Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative

<p><span>p-<em><span>tert-</span></em>butylcalix[4]arene was synthesized with the condesation reaction of p-<em><span>tert</span></em>-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl p...

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Main Authors: E. ERDEM, M. YENIÇERI, Ç. AYDIN, R. MAMMADOV, S. SÖYLEYICI
Format: Article
Language:English
Published: izzet kara 2014-07-01
Series:International Journal of Secondary Metabolite
Online Access:http://ijate.net/index.php/ijsm/article/view/31
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author E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
author_facet E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
author_sort E. ERDEM
collection DOAJ
description <p><span>p-<em><span>tert-</span></em>butylcalix[4]arene was synthesized with the condesation reaction of p-<em><span>tert</span></em>-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) was synthesized with appropriate pyrrole and aldehyde compounds and then was bonded p-<em><span>tert</span></em>-butylcalix[4]arene derivative via lower rim hydroxyl groups.</span></p><p><span>The antioxidant activity of the calix[4]arene-BODIPY compound were determined using β-karotene-linoleic acid system. Moreover, the free radical scavenging activity values were tested with DPPH free radical. The compound showed strong antioxidant activity.Total antioxidant activity of the compound was determined using β–carotenelinoleic acid model system and was found the antioxidant activity of 72,50%. The free radical scavenging activities were determined as 75.19%. Results show that, calix[4]arene-BODIPY compound has the antioxidant activity. </span></p>
format Article
id doaj-art-1fdf188ee5da45f0aff6a4f9503a22a5
institution Kabale University
issn 2148-6905
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publishDate 2014-07-01
publisher izzet kara
record_format Article
series International Journal of Secondary Metabolite
spelling doaj-art-1fdf188ee5da45f0aff6a4f9503a22a52025-08-20T03:54:34Zengizzet karaInternational Journal of Secondary Metabolite2148-69052014-07-0111-224Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy DerivativeE. ERDEM0M. YENIÇERIÇ. AYDINR. MAMMADOVS. SÖYLEYICIPamukkale University<p><span>p-<em><span>tert-</span></em>butylcalix[4]arene was synthesized with the condesation reaction of p-<em><span>tert</span></em>-butylphenol and formaldehyde in basic conditions and then has derivatized from the both of two hydroxyl position with chloride which is containing donor oxygen atoms. BODIPY compound (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) was synthesized with appropriate pyrrole and aldehyde compounds and then was bonded p-<em><span>tert</span></em>-butylcalix[4]arene derivative via lower rim hydroxyl groups.</span></p><p><span>The antioxidant activity of the calix[4]arene-BODIPY compound were determined using β-karotene-linoleic acid system. Moreover, the free radical scavenging activity values were tested with DPPH free radical. The compound showed strong antioxidant activity.Total antioxidant activity of the compound was determined using β–carotenelinoleic acid model system and was found the antioxidant activity of 72,50%. The free radical scavenging activities were determined as 75.19%. Results show that, calix[4]arene-BODIPY compound has the antioxidant activity. </span></p>http://ijate.net/index.php/ijsm/article/view/31
spellingShingle E. ERDEM
M. YENIÇERI
Ç. AYDIN
R. MAMMADOV
S. SÖYLEYICI
Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
International Journal of Secondary Metabolite
title Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_full Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_fullStr Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_full_unstemmed Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_short Antioxidant and DPPH (1,1-diphenyl-2-picrylhydrazyl) Free Radical Scavenging Activities of New the Calix[4]arene-bodipy Derivative
title_sort antioxidant and dpph 1 1 diphenyl 2 picrylhydrazyl free radical scavenging activities of new the calix 4 arene bodipy derivative
url http://ijate.net/index.php/ijsm/article/view/31
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