Simple Ion Transfer at Liquid|Liquid Interfaces
The main aspects related to the charge transfer reactions occurring at the interface between two immiscible electrolyte solutions (ITIES) are described. The particular topics to be discussed involve simple ion transfer. Focus is given on theoretical approaches, numerical simulations, and experimenta...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/462197 |
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| _version_ | 1832558914559803392 |
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| author | L. J. Sanchez Vallejo J. M. Ovejero R. A. Fernández S. A. Dassie |
| author_facet | L. J. Sanchez Vallejo J. M. Ovejero R. A. Fernández S. A. Dassie |
| author_sort | L. J. Sanchez Vallejo |
| collection | DOAJ |
| description | The main aspects related to the charge transfer reactions occurring at the interface between two immiscible electrolyte solutions (ITIES) are described. The particular topics to be discussed involve simple ion transfer. Focus is given on theoretical approaches, numerical simulations, and experimental methodologies. Concerning the theoretical procedures, different computational simulations related to simple ion transfer are reviewed. The main conclusions drawn from the most accepted models are described and analyzed in regard to their relevance for explaining different aspects of ion transfer. We describe numerical simulations implementing different approaches for solving the differential equations associated with the mass transport and charge transfer. These numerical simulations are correlated with selected experimental results; their usefulness in designing new experiments is summarized. Finally, many practical applications can be envisaged regarding the determination of physicochemical properties, electroanalysis, drug lipophilicity, and phase-transfer catalysis. |
| format | Article |
| id | doaj-art-2052d15d4291497abfdb17745ad00fa7 |
| institution | Kabale University |
| issn | 2090-3529 2090-3537 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-2052d15d4291497abfdb17745ad00fa72025-02-03T01:31:16ZengWileyInternational Journal of Electrochemistry2090-35292090-35372012-01-01201210.1155/2012/462197462197Simple Ion Transfer at Liquid|Liquid InterfacesL. J. Sanchez Vallejo0J. M. Ovejero1R. A. Fernández2S. A. Dassie3Instituto de Investigaciones en Fisicoquímica de Córdoba (INFIQC), CONICET y Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaInstituto de Investigaciones en Fisicoquímica de Córdoba (INFIQC), CONICET y Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaInstituto de Investigaciones en Fisicoquímica de Córdoba (INFIQC), CONICET y Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaInstituto de Investigaciones en Fisicoquímica de Córdoba (INFIQC), CONICET y Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba X5000HUA, ArgentinaThe main aspects related to the charge transfer reactions occurring at the interface between two immiscible electrolyte solutions (ITIES) are described. The particular topics to be discussed involve simple ion transfer. Focus is given on theoretical approaches, numerical simulations, and experimental methodologies. Concerning the theoretical procedures, different computational simulations related to simple ion transfer are reviewed. The main conclusions drawn from the most accepted models are described and analyzed in regard to their relevance for explaining different aspects of ion transfer. We describe numerical simulations implementing different approaches for solving the differential equations associated with the mass transport and charge transfer. These numerical simulations are correlated with selected experimental results; their usefulness in designing new experiments is summarized. Finally, many practical applications can be envisaged regarding the determination of physicochemical properties, electroanalysis, drug lipophilicity, and phase-transfer catalysis.http://dx.doi.org/10.1155/2012/462197 |
| spellingShingle | L. J. Sanchez Vallejo J. M. Ovejero R. A. Fernández S. A. Dassie Simple Ion Transfer at Liquid|Liquid Interfaces International Journal of Electrochemistry |
| title | Simple Ion Transfer at Liquid|Liquid Interfaces |
| title_full | Simple Ion Transfer at Liquid|Liquid Interfaces |
| title_fullStr | Simple Ion Transfer at Liquid|Liquid Interfaces |
| title_full_unstemmed | Simple Ion Transfer at Liquid|Liquid Interfaces |
| title_short | Simple Ion Transfer at Liquid|Liquid Interfaces |
| title_sort | simple ion transfer at liquid liquid interfaces |
| url | http://dx.doi.org/10.1155/2012/462197 |
| work_keys_str_mv | AT ljsanchezvallejo simpleiontransferatliquidliquidinterfaces AT jmovejero simpleiontransferatliquidliquidinterfaces AT rafernandez simpleiontransferatliquidliquidinterfaces AT sadassie simpleiontransferatliquidliquidinterfaces |