iran.Department of Chemistry, Faculty of Science, University of Zanjan, Iran.Department of Chemistry, Faculty of Science, University of Zanjan, Iran.Department of Chemistry, Faculty of Science, University of Zanjan, Iran.The current research seeks to introduce a new catalytic system called poly(N-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid sodium)- [Zn2(BDC)1.5(L)(DMF)], which refers to a thermo-responsive amphiphilic Zinc-MOF-paired ionic co-polymeric hydrogel, composed of poly(N-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid sodium) hydrogel and [Zn2(BDC)1.5(L)(DMF)] as a metal-organic framework. The catalytic system was constructed using free-radical polymerization at ambient temperature. Dynamic light scattering was then used to assess the temperature-responsiveness of the adsorbent and determine the hydrodynamic radii of the constructed compounds. LCST of the composite was around 56-58 ͌C. To determine the amounts of Zn metals in the prepared compound, atomic absorption spectroscopy (AAS) was used. The prepared composites were used to adsorb Methylene Blue from aqueous solutions. The results showed that p(NIPAM-co-NaAMPS)‐([Zn2(BDC)1.5(L)(DMF)]) composite had the potential to effectively adsorb the methylene blue in the solid-liquid biphasic reaction system. After the catalytic activity was completed, the adsorbent could be easily separated from the reaction media by manipulating temperature. It could also be reused without any loss in activity.http://www.nanochemres.org/article_195697_a73b5cd34f3903526b2247bf51974925.pdfthermoresponse hydrogelsmetal-organic frameworkmb adsorption |
| spellingShingle | Faezeh Mousavi-Torkamani Massomeh Ghorbanloo Mitra Saffari Nastaran Maddahzadeh In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment Nanochemistry Research thermoresponse hydrogels metal-organic framework mb adsorption |
| title | In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment |
| title_full | In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment |
| title_fullStr | In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment |
| title_full_unstemmed | In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment |
| title_short | In Situ Synthesis of MOF/Thermoresponsive Hydrogel Composite-Based Adsorbents for Water Treatment |
| title_sort | in situ synthesis of mof thermoresponsive hydrogel composite based adsorbents for water treatment |
| topic | thermoresponse hydrogels metal-organic framework mb adsorption |
| url | http://www.nanochemres.org/article_195697_a73b5cd34f3903526b2247bf51974925.pdf |
| work_keys_str_mv | AT faezehmousavitorkamani insitusynthesisofmofthermoresponsivehydrogelcompositebasedadsorbentsforwatertreatment AT massomehghorbanloo insitusynthesisofmofthermoresponsivehydrogelcompositebasedadsorbentsforwatertreatment AT mitrasaffari insitusynthesisofmofthermoresponsivehydrogelcompositebasedadsorbentsforwatertreatment AT nastaranmaddahzadeh insitusynthesisofmofthermoresponsivehydrogelcompositebasedadsorbentsforwatertreatment |