A Rapid and Practical Method for Deprotection of 1,1-Diacetates Catalyzed by Zirconium Sulfate Tetrahydrate-Silica Gel
A simple and efficient procedure for converting a variety of 1,1-diacetates into the corresponding aldehydes was developed. The methodology has been done with zirconium sulfate tetrahydrate-silica gel as catalyst. The temperature plays an important role in these reactions. The phenolic acetate funct...
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
2004-06-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31593_d1af73a041c4bcd84e600c3d4b76f873.pdf |
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| Summary: | A simple and efficient procedure for converting a variety of 1,1-diacetates into the corresponding aldehydes was developed. The methodology has been done with zirconium sulfate tetrahydrate-silica gel as catalyst. The temperature plays an important role in these reactions. The phenolic acetate function can selectively be deprotected into phenol. |
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| ISSN: | 1016-1104 2345-6914 |