Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides
The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relat...
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| Format: | Article |
| Language: | English |
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Wiley
2017-01-01
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| Series: | Advances in Materials Science and Engineering |
| Online Access: | http://dx.doi.org/10.1155/2017/5370289 |
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| author | Dunya Mahammad Babanly Qorkhmaz Mansur Huseynov Ziya Saxaveddin Aliev Dilgam Babir Tagiyev Mahammad Baba Babanly |
| author_facet | Dunya Mahammad Babanly Qorkhmaz Mansur Huseynov Ziya Saxaveddin Aliev Dilgam Babir Tagiyev Mahammad Baba Babanly |
| author_sort | Dunya Mahammad Babanly |
| collection | DOAJ |
| description | The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed. |
| format | Article |
| id | doaj-art-242bd19ab00746049ec81b362a6cffa7 |
| institution | Kabale University |
| issn | 1687-8434 1687-8442 |
| language | English |
| publishDate | 2017-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advances in Materials Science and Engineering |
| spelling | doaj-art-242bd19ab00746049ec81b362a6cffa72025-02-03T01:22:55ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422017-01-01201710.1155/2017/53702895370289Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium ChalcohalidesDunya Mahammad Babanly0Qorkhmaz Mansur Huseynov1Ziya Saxaveddin Aliev2Dilgam Babir Tagiyev3Mahammad Baba Babanly4Institute of Catalysis and Inorganic Chemistry, ANAS, 1143 Baku, AzerbaijanANAS, Nakhchivan Branch, 7000 Nakhchivan, AzerbaijanAzerbaijani State Oil and Industrial University, Azadlıg Av. 16/21, 1010 Baku, AzerbaijanInstitute of Catalysis and Inorganic Chemistry, ANAS, 1143 Baku, AzerbaijanInstitute of Catalysis and Inorganic Chemistry, ANAS, 1143 Baku, AzerbaijanThe solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed.http://dx.doi.org/10.1155/2017/5370289 |
| spellingShingle | Dunya Mahammad Babanly Qorkhmaz Mansur Huseynov Ziya Saxaveddin Aliev Dilgam Babir Tagiyev Mahammad Baba Babanly Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides Advances in Materials Science and Engineering |
| title | Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides |
| title_full | Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides |
| title_fullStr | Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides |
| title_full_unstemmed | Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides |
| title_short | Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides |
| title_sort | thermodynamic study of tl6sbr4 compound and some regularities in thermodynamic properties of thallium chalcohalides |
| url | http://dx.doi.org/10.1155/2017/5370289 |
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