New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality

The hydrogen fuel quality is critical to the efficiency and longevity of fuel cell electric vehicles (FCEVs), with ISO 14687:2019 grade D establishing stringent impurity limits. This study compared two different sampling techniques for assessing the hydrogen fuel quality, focusing on the National Ph...

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Main Authors: Linga Reddy Enakonda, Thomas Bacquart, Shirin Khaki, Fangyu Zhang, Hannah Kerr, Benjamin Longhurst, Abigail S. O. Morris
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Hydrogen
Subjects:
Online Access:https://www.mdpi.com/2673-4141/6/2/35
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author Linga Reddy Enakonda
Thomas Bacquart
Shirin Khaki
Fangyu Zhang
Hannah Kerr
Benjamin Longhurst
Abigail S. O. Morris
author_facet Linga Reddy Enakonda
Thomas Bacquart
Shirin Khaki
Fangyu Zhang
Hannah Kerr
Benjamin Longhurst
Abigail S. O. Morris
author_sort Linga Reddy Enakonda
collection DOAJ
description The hydrogen fuel quality is critical to the efficiency and longevity of fuel cell electric vehicles (FCEVs), with ISO 14687:2019 grade D establishing stringent impurity limits. This study compared two different sampling techniques for assessing the hydrogen fuel quality, focusing on the National Physical Laboratory hydrogen direct sampling apparatus (NPL DirSAM) from a 35 MPa heavy-duty (HD) dispenser and qualitizer sampling from a 70 MPa light-duty (LD) nozzle, both of which were deployed on the same day at a local hydrogen refuelling station (HRS). The collected samples were analysed as per the ISO 14687:2019 contaminants using the NPL H<sub>2</sub>-quality laboratory. The NPL DirSAM was able to sample an HD HRS, demonstrating the ability to realise such sampling on an HD nozzle. The comparison of the LD (H<sub>2</sub> Qualitizer sampling) and HD (NPL DirSAM) devices showed good agreement but significant variation, especially for sulphur compounds, non-methane hydrocarbons and carbon dioxide. These variations may be related to the HRS difference between the LD and HD devices (e.g., flow path, refuelling conditions and precooling for light duty versus no precooling for heavy duty). Further study of HD and LD H<sub>2</sub> fuel at HRSs is needed for a better understanding.
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spelling doaj-art-23f8a1e1cefa43c58d7234effe2ef3152025-08-20T02:21:02ZengMDPI AGHydrogen2673-41412025-05-01623510.3390/hydrogen6020035New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel QualityLinga Reddy Enakonda0Thomas Bacquart1Shirin Khaki2Fangyu Zhang3Hannah Kerr4Benjamin Longhurst5Abigail S. O. Morris6Atmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKAtmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKAtmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKAtmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKAtmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKAtmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKAtmospheric Environmental Science Department, National Physical Laboratory, Hampton Road, Teddington TW11 0LW, Middlesex, UKThe hydrogen fuel quality is critical to the efficiency and longevity of fuel cell electric vehicles (FCEVs), with ISO 14687:2019 grade D establishing stringent impurity limits. This study compared two different sampling techniques for assessing the hydrogen fuel quality, focusing on the National Physical Laboratory hydrogen direct sampling apparatus (NPL DirSAM) from a 35 MPa heavy-duty (HD) dispenser and qualitizer sampling from a 70 MPa light-duty (LD) nozzle, both of which were deployed on the same day at a local hydrogen refuelling station (HRS). The collected samples were analysed as per the ISO 14687:2019 contaminants using the NPL H<sub>2</sub>-quality laboratory. The NPL DirSAM was able to sample an HD HRS, demonstrating the ability to realise such sampling on an HD nozzle. The comparison of the LD (H<sub>2</sub> Qualitizer sampling) and HD (NPL DirSAM) devices showed good agreement but significant variation, especially for sulphur compounds, non-methane hydrocarbons and carbon dioxide. These variations may be related to the HRS difference between the LD and HD devices (e.g., flow path, refuelling conditions and precooling for light duty versus no precooling for heavy duty). Further study of HD and LD H<sub>2</sub> fuel at HRSs is needed for a better understanding.https://www.mdpi.com/2673-4141/6/2/35HRS samplingNPL DirSAMqualitizerISO-14687:2019hydrogen purity
spellingShingle Linga Reddy Enakonda
Thomas Bacquart
Shirin Khaki
Fangyu Zhang
Hannah Kerr
Benjamin Longhurst
Abigail S. O. Morris
New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality
Hydrogen
HRS sampling
NPL DirSAM
qualitizer
ISO-14687:2019
hydrogen purity
title New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality
title_full New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality
title_fullStr New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality
title_full_unstemmed New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality
title_short New Heavy-Duty Sampling System for Hydrogen Refuelling Stations—Comparison of Impact of Light-Duty Versus Heavy-Duty Sampling Techniques on Hydrogen Fuel Quality
title_sort new heavy duty sampling system for hydrogen refuelling stations comparison of impact of light duty versus heavy duty sampling techniques on hydrogen fuel quality
topic HRS sampling
NPL DirSAM
qualitizer
ISO-14687:2019
hydrogen purity
url https://www.mdpi.com/2673-4141/6/2/35
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