Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides
A heterostructure of diamagnetic magnesium‒aluminium layered double hydroxides (Mg‒Al LDHs) and photomag‐ netic cobalt‒iron Prussian Blue analogue (Co‒Fe PBA) was designed, synthesized and then designated as LDH‒PB. The cyanide-bridged Co‒Fe PBA was two-dimensionally intercalated into the Mg‒Al LDH...
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| Language: | English |
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Wiley
2016-04-01
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| Series: | Nanomaterials and Nanotechnology |
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| Online Access: | http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/co-ndash-fe-prussian-blue-analogue-intercalated-into-diamagnetic-mg-ndash-al-layered-double-hydroxid |
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| author | Cuijuan Zhang Takashi Yamamoto Yasuaki Einaga |
| author_facet | Cuijuan Zhang Takashi Yamamoto Yasuaki Einaga |
| author_sort | Cuijuan Zhang |
| collection | DOAJ |
| description | A heterostructure of diamagnetic magnesium‒aluminium layered double hydroxides (Mg‒Al LDHs) and photomag‐ netic cobalt‒iron Prussian Blue analogue (Co‒Fe PBA) was designed, synthesized and then designated as LDH‒PB. The cyanide-bridged Co‒Fe PBA was two-dimensionally intercalated into the Mg‒Al LDH template by the stepwise anion exchange method. LDH‒PB showed ferrimagnetic properties with in-plane antiferromagnetic exchange interactions, as well as small photo-induced magnetization by visible light illumination due to the low dimensional structures and the characteristic photo-induced electronic states of the mixed valence of FeIII(low spin, S = 1/2)‒CN‒ CoII(high spin, S = 3/2)‒NC‒FeII (low spin, S = 0). |
| format | Article |
| id | doaj-art-2575cb0219d74af38324d8a7607c2f88 |
| institution | Kabale University |
| issn | 1847-9804 |
| language | English |
| publishDate | 2016-04-01 |
| publisher | Wiley |
| record_format | Article |
| series | Nanomaterials and Nanotechnology |
| spelling | doaj-art-2575cb0219d74af38324d8a7607c2f882025-08-20T03:54:52ZengWileyNanomaterials and Nanotechnology1847-98042016-04-01626http://dx.doi.org/10.5772/6327650331Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double HydroxidesCuijuan ZhangTakashi YamamotoYasuaki EinagaA heterostructure of diamagnetic magnesium‒aluminium layered double hydroxides (Mg‒Al LDHs) and photomag‐ netic cobalt‒iron Prussian Blue analogue (Co‒Fe PBA) was designed, synthesized and then designated as LDH‒PB. The cyanide-bridged Co‒Fe PBA was two-dimensionally intercalated into the Mg‒Al LDH template by the stepwise anion exchange method. LDH‒PB showed ferrimagnetic properties with in-plane antiferromagnetic exchange interactions, as well as small photo-induced magnetization by visible light illumination due to the low dimensional structures and the characteristic photo-induced electronic states of the mixed valence of FeIII(low spin, S = 1/2)‒CN‒ CoII(high spin, S = 3/2)‒NC‒FeII (low spin, S = 0).http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/co-ndash-fe-prussian-blue-analogue-intercalated-into-diamagnetic-mg-ndash-al-layered-double-hydroxidLayered Double Hydroxides (LDHs)Prussian Blue Analogue (PBA)PhotomagneticMolecule-based MagnetIntercalation |
| spellingShingle | Cuijuan Zhang Takashi Yamamoto Yasuaki Einaga Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides Nanomaterials and Nanotechnology Layered Double Hydroxides (LDHs) Prussian Blue Analogue (PBA) Photomagnetic Molecule-based Magnet Intercalation |
| title | Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides |
| title_full | Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides |
| title_fullStr | Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides |
| title_full_unstemmed | Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides |
| title_short | Co–Fe Prussian Blue Analogue Intercalated into Diamagnetic Mg–Al Layered Double Hydroxides |
| title_sort | co fe prussian blue analogue intercalated into diamagnetic mg al layered double hydroxides |
| topic | Layered Double Hydroxides (LDHs) Prussian Blue Analogue (PBA) Photomagnetic Molecule-based Magnet Intercalation |
| url | http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/co-ndash-fe-prussian-blue-analogue-intercalated-into-diamagnetic-mg-ndash-al-layered-double-hydroxid |
| work_keys_str_mv | AT cuijuanzhang cofeprussianblueanalogueintercalatedintodiamagneticmgallayereddoublehydroxides AT takashiyamamoto cofeprussianblueanalogueintercalatedintodiamagneticmgallayereddoublehydroxides AT yasuakieinaga cofeprussianblueanalogueintercalatedintodiamagneticmgallayereddoublehydroxides |