Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural
Conversion of HMF into FDCA was carried out by a simple and green process based on alkaline ionic liquid (IL) modified Pd/C catalyst (Pd/C-OH−). Alkaline ionic liquids were chosen to optimize Pd/C catalyst for special hydrophilicity and hydrophobicity, redox stability, and unique dissolving abilitie...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2018-01-01
|
| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2018/2018743 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849308082617712640 |
|---|---|
| author | Zou Bin Chen Xueshan Xia Jiaojiao Zhou Cunshan |
| author_facet | Zou Bin Chen Xueshan Xia Jiaojiao Zhou Cunshan |
| author_sort | Zou Bin |
| collection | DOAJ |
| description | Conversion of HMF into FDCA was carried out by a simple and green process based on alkaline ionic liquid (IL) modified Pd/C catalyst (Pd/C-OH−). Alkaline ionic liquids were chosen to optimize Pd/C catalyst for special hydrophilicity and hydrophobicity, redox stability, and unique dissolving abilities for polar compounds. The Pd/C-OH− catalyst was successfully prepared and characterized by SEM, XRD, TG, FT-IR, and CO2-TPD technologies. Loading of alkaline ionic liquid on the surface of Pd/C was 2.54 mmol·g−1. The catalyst showed excellent catalytic activity in the HMF oxidation after optimization of reaction temperature, reaction time, catalyst amount, and solvent. Supported alkaline ionic liquid (IL) could be a substitute and promotion for homogeneous base (NaOH). Under optimal reaction conditions, high HMF conversion of 100% and FDCA yield of 82.39% were achieved over Pd/C-OH− catalyst in water at 373 K for 24 h. |
| format | Article |
| id | doaj-art-1e228df4bdb44853b69f7cf2ef79daee |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-1e228df4bdb44853b69f7cf2ef79daee2025-08-20T03:54:34ZengWileyJournal of Chemistry2090-90632090-90712018-01-01201810.1155/2018/20187432018743Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-HydroxymethylfurfuralZou Bin0Chen Xueshan1Xia Jiaojiao2Zhou Cunshan3School of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, ChinaSchool of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, ChinaSchool of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, ChinaSchool of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, ChinaConversion of HMF into FDCA was carried out by a simple and green process based on alkaline ionic liquid (IL) modified Pd/C catalyst (Pd/C-OH−). Alkaline ionic liquids were chosen to optimize Pd/C catalyst for special hydrophilicity and hydrophobicity, redox stability, and unique dissolving abilities for polar compounds. The Pd/C-OH− catalyst was successfully prepared and characterized by SEM, XRD, TG, FT-IR, and CO2-TPD technologies. Loading of alkaline ionic liquid on the surface of Pd/C was 2.54 mmol·g−1. The catalyst showed excellent catalytic activity in the HMF oxidation after optimization of reaction temperature, reaction time, catalyst amount, and solvent. Supported alkaline ionic liquid (IL) could be a substitute and promotion for homogeneous base (NaOH). Under optimal reaction conditions, high HMF conversion of 100% and FDCA yield of 82.39% were achieved over Pd/C-OH− catalyst in water at 373 K for 24 h.http://dx.doi.org/10.1155/2018/2018743 |
| spellingShingle | Zou Bin Chen Xueshan Xia Jiaojiao Zhou Cunshan Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural Journal of Chemistry |
| title | Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural |
| title_full | Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural |
| title_fullStr | Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural |
| title_full_unstemmed | Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural |
| title_short | Alkaline Ionic Liquid Modified Pd/C Catalyst as an Efficient Catalyst for Oxidation of 5-Hydroxymethylfurfural |
| title_sort | alkaline ionic liquid modified pd c catalyst as an efficient catalyst for oxidation of 5 hydroxymethylfurfural |
| url | http://dx.doi.org/10.1155/2018/2018743 |
| work_keys_str_mv | AT zoubin alkalineionicliquidmodifiedpdccatalystasanefficientcatalystforoxidationof5hydroxymethylfurfural AT chenxueshan alkalineionicliquidmodifiedpdccatalystasanefficientcatalystforoxidationof5hydroxymethylfurfural AT xiajiaojiao alkalineionicliquidmodifiedpdccatalystasanefficientcatalystforoxidationof5hydroxymethylfurfural AT zhoucunshan alkalineionicliquidmodifiedpdccatalystasanefficientcatalystforoxidationof5hydroxymethylfurfural |