Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media

The utilization of fly ash ceramic granulated concrete (FACGC) has been observed in the construction of lightweight prefabricated structures, such as long-span bridges and high-rise buildings. The performance of FACGC is greatly influenced by the coupling effects of steam curing and salt-freezing. T...

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Main Authors: Jin Qu, Haitao Mao, Xiaoju Wang, Chang Liu
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Case Studies in Construction Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2214509525002931
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author Jin Qu
Haitao Mao
Xiaoju Wang
Chang Liu
author_facet Jin Qu
Haitao Mao
Xiaoju Wang
Chang Liu
author_sort Jin Qu
collection DOAJ
description The utilization of fly ash ceramic granulated concrete (FACGC) has been observed in the construction of lightweight prefabricated structures, such as long-span bridges and high-rise buildings. The performance of FACGC is greatly influenced by the coupling effects of steam curing and salt-freezing. This study investigates the alterations in the macroscopic characteristics of FACGC test blocks under freeze-thaw cycles in water and aqueous NaCl solution (3 %), considering both standard curing and steam curing conditions. Scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) were employed to uncover the internal deteriorating mechanism at the microscopic level. The findings indicate that the coupling of salt freezing and steam curing leads to the most significant degradation of mechanical properties and internal pore structure. During the initial 50 freeze-thaw cycles, the mass loss rate initially increases and subsequently decreases across different media. As the number of cycles increases, the mass loss rate and compressive strength loss rise sharply, while the relative dynamic elasticity modulus declines abruptly. The salt-frozen group exhibits abrupt changes 1–2 cycles earlier than the water-frozen group. Nevertheless, the incorporation of fly ash, slag, and silica fume results in a notable enhancement of their strength, ranging from 10 % to 20 %. Additionally, this combination leads to a delay of 1–2 freeze-thaw cycles in reaching the failure threshold. The coupling of steam curing and freeze-thaw resulted in a more rapid formation of large pores and micro-cracks, and the porosity of the test block exhibited a significant increase of 163.78 % when compared to the test block subjected to water freezing and conventional curing. The degradation of the pore size of coal ash ceramic concrete was shown to be influenced by the salt solution in the following sequence: medium pores > large pores > micro-cracks > small pores. Furthermore, the coupling of salt freezing and steam curing increases the calcium-to-silicon (Ca/Si) ratio and reduces internal polymerization degree, while the incorporation of fly ash, slag, and silica fume into the cementing material enhances the internal pore structure and effectively fills the small pores, thereby improving the microscopic properties of FACGC.
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spelling doaj-art-1df5e1fdb1644223814ebfac692b79a92025-08-20T01:58:27ZengElsevierCase Studies in Construction Materials2214-50952025-07-0122e0449510.1016/j.cscm.2025.e04495Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw mediaJin Qu0Haitao Mao1Xiaoju Wang2Chang Liu3Shanxi Agriculture University, College of Urban and Rural Construction, Jinzhong, 030801, People's Republic of China; Shanxi Agriculture University, College of Agriculture Engineering, Jinzhong, 030801, People's Republic of ChinaShanxi Agriculture University, College of Urban and Rural Construction, Jinzhong, 030801, People's Republic of China; Correspondence to: No.1 Mingxian South Road, Taigu District, Jinzhong City, Shanxi Province, 030801, People's Republic of China.Shanxi Agriculture University, College of Urban and Rural Construction, Jinzhong, 030801, People's Republic of ChinaShanxi Agriculture University, College of Urban and Rural Construction, Jinzhong, 030801, People's Republic of ChinaThe utilization of fly ash ceramic granulated concrete (FACGC) has been observed in the construction of lightweight prefabricated structures, such as long-span bridges and high-rise buildings. The performance of FACGC is greatly influenced by the coupling effects of steam curing and salt-freezing. This study investigates the alterations in the macroscopic characteristics of FACGC test blocks under freeze-thaw cycles in water and aqueous NaCl solution (3 %), considering both standard curing and steam curing conditions. Scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) were employed to uncover the internal deteriorating mechanism at the microscopic level. The findings indicate that the coupling of salt freezing and steam curing leads to the most significant degradation of mechanical properties and internal pore structure. During the initial 50 freeze-thaw cycles, the mass loss rate initially increases and subsequently decreases across different media. As the number of cycles increases, the mass loss rate and compressive strength loss rise sharply, while the relative dynamic elasticity modulus declines abruptly. The salt-frozen group exhibits abrupt changes 1–2 cycles earlier than the water-frozen group. Nevertheless, the incorporation of fly ash, slag, and silica fume results in a notable enhancement of their strength, ranging from 10 % to 20 %. Additionally, this combination leads to a delay of 1–2 freeze-thaw cycles in reaching the failure threshold. The coupling of steam curing and freeze-thaw resulted in a more rapid formation of large pores and micro-cracks, and the porosity of the test block exhibited a significant increase of 163.78 % when compared to the test block subjected to water freezing and conventional curing. The degradation of the pore size of coal ash ceramic concrete was shown to be influenced by the salt solution in the following sequence: medium pores > large pores > micro-cracks > small pores. Furthermore, the coupling of salt freezing and steam curing increases the calcium-to-silicon (Ca/Si) ratio and reduces internal polymerization degree, while the incorporation of fly ash, slag, and silica fume into the cementing material enhances the internal pore structure and effectively fills the small pores, thereby improving the microscopic properties of FACGC.http://www.sciencedirect.com/science/article/pii/S2214509525002931Steam curingFly ash ceramic granulated concrete(FACGC)Salt freezePore structure
spellingShingle Jin Qu
Haitao Mao
Xiaoju Wang
Chang Liu
Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media
Case Studies in Construction Materials
Steam curing
Fly ash ceramic granulated concrete(FACGC)
Salt freeze
Pore structure
title Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media
title_full Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media
title_fullStr Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media
title_full_unstemmed Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media
title_short Study on the macro-micro properties of fly ash ceramic granulated concrete (FACGC) under the coupling of curing regime and freeze-thaw media
title_sort study on the macro micro properties of fly ash ceramic granulated concrete facgc under the coupling of curing regime and freeze thaw media
topic Steam curing
Fly ash ceramic granulated concrete(FACGC)
Salt freeze
Pore structure
url http://www.sciencedirect.com/science/article/pii/S2214509525002931
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