Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions
The concept of green chemistry is fast gaining traction nowadays and in line with the United Nations Sustainable Development Goals. In this manuscript, a simple yet efficient procedure in the synthesis of symmetrical 1,3-diynes using various alkynes catalyzed by copper under base-free and solvent-le...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2020-03-01
|
| Series: | Kuwait Journal of Science |
| Subjects: | |
| Online Access: | https://journalskuwait.org/kjs/index.php/KJS/article/view/7449 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849471139973169152 |
|---|---|
| author | Poh Wai Wai Chia Nur Aimi Aqilah Ahmad Ruslan Fu Siong Julius Yong Su-Yin Kan |
| author_facet | Poh Wai Wai Chia Nur Aimi Aqilah Ahmad Ruslan Fu Siong Julius Yong Su-Yin Kan |
| author_sort | Poh Wai Wai Chia |
| collection | DOAJ |
| description | The concept of green chemistry is fast gaining traction nowadays and in line with the United Nations Sustainable Development Goals. In this manuscript, a simple yet efficient procedure in the synthesis of symmetrical 1,3-diynes using various alkynes catalyzed by copper under base-free and solvent-less condition is presented. With the improved protocol, the formation of homocoupled 1,3-diynes from different alkynes were afforded in good yields. The improved synthetic protocol is in compliance with the principles of green chemistry, which include recyclable catalytic system, avoid the use of base and mild homocoupling reaction condition. The improved protocol can be applied for the synthesis of many desirable compounds that is of interest to the academia and industries.
|
| format | Article |
| id | doaj-art-25d2b6407cc54261b7462d41a94460ab |
| institution | Kabale University |
| issn | 2307-4108 2307-4116 |
| language | English |
| publishDate | 2020-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Kuwait Journal of Science |
| spelling | doaj-art-25d2b6407cc54261b7462d41a94460ab2025-08-20T03:24:56ZengElsevierKuwait Journal of Science2307-41082307-41162020-03-01472Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditionsPoh Wai Wai Chia0Nur Aimi Aqilah Ahmad Ruslan1Fu Siong Julius Yong2Su-Yin Kan3Faculty of Science and Marine Environment, University Malaysia Terengganu, Terengganu, Malaysia.Faculty of Science and Marine Environment, University Malaysia Terengganu, Terengganu, Malaysia.Institute of Marine Biotechnology, University Malaysia Terengganu, Terengganu, Malaysia.Dept. of Health Sciences, University Sultan Zainal Abidin, 21300 Kuala Nerus, Malaysia.The concept of green chemistry is fast gaining traction nowadays and in line with the United Nations Sustainable Development Goals. In this manuscript, a simple yet efficient procedure in the synthesis of symmetrical 1,3-diynes using various alkynes catalyzed by copper under base-free and solvent-less condition is presented. With the improved protocol, the formation of homocoupled 1,3-diynes from different alkynes were afforded in good yields. The improved synthetic protocol is in compliance with the principles of green chemistry, which include recyclable catalytic system, avoid the use of base and mild homocoupling reaction condition. The improved protocol can be applied for the synthesis of many desirable compounds that is of interest to the academia and industries. https://journalskuwait.org/kjs/index.php/KJS/article/view/7449Alkynes13-DiynesGreen chemistry10-PhenantrolineRecyclable catalytic system. |
| spellingShingle | Poh Wai Wai Chia Nur Aimi Aqilah Ahmad Ruslan Fu Siong Julius Yong Su-Yin Kan Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions Kuwait Journal of Science Alkynes 1 3-Diynes Green chemistry 10-Phenantroline Recyclable catalytic system. |
| title | Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions |
| title_full | Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions |
| title_fullStr | Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions |
| title_full_unstemmed | Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions |
| title_short | Homocoupling of terminal alkynes catalyzed by copper complexes of 1,10-phenanthroline under base- and solvent-free conditions |
| title_sort | homocoupling of terminal alkynes catalyzed by copper complexes of 1 10 phenanthroline under base and solvent free conditions |
| topic | Alkynes 1 3-Diynes Green chemistry 10-Phenantroline Recyclable catalytic system. |
| url | https://journalskuwait.org/kjs/index.php/KJS/article/view/7449 |
| work_keys_str_mv | AT pohwaiwaichia homocouplingofterminalalkynescatalyzedbycoppercomplexesof110phenanthrolineunderbaseandsolventfreeconditions AT nuraimiaqilahahmadruslan homocouplingofterminalalkynescatalyzedbycoppercomplexesof110phenanthrolineunderbaseandsolventfreeconditions AT fusiongjuliusyong homocouplingofterminalalkynescatalyzedbycoppercomplexesof110phenanthrolineunderbaseandsolventfreeconditions AT suyinkan homocouplingofterminalalkynescatalyzedbycoppercomplexesof110phenanthrolineunderbaseandsolventfreeconditions |