ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves

The agricultural sugarcane residues, bagasse and straws, can be used for second-generation ethanol (2GE) production by the cellulose conversion into glucose (saccharification). However, the lignin content negatively impacts the saccharification process. This polymer is mainly composed of guaiacyl (G...

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Main Authors: Juan Pablo Portilla Llerena, Eduardo Kiyota, Fernanda Raquel Camilo dos Santos, Julio C. Garcia, Rodrigo Faleiro de Lima, Juliana Lischka Sampaio Mayer, Michael dos Santos Brito, Paulo Mazzafera, Silvana Creste, Paula Macedo Nobile
Format: Article
Language:English
Published: Taylor & Francis Group 2024-12-01
Series:GM Crops & Food
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Online Access:https://www.tandfonline.com/doi/10.1080/21645698.2024.2325181
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author Juan Pablo Portilla Llerena
Eduardo Kiyota
Fernanda Raquel Camilo dos Santos
Julio C. Garcia
Rodrigo Faleiro de Lima
Juliana Lischka Sampaio Mayer
Michael dos Santos Brito
Paulo Mazzafera
Silvana Creste
Paula Macedo Nobile
author_facet Juan Pablo Portilla Llerena
Eduardo Kiyota
Fernanda Raquel Camilo dos Santos
Julio C. Garcia
Rodrigo Faleiro de Lima
Juliana Lischka Sampaio Mayer
Michael dos Santos Brito
Paulo Mazzafera
Silvana Creste
Paula Macedo Nobile
author_sort Juan Pablo Portilla Llerena
collection DOAJ
description The agricultural sugarcane residues, bagasse and straws, can be used for second-generation ethanol (2GE) production by the cellulose conversion into glucose (saccharification). However, the lignin content negatively impacts the saccharification process. This polymer is mainly composed of guaiacyl (G), hydroxyphenyl (H), and syringyl (S) units, the latter formed in the ferulate 5-hydroxylase (F5H) branch of the lignin biosynthesis pathway. We have generated transgenic lines overexpressing ShF5H1 under the control of the C4H (cinnamate 4-hydroxylase) rice promoter, which led to a significant increase of up to 160% in the S/G ratio and 63% in the saccharification efficiency in leaves. Nevertheless, the content of lignin was unchanged in this organ. In culms, neither the S/G ratio nor sucrose accumulation was altered, suggesting that ShF5H1 overexpression would not affect first-generation ethanol production. Interestingly, the bagasse showed a significantly higher fiber content. Our results indicate that the tissue-specific manipulation of the biosynthetic branch leading to S unit formation is industrially advantageous and has established a foundation for further studies aiming at refining lignin modifications. Thus, the ShF5H1 overexpression in sugarcane emerges as an efficient strategy to improve 2GE production from straw.
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spelling doaj-art-1ea2056f77d8469a8f63c4456916feb22025-08-20T02:49:20ZengTaylor & Francis GroupGM Crops & Food2164-56982164-57012024-12-01151678410.1080/21645698.2024.2325181ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leavesJuan Pablo Portilla Llerena0Eduardo Kiyota1Fernanda Raquel Camilo dos Santos2Julio C. Garcia3Rodrigo Faleiro de Lima4Juliana Lischka Sampaio Mayer5Michael dos Santos Brito6Paulo Mazzafera7Silvana Creste8Paula Macedo Nobile9Department of Plant Biology, Institute of Biology, University of Campinas, Campinas, BrazilDepartment of Plant Biology, Institute of Biology, University of Campinas, Campinas, BrazilCentro de Cana, Instituto Agronômico (IAC), Ribeirão Preto, BrazilCentro de Cana, Instituto Agronômico (IAC), Ribeirão Preto, BrazilDepartment of Plant Biology, Institute of Biology, University of Campinas, Campinas, BrazilDepartment of Plant Biology, Institute of Biology, University of Campinas, Campinas, BrazilCentro de Cana, Instituto Agronômico (IAC), Ribeirão Preto, BrazilDepartment of Plant Biology, Institute of Biology, University of Campinas, Campinas, BrazilCentro de Cana, Instituto Agronômico (IAC), Ribeirão Preto, BrazilCentro de Cana, Instituto Agronômico (IAC), Ribeirão Preto, BrazilThe agricultural sugarcane residues, bagasse and straws, can be used for second-generation ethanol (2GE) production by the cellulose conversion into glucose (saccharification). However, the lignin content negatively impacts the saccharification process. This polymer is mainly composed of guaiacyl (G), hydroxyphenyl (H), and syringyl (S) units, the latter formed in the ferulate 5-hydroxylase (F5H) branch of the lignin biosynthesis pathway. We have generated transgenic lines overexpressing ShF5H1 under the control of the C4H (cinnamate 4-hydroxylase) rice promoter, which led to a significant increase of up to 160% in the S/G ratio and 63% in the saccharification efficiency in leaves. Nevertheless, the content of lignin was unchanged in this organ. In culms, neither the S/G ratio nor sucrose accumulation was altered, suggesting that ShF5H1 overexpression would not affect first-generation ethanol production. Interestingly, the bagasse showed a significantly higher fiber content. Our results indicate that the tissue-specific manipulation of the biosynthetic branch leading to S unit formation is industrially advantageous and has established a foundation for further studies aiming at refining lignin modifications. Thus, the ShF5H1 overexpression in sugarcane emerges as an efficient strategy to improve 2GE production from straw.https://www.tandfonline.com/doi/10.1080/21645698.2024.2325181Bioenergyferulate 5-hydroxylaselignocellulosemonolignolsaccharum spp
spellingShingle Juan Pablo Portilla Llerena
Eduardo Kiyota
Fernanda Raquel Camilo dos Santos
Julio C. Garcia
Rodrigo Faleiro de Lima
Juliana Lischka Sampaio Mayer
Michael dos Santos Brito
Paulo Mazzafera
Silvana Creste
Paula Macedo Nobile
ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
GM Crops & Food
Bioenergy
ferulate 5-hydroxylase
lignocellulose
monolignol
saccharum spp
title ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
title_full ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
title_fullStr ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
title_full_unstemmed ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
title_short ShF5H1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
title_sort shf5h1 overexpression increases syringyl lignin and improves saccharification in sugarcane leaves
topic Bioenergy
ferulate 5-hydroxylase
lignocellulose
monolignol
saccharum spp
url https://www.tandfonline.com/doi/10.1080/21645698.2024.2325181
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