Sb distribution in the phases of SiO2 saturated Sb-Fe-O-SiO2-CaO system in air
Sb distribution in the phases of SiO2 saturated Sb-Fe-O-SiO2-CaO system was determined for the first time through hightemperature experiment and quenching techniques, followed by Electron probe X-ray microanalysis (EPMA) in air (Ptot = 1 atm, PO2 = 0.21 atm). The phases were quantified in the temper...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
University of Belgrade, Technical Faculty, Bor
2021-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2021/1450-53392000030Z.pdf |
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| Summary: | Sb distribution in the phases of SiO2 saturated Sb-Fe-O-SiO2-CaO system was determined for the first time through hightemperature experiment and quenching techniques, followed by Electron probe X-ray microanalysis (EPMA) in air (Ptot = 1 atm, PO2 = 0.21 atm). The phases were quantified in the temperature range of 900°C-1200°C and the effects of Fe/SiO2 (mass fraction) and CaO/SiO2 (mass fraction) on Sb2O3 content in the Sb-Fe-O-SiO2-CaO system were investigated at 1200°C. The results indicated that the Sb-containing phase primarily existed in the solid solution phase at 1200°C. With the increase of temperature from 1100°C to 1200°C, the Sb2O3 content in the solid solution phase increased drastically from 7.52 wt% to 17.36 wt%. Lowering the values of CaO/SiO2 and Fe/SiO2 in the smelting process effectively reduced Sb2O3 content in the slag. The verification of the experiment results suggested that the antimony content in slag was 0.57 wt%, the crude antimony yield rate was lower than 4%, and the crude antimony grade was beyond 94 wt%, which meant that the reduction of antimony content in the slag could be achieved. |
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| ISSN: | 1450-5339 2217-7175 |