Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire

The new eco-friendly flammable refrigerant in air conditioners has resulted in an annual increase in fire incidents associated with these units. Fire investigators face significant challenges in identifying the causes of these fires. In this study, copper tube samples were extracted from various loc...

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Main Authors: Yunlong Ou, Ming Fu, Jing Zhang, Wenzhong Mi, Changzheng Li, Shouhai Chen, Shoulei Zheng
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Fire
Subjects:
Online Access:https://www.mdpi.com/2571-6255/8/4/145
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author Yunlong Ou
Ming Fu
Jing Zhang
Wenzhong Mi
Changzheng Li
Shouhai Chen
Shoulei Zheng
author_facet Yunlong Ou
Ming Fu
Jing Zhang
Wenzhong Mi
Changzheng Li
Shouhai Chen
Shoulei Zheng
author_sort Yunlong Ou
collection DOAJ
description The new eco-friendly flammable refrigerant in air conditioners has resulted in an annual increase in fire incidents associated with these units. Fire investigators face significant challenges in identifying the causes of these fires. In this study, copper tube samples were extracted from various locations of air conditioner condenser debris post fire. The morphology characteristics of the ruptured copper tubes formed by a high-temperature flame in fire and that formed by corrosion were analyzed, respectively. The findings indicate that the ruptures in the copper tubes of air conditioners may be classified into two types based on their origins: ruptures resulting from fire and ruptures resulting from corrosion. The ruptures in the copper tubes resulting from fire are associated with the presence of aluminum alloy fins. At elevated temperatures, the copper and aluminum atoms persist in diffusing and fracturing. A significant quantity of silver-white aluminum is present surrounding the ruptures, and distinct elemental layers may be seen in the cross-section. The corrosion-induced ruptures in the copper tubes are associated with ant nest corrosion. Despite the influence of high-temperature flame melting on surface corrosion pits, they will not entirely obscure the pits and the cross-section continues to exhibit the bifurcated structure characteristic of ant nest corrosion. This investigation demonstrates that corrosion of ant nests is the root cause of copper tube breakage obscured by flames. An investigation method for the refrigerant leakage air conditioning fire is proposed. The above findings can provide proof and method for air conditioning fire investigation.
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publishDate 2025-04-01
publisher MDPI AG
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spelling doaj-art-23eaadbf31e34d5ea616ca45b190db782025-08-20T02:28:22ZengMDPI AGFire2571-62552025-04-018414510.3390/fire8040145Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After FireYunlong Ou0Ming Fu1Jing Zhang2Wenzhong Mi3Changzheng Li4Shouhai Chen5Shoulei Zheng6School of Safety Science and Engineering, Anhui University of Science and Technology, Huainan 232001, ChinaHefei Institute for Public Safety Research, Tsinghua University, Hefei 230601, ChinaHefei Institute for Public Safety Research, Tsinghua University, Hefei 230601, ChinaHefei Institute for Public Safety Research, Tsinghua University, Hefei 230601, ChinaHefei Institute for Public Safety Research, Tsinghua University, Hefei 230601, ChinaHisense Air Conditioning Co., Ltd., Tsingdao 266736, ChinaTsingdao Haier Home Life Service Co., Ltd., Tsingdao 266103, ChinaThe new eco-friendly flammable refrigerant in air conditioners has resulted in an annual increase in fire incidents associated with these units. Fire investigators face significant challenges in identifying the causes of these fires. In this study, copper tube samples were extracted from various locations of air conditioner condenser debris post fire. The morphology characteristics of the ruptured copper tubes formed by a high-temperature flame in fire and that formed by corrosion were analyzed, respectively. The findings indicate that the ruptures in the copper tubes of air conditioners may be classified into two types based on their origins: ruptures resulting from fire and ruptures resulting from corrosion. The ruptures in the copper tubes resulting from fire are associated with the presence of aluminum alloy fins. At elevated temperatures, the copper and aluminum atoms persist in diffusing and fracturing. A significant quantity of silver-white aluminum is present surrounding the ruptures, and distinct elemental layers may be seen in the cross-section. The corrosion-induced ruptures in the copper tubes are associated with ant nest corrosion. Despite the influence of high-temperature flame melting on surface corrosion pits, they will not entirely obscure the pits and the cross-section continues to exhibit the bifurcated structure characteristic of ant nest corrosion. This investigation demonstrates that corrosion of ant nests is the root cause of copper tube breakage obscured by flames. An investigation method for the refrigerant leakage air conditioning fire is proposed. The above findings can provide proof and method for air conditioning fire investigation.https://www.mdpi.com/2571-6255/8/4/145air conditioning firefire investigationinternal thread copper tubehigh temperaturecorrosionrupture morphology
spellingShingle Yunlong Ou
Ming Fu
Jing Zhang
Wenzhong Mi
Changzheng Li
Shouhai Chen
Shoulei Zheng
Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire
Fire
air conditioning fire
fire investigation
internal thread copper tube
high temperature
corrosion
rupture morphology
title Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire
title_full Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire
title_fullStr Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire
title_full_unstemmed Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire
title_short Case Study on the Rupture Morphology of a Copper Tube in an Air Conditioner Condenser After Fire
title_sort case study on the rupture morphology of a copper tube in an air conditioner condenser after fire
topic air conditioning fire
fire investigation
internal thread copper tube
high temperature
corrosion
rupture morphology
url https://www.mdpi.com/2571-6255/8/4/145
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