Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K
Ultrasonic velocity and density measurements were made in two binary liquid mixtures Isopropyl acetate (IPA) and Isobutyl acetate (IBA) with cyclohexanone (CY) as a common component at 303K, at fixed frequency of 2MHz using single crystal variable path interferometer and specific gravity bottle resp...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/681241 |
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| author | P. Paul Divakar B. V. Rao K. Samatha |
| author_facet | P. Paul Divakar B. V. Rao K. Samatha |
| author_sort | P. Paul Divakar |
| collection | DOAJ |
| description | Ultrasonic velocity and density measurements were made in two binary liquid mixtures Isopropyl acetate (IPA) and Isobutyl acetate (IBA) with cyclohexanone (CY) as a common component at 303K, at fixed frequency of 2MHz using single crystal variable path interferometer and specific gravity bottle respectively. The experimental data have been used to calculate the acoustic impedance, adiabatic compressibility, inter molecular free length and molar volume. The excess thermodynamic parameters have been evaluated and discussed in the light of molecular interactions. |
| format | Article |
| id | doaj-art-1d8fbc428876436895378d59e982a149 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-1d8fbc428876436895378d59e982a1492025-02-03T01:26:22ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01931332133510.1155/2012/681241Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303KP. Paul Divakar0B. V. Rao1K. Samatha2Ultrasonic Laboratories, Department of Physics, Andhra University, Visakhapatnam – 530 003, IndiaDepartment of Engineering Chemistry, Andhra University, Visakhapatnam – 530 003, IndiaUltrasonic Laboratories, Department of Physics, Andhra University, Visakhapatnam – 530 003, IndiaUltrasonic velocity and density measurements were made in two binary liquid mixtures Isopropyl acetate (IPA) and Isobutyl acetate (IBA) with cyclohexanone (CY) as a common component at 303K, at fixed frequency of 2MHz using single crystal variable path interferometer and specific gravity bottle respectively. The experimental data have been used to calculate the acoustic impedance, adiabatic compressibility, inter molecular free length and molar volume. The excess thermodynamic parameters have been evaluated and discussed in the light of molecular interactions.http://dx.doi.org/10.1155/2012/681241 |
| spellingShingle | P. Paul Divakar B. V. Rao K. Samatha Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K E-Journal of Chemistry |
| title | Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K |
| title_full | Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K |
| title_fullStr | Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K |
| title_full_unstemmed | Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K |
| title_short | Study of Molecular Interactions in Binary Liquid Mixtures by Acoustical Method at 303K |
| title_sort | study of molecular interactions in binary liquid mixtures by acoustical method at 303k |
| url | http://dx.doi.org/10.1155/2012/681241 |
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