Highly Isotactic Poly(N-butenyl-carbazole): Synthesis, Characterization, and Optical Properties
The synthesis of isotactic poly(N-butenyl-carbazole) (i-PBK) by using homogeneous isospecific Ziegler-Natta catalytic system is reported. The achieved polymer is crystalline and shows, to DSC and X-ray analysis, two distinct crystalline phases. i-PBK FTIR spectrum and X-ray diffraction pattern are c...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2016-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2016/1656459 |
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| Summary: | The synthesis of isotactic poly(N-butenyl-carbazole) (i-PBK) by using homogeneous isospecific Ziegler-Natta catalytic system is reported. The achieved polymer is crystalline and shows, to DSC and X-ray analysis, two distinct crystalline phases. i-PBK FTIR spectrum and X-ray diffraction pattern are compared with those of poly(N-vinylcarbazole) (PVK). The observed differences are tentatively associated with higher flexibility of the i-PBK chains due to the alkylene group connecting the carbazole group to the main chain. i-PBK optical properties are also compared with those of PVK and isotactic poly(N-pentenyl-carbazole) (i-PPK), a higher homologue of i-PBK recently used as emitting layer in organic light emitting diodes (OLEDs) showing white light emission. The close similarity of the fluorescence spectra of i-PBK and i-PPK is a promising basis for optical applications of this polymer. |
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| ISSN: | 2090-9063 2090-9071 |