Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices
This study covers the synthesis and electrochemical characteristics of a nanocomposite solid electrolyte, AgI–Ag2CO3, including TiO2 nano-filler at various weight percentages ranging from 0 to 40 wt %. A series of compositions with various weight percentages of (1-x) AgI–Ag2CO3 -(x) TiO2 samples hav...
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| Language: | English |
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Elsevier
2025-06-01
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| Series: | Hybrid Advances |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2773207X25000223 |
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| author | Abjana Parbin Shahla Imteyaz Rafiuddin |
| author_facet | Abjana Parbin Shahla Imteyaz Rafiuddin |
| author_sort | Abjana Parbin |
| collection | DOAJ |
| description | This study covers the synthesis and electrochemical characteristics of a nanocomposite solid electrolyte, AgI–Ag2CO3, including TiO2 nano-filler at various weight percentages ranging from 0 to 40 wt %. A series of compositions with various weight percentages of (1-x) AgI–Ag2CO3 -(x) TiO2 samples have been fabricated by the solid-state method and characterized by FT-IR, XRD, SEM-EDX, TEM, and Impedance Spectroscopy to execute a comprehensive structural analysis of the post-synthetically modified solid electrolyte (SE). Among the various nanocomposite material compositions, 20 wt % TiO2 nanocomposite shows the highest ionic conductivity, i.e., σ = 1.159 × 10−2 Scm−1 and the lowest activation energy, 0.4789 eV at 298 K. The suggested conceptual approach was validated by the solid electrolyte's impedance, capacitance, and other structural behavior. The change in structure and morphology of the solid electrolyte has been found to be associated with the increase in conductivity, indicating that the amorphous domain is appropriate for solid-state battery applications. |
| format | Article |
| id | doaj-art-23c2edcd3d96481d964ddab8d66428af |
| institution | Kabale University |
| issn | 2773-207X |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Hybrid Advances |
| spelling | doaj-art-23c2edcd3d96481d964ddab8d66428af2025-08-20T03:25:54ZengElsevierHybrid Advances2773-207X2025-06-01910039810.1016/j.hybadv.2025.100398Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devicesAbjana Parbin0Shahla Imteyaz1 Rafiuddin2Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University, Aligarh, 202002, IndiaPhysical Chemistry Division, Department of Chemistry, Aligarh Muslim University, Aligarh, 202002, IndiaCorresponding author.; Physical Chemistry Division, Department of Chemistry, Aligarh Muslim University, Aligarh, 202002, IndiaThis study covers the synthesis and electrochemical characteristics of a nanocomposite solid electrolyte, AgI–Ag2CO3, including TiO2 nano-filler at various weight percentages ranging from 0 to 40 wt %. A series of compositions with various weight percentages of (1-x) AgI–Ag2CO3 -(x) TiO2 samples have been fabricated by the solid-state method and characterized by FT-IR, XRD, SEM-EDX, TEM, and Impedance Spectroscopy to execute a comprehensive structural analysis of the post-synthetically modified solid electrolyte (SE). Among the various nanocomposite material compositions, 20 wt % TiO2 nanocomposite shows the highest ionic conductivity, i.e., σ = 1.159 × 10−2 Scm−1 and the lowest activation energy, 0.4789 eV at 298 K. The suggested conceptual approach was validated by the solid electrolyte's impedance, capacitance, and other structural behavior. The change in structure and morphology of the solid electrolyte has been found to be associated with the increase in conductivity, indicating that the amorphous domain is appropriate for solid-state battery applications.http://www.sciencedirect.com/science/article/pii/S2773207X25000223Solid electrolyteActivation energyIonic conductivityDielectric constantDielectric modulus |
| spellingShingle | Abjana Parbin Shahla Imteyaz Rafiuddin Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices Hybrid Advances Solid electrolyte Activation energy Ionic conductivity Dielectric constant Dielectric modulus |
| title | Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices |
| title_full | Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices |
| title_fullStr | Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices |
| title_full_unstemmed | Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices |
| title_short | Synthesis and electrochemical characterization of titania nano-filler embedded AgI–Ag2CO3 solid electrolyte for energy storage devices |
| title_sort | synthesis and electrochemical characterization of titania nano filler embedded agi ag2co3 solid electrolyte for energy storage devices |
| topic | Solid electrolyte Activation energy Ionic conductivity Dielectric constant Dielectric modulus |
| url | http://www.sciencedirect.com/science/article/pii/S2773207X25000223 |
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