Azote asymétrique: racémisation et échange de deutérium dans des complexes macrocycliques
Racemization kinetics of the Ni2+- and Cu2+-complexes of three macrocyclic ligands with coordinated nitrogen as asymmetric centers have been measured. Reaction rates of all the complexes are first order in complex concentration and in hydroxide ion concentration. Arrhenius activation energies are i...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1971-10-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/8939 |
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