Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds
The utilization of waste fibers represents an important environmental benefit and great economic savings for the community. In this study short nylon fibers waste was modified with Glycidyl 3-Pentadecenyl Phenyl Ether (GPPE) in the presence of Triethylamine/Ammonium persulfate by a simple two-step p...
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| Format: | Article |
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Wiley
2019-01-01
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| Series: | Advances in Polymer Technology |
| Online Access: | http://dx.doi.org/10.1155/2019/5847292 |
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| author | Lan Cen Guo-zheng Lv Xin-wen Tan Zhan-lin Gong |
| author_facet | Lan Cen Guo-zheng Lv Xin-wen Tan Zhan-lin Gong |
| author_sort | Lan Cen |
| collection | DOAJ |
| description | The utilization of waste fibers represents an important environmental benefit and great economic savings for the community. In this study short nylon fibers waste was modified with Glycidyl 3-Pentadecenyl Phenyl Ether (GPPE) in the presence of Triethylamine/Ammonium persulfate by a simple two-step procedure. The reinforcing effects of modified fibers (MNSF-2) on the vulcanization characteristics, mechanical properties, dynamic mechanical properties, and the wear resistant property of Styrene Butadiene Rubber (SBR) tread compounds were investigated. The addition of the MNSF-2 resulted in slightly lower minimum torque (ML) and maximum torque (MH), as well as longer cure time (t90) and scorch time (t10) of tread compounds. The deterioration of tensile strength and elongation at break of the tread compound containing short nylon fibers waste (NSF) was apparent. Conversely, the modified fibers showed reinforcing effect on tread compounds. The tensile strength values of compounds increased with MNSF-2 content, passed through a maximum value, and then reduced slightly. The modulus and the tear strength of compounds increased significantly with fiber loadings. The highest tear strength value was observed in 8phr MNSF-2 reinforced SBR compounds, 31.9% higher than that of the gum compound. Meanwhile elongation at break of MNSF-2 compound maintained a relative high value than that of NSF/SBR compound. The addition of NSF exaggerated wear volume of compounds. However, the wear resistance of MNSF-2 compounds was superior to that of NSF compounds and comparable with that of the gum compound. The DMA results reveal that E′ and tanδ values decreased at elevated temperature. Meanwhile enhanced storage modulus in MNSF-2/SBR tread compound can be observed. It is worth highlighting that MNSF-2/SBR compounds show higher tanδ at 0°C, indicating improved wet traction of tread compounds, while tanδ at 60°C maintains almost the same value as that of the gum sample. The results of this study are encouraging, demonstrating that the use of short nylon fibers waste in composites offers promising potential for the green tire application. |
| format | Article |
| id | doaj-art-22caecddddcc48feb0309d6b080e5b2b |
| institution | OA Journals |
| issn | 0730-6679 1098-2329 |
| language | English |
| publishDate | 2019-01-01 |
| publisher | Wiley |
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| series | Advances in Polymer Technology |
| spelling | doaj-art-22caecddddcc48feb0309d6b080e5b2b2025-08-20T02:04:37ZengWileyAdvances in Polymer Technology0730-66791098-23292019-01-01201910.1155/2019/58472925847292Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread CompoundsLan Cen0Guo-zheng Lv1Xin-wen Tan2Zhan-lin Gong3School of Materials and Energy, Guangdong University of Technology, Higher Education Mega Center, Guangzhou 510006, ChinaSchool of Materials and Energy, Guangdong University of Technology, Higher Education Mega Center, Guangzhou 510006, ChinaSchool of Materials and Energy, Guangdong University of Technology, Higher Education Mega Center, Guangzhou 510006, ChinaSchool of Materials and Energy, Guangdong University of Technology, Higher Education Mega Center, Guangzhou 510006, ChinaThe utilization of waste fibers represents an important environmental benefit and great economic savings for the community. In this study short nylon fibers waste was modified with Glycidyl 3-Pentadecenyl Phenyl Ether (GPPE) in the presence of Triethylamine/Ammonium persulfate by a simple two-step procedure. The reinforcing effects of modified fibers (MNSF-2) on the vulcanization characteristics, mechanical properties, dynamic mechanical properties, and the wear resistant property of Styrene Butadiene Rubber (SBR) tread compounds were investigated. The addition of the MNSF-2 resulted in slightly lower minimum torque (ML) and maximum torque (MH), as well as longer cure time (t90) and scorch time (t10) of tread compounds. The deterioration of tensile strength and elongation at break of the tread compound containing short nylon fibers waste (NSF) was apparent. Conversely, the modified fibers showed reinforcing effect on tread compounds. The tensile strength values of compounds increased with MNSF-2 content, passed through a maximum value, and then reduced slightly. The modulus and the tear strength of compounds increased significantly with fiber loadings. The highest tear strength value was observed in 8phr MNSF-2 reinforced SBR compounds, 31.9% higher than that of the gum compound. Meanwhile elongation at break of MNSF-2 compound maintained a relative high value than that of NSF/SBR compound. The addition of NSF exaggerated wear volume of compounds. However, the wear resistance of MNSF-2 compounds was superior to that of NSF compounds and comparable with that of the gum compound. The DMA results reveal that E′ and tanδ values decreased at elevated temperature. Meanwhile enhanced storage modulus in MNSF-2/SBR tread compound can be observed. It is worth highlighting that MNSF-2/SBR compounds show higher tanδ at 0°C, indicating improved wet traction of tread compounds, while tanδ at 60°C maintains almost the same value as that of the gum sample. The results of this study are encouraging, demonstrating that the use of short nylon fibers waste in composites offers promising potential for the green tire application.http://dx.doi.org/10.1155/2019/5847292 |
| spellingShingle | Lan Cen Guo-zheng Lv Xin-wen Tan Zhan-lin Gong Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds Advances in Polymer Technology |
| title | Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds |
| title_full | Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds |
| title_fullStr | Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds |
| title_full_unstemmed | Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds |
| title_short | Short Nylon Fibers Waste Modified with Glycidyl 3-Pentadecenyl Phenyl Ether to Reinforce Styrene Butadiene Rubber Tread Compounds |
| title_sort | short nylon fibers waste modified with glycidyl 3 pentadecenyl phenyl ether to reinforce styrene butadiene rubber tread compounds |
| url | http://dx.doi.org/10.1155/2019/5847292 |
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