Iron-catalyzed aliphatic C–H functionalization to construct carbon–carbon bonds
Abstract Although cytochrome P450 enzymes are powerful catalysts for hydrogen-atom abstraction from alkanes by iron-oxo species, the process typically leads to oxygenated products due to ultrafast oxygen rebound. Developing synthetic catalysts that mimic this activity while avoiding oxygenation rema...
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| Main Authors: | Lulu Zhou, Hengrui Cai, Dong Xie, Kangkang Sun, Shanmei Zhu, Mengying Guo, Wei Han |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-05-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-025-60010-1 |
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