Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant

Extensive antibiotic use in swine production contaminates manure and wastewater with antibiotics. Discharging this waste into the environment, even after treatment, potentially fuels the spread of antibiotic resistance. This study investigated a full-scale swine wastewater treatment plant that combi...

Full description

Saved in:
Bibliographic Details
Main Authors: Taeyoung Cha, Min-Sang Kim, Yuhoon Hwang, Eun Sook Jeong, Hongmok Jo, Si-Kyung Cho
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/15/9/5158
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850137678224293888
author Taeyoung Cha
Min-Sang Kim
Yuhoon Hwang
Eun Sook Jeong
Hongmok Jo
Si-Kyung Cho
author_facet Taeyoung Cha
Min-Sang Kim
Yuhoon Hwang
Eun Sook Jeong
Hongmok Jo
Si-Kyung Cho
author_sort Taeyoung Cha
collection DOAJ
description Extensive antibiotic use in swine production contaminates manure and wastewater with antibiotics. Discharging this waste into the environment, even after treatment, potentially fuels the spread of antibiotic resistance. This study investigated a full-scale swine wastewater treatment plant that combines coagulation–sedimentation, sand filtration, ozonation, activated carbon filtration, and a deaeration process. At each stage of this process, samples were collected and analyzed to determine their water quality parameters, antibiotic concentrations, and antibiotic resistance genes (ARGs). The experimental results showed coagulation–sedimentation effectively removed suspended solids (92.2%) and total phosphorus (96.9%). Ozonation significantly reduced antibiotic levels, including sulfamethazine by over 99.9%, although ARGs such as <i>tet</i>M, <i>sul</i>1, and <i>sul</i>2 were only removed at levels up to 95.9%. Interestingly, partial rebounds of sulfamethazine (438.9 μg/L) and marbofloxacin (0.40 μg/L) appeared in the final effluent, suggesting that desorption or operational factors (e.g., hydraulic fluctuation, filter media saturation, and pH) may affect the treatment process. In addition, strong correlations emerged between the levels of suspended solids and those of certain antibiotics (lincomycin, tiamulin), indicating particle-mediated sorption as a key mechanism. Even though ozonation and coagulation–sedimentation were found to contribute to the substantial removal of pollutants, the observed rebounds and residual ARGs highlight the need for optimized operational strategies and multi-barrier approaches to fully mitigate antibiotic contamination and inhibit the proliferation of resistant bacteria in swine wastewater.
format Article
id doaj-art-1dc3d56e530a4c2d833a36bb39d6c844
institution OA Journals
issn 2076-3417
language English
publishDate 2025-05-01
publisher MDPI AG
record_format Article
series Applied Sciences
spelling doaj-art-1dc3d56e530a4c2d833a36bb39d6c8442025-08-20T02:30:46ZengMDPI AGApplied Sciences2076-34172025-05-01159515810.3390/app15095158Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment PlantTaeyoung Cha0Min-Sang Kim1Yuhoon Hwang2Eun Sook Jeong3Hongmok Jo4Si-Kyung Cho5Department of Biological and Environmental Science, Dongguk University, 32 Dongguk-ro, Ilsandong-gu, Goyang 10326, Republic of KoreaDepartment of Biological and Environmental Science, Dongguk University, 32 Dongguk-ro, Ilsandong-gu, Goyang 10326, Republic of KoreaDepartment of Environmental Engineering, Seoul National University of Science and Technology, Seoul 01811, Republic of KoreaInstitute of Environmental Technology, Seoul National University of Science and Technology, Seoul 01811, Republic of KoreaDepartment of Biological and Environmental Science, Dongguk University, 32 Dongguk-ro, Ilsandong-gu, Goyang 10326, Republic of KoreaDepartment of Biological and Environmental Science, Dongguk University, 32 Dongguk-ro, Ilsandong-gu, Goyang 10326, Republic of KoreaExtensive antibiotic use in swine production contaminates manure and wastewater with antibiotics. Discharging this waste into the environment, even after treatment, potentially fuels the spread of antibiotic resistance. This study investigated a full-scale swine wastewater treatment plant that combines coagulation–sedimentation, sand filtration, ozonation, activated carbon filtration, and a deaeration process. At each stage of this process, samples were collected and analyzed to determine their water quality parameters, antibiotic concentrations, and antibiotic resistance genes (ARGs). The experimental results showed coagulation–sedimentation effectively removed suspended solids (92.2%) and total phosphorus (96.9%). Ozonation significantly reduced antibiotic levels, including sulfamethazine by over 99.9%, although ARGs such as <i>tet</i>M, <i>sul</i>1, and <i>sul</i>2 were only removed at levels up to 95.9%. Interestingly, partial rebounds of sulfamethazine (438.9 μg/L) and marbofloxacin (0.40 μg/L) appeared in the final effluent, suggesting that desorption or operational factors (e.g., hydraulic fluctuation, filter media saturation, and pH) may affect the treatment process. In addition, strong correlations emerged between the levels of suspended solids and those of certain antibiotics (lincomycin, tiamulin), indicating particle-mediated sorption as a key mechanism. Even though ozonation and coagulation–sedimentation were found to contribute to the substantial removal of pollutants, the observed rebounds and residual ARGs highlight the need for optimized operational strategies and multi-barrier approaches to fully mitigate antibiotic contamination and inhibit the proliferation of resistant bacteria in swine wastewater.https://www.mdpi.com/2076-3417/15/9/5158swine wastewaterozoneantibioticsantibiotic resistance genes
spellingShingle Taeyoung Cha
Min-Sang Kim
Yuhoon Hwang
Eun Sook Jeong
Hongmok Jo
Si-Kyung Cho
Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant
Applied Sciences
swine wastewater
ozone
antibiotics
antibiotic resistance genes
title Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant
title_full Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant
title_fullStr Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant
title_full_unstemmed Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant
title_short Effects of Ozone Oxidation Process on Residual Antibiotics and Antibiotic Resistance Genes in a Swine Wastewater Treatment Plant
title_sort effects of ozone oxidation process on residual antibiotics and antibiotic resistance genes in a swine wastewater treatment plant
topic swine wastewater
ozone
antibiotics
antibiotic resistance genes
url https://www.mdpi.com/2076-3417/15/9/5158
work_keys_str_mv AT taeyoungcha effectsofozoneoxidationprocessonresidualantibioticsandantibioticresistancegenesinaswinewastewatertreatmentplant
AT minsangkim effectsofozoneoxidationprocessonresidualantibioticsandantibioticresistancegenesinaswinewastewatertreatmentplant
AT yuhoonhwang effectsofozoneoxidationprocessonresidualantibioticsandantibioticresistancegenesinaswinewastewatertreatmentplant
AT eunsookjeong effectsofozoneoxidationprocessonresidualantibioticsandantibioticresistancegenesinaswinewastewatertreatmentplant
AT hongmokjo effectsofozoneoxidationprocessonresidualantibioticsandantibioticresistancegenesinaswinewastewatertreatmentplant
AT sikyungcho effectsofozoneoxidationprocessonresidualantibioticsandantibioticresistancegenesinaswinewastewatertreatmentplant