Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09

Four new lactones, including hypomonacid A (1) and hypomonone A–C (4–6), as well as nine known polyketide analogues (2–3 and 7–13) were obtained from endophytic fungus Hypomontagnella sp. TX-09 derived from Santalum album. Their planar structures were extensively established by analysing HRESIMS and...

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Main Authors: Xin Ouyang, Senhua Chen, Qiling Chen, Heng Guo, Lan Liu, Hongju Liu, Chong Yan
Format: Article
Language:English
Published: Taylor & Francis Group 2025-04-01
Series:Mycology
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/21501203.2024.2397600
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author Xin Ouyang
Senhua Chen
Qiling Chen
Heng Guo
Lan Liu
Hongju Liu
Chong Yan
author_facet Xin Ouyang
Senhua Chen
Qiling Chen
Heng Guo
Lan Liu
Hongju Liu
Chong Yan
author_sort Xin Ouyang
collection DOAJ
description Four new lactones, including hypomonacid A (1) and hypomonone A–C (4–6), as well as nine known polyketide analogues (2–3 and 7–13) were obtained from endophytic fungus Hypomontagnella sp. TX-09 derived from Santalum album. Their planar structures were extensively established by analysing HRESIMS and NMR spectroscopic data. Stereochemistry of new compounds was determined by X-ray diffraction analysis and modified Mosher’s method in combination with quantum-chemical ECD calculation. In addition, compounds 1 and 2 showed anti-inflammatory activity by inhibition of lipopolysaccharide (LPS)-induced NO production in RAW264.7 cells at 50 μmol/L without cytotoxicity. Among them, compound 1 inhibited the production of LPS-stimulated inflammation in mouse macrophage RAW264.7 cells by suppressing the expression of iNOS, TNF-α, IL-1β, and IL-6.
format Article
id doaj-art-230ae70c19c34ff69d0c98b551900486
institution Kabale University
issn 2150-1203
2150-1211
language English
publishDate 2025-04-01
publisher Taylor & Francis Group
record_format Article
series Mycology
spelling doaj-art-230ae70c19c34ff69d0c98b5519004862025-08-20T03:47:28ZengTaylor & Francis GroupMycology2150-12032150-12112025-04-0116291892810.1080/21501203.2024.2397600Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09Xin Ouyang0Senhua Chen1Qiling Chen2Heng Guo3Lan Liu4Hongju Liu5Chong Yan6School of Pharmacy, Guangdong Medical University, Dongguan, ChinaSchool of Marine Sciences, Sun Yat-sen University, Zhuhai, ChinaSchool of Pharmacy, Guangdong Medical University, Dongguan, ChinaSchool of Marine Sciences, Sun Yat-sen University, Zhuhai, ChinaSchool of Marine Sciences, Sun Yat-sen University, Zhuhai, ChinaSchool of Pharmacy, Guangdong Medical University, Dongguan, ChinaSchool of Pharmacy, Guangdong Medical University, Dongguan, ChinaFour new lactones, including hypomonacid A (1) and hypomonone A–C (4–6), as well as nine known polyketide analogues (2–3 and 7–13) were obtained from endophytic fungus Hypomontagnella sp. TX-09 derived from Santalum album. Their planar structures were extensively established by analysing HRESIMS and NMR spectroscopic data. Stereochemistry of new compounds was determined by X-ray diffraction analysis and modified Mosher’s method in combination with quantum-chemical ECD calculation. In addition, compounds 1 and 2 showed anti-inflammatory activity by inhibition of lipopolysaccharide (LPS)-induced NO production in RAW264.7 cells at 50 μmol/L without cytotoxicity. Among them, compound 1 inhibited the production of LPS-stimulated inflammation in mouse macrophage RAW264.7 cells by suppressing the expression of iNOS, TNF-α, IL-1β, and IL-6.https://www.tandfonline.com/doi/10.1080/21501203.2024.2397600Polyketidesendophytic fungusHypomontagnella sp.anti-inflammatory activity
spellingShingle Xin Ouyang
Senhua Chen
Qiling Chen
Heng Guo
Lan Liu
Hongju Liu
Chong Yan
Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09
Mycology
Polyketides
endophytic fungus
Hypomontagnella sp.
anti-inflammatory activity
title Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09
title_full Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09
title_fullStr Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09
title_full_unstemmed Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09
title_short Anti-inflammatory polyketides from Santalum album derived endophytic fungus Hypomontagnella sp. TX-09
title_sort anti inflammatory polyketides from santalum album derived endophytic fungus hypomontagnella sp tx 09
topic Polyketides
endophytic fungus
Hypomontagnella sp.
anti-inflammatory activity
url https://www.tandfonline.com/doi/10.1080/21501203.2024.2397600
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