Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation
Flow-through stripping chronopotentiometry with a gold wire electrode was used for the determination of total arsenic and cadmium in cadmium sulphate solutions for cadmium production. The analysis is based on the online separation of arsenic as arsenate anion from cadmium cations by means of a catio...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | Journal of Analytical Methods in Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/814983 |
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| author | Frantisek Cacho Lukas Lauko Alena Manova Jan Dzurov Ernest Beinrohr |
| author_facet | Frantisek Cacho Lukas Lauko Alena Manova Jan Dzurov Ernest Beinrohr |
| author_sort | Frantisek Cacho |
| collection | DOAJ |
| description | Flow-through stripping chronopotentiometry with a gold wire electrode was used for the determination of total arsenic and cadmium in cadmium sulphate solutions for cadmium production. The analysis is based on the online separation of arsenic as arsenate anion from cadmium cations by means of a cation exchanger. On measuring arsenate in the effluent, the trapped cadmium is eluted by sodium chloride solution and determined in a small segment of the effluent by making use of the same electrode. The elaborated protocol enables a full automatic measurement of both species in the same sample solution. The accuracy of the results was confirmed by atomic absorption spectrometry. The LOD and LOQ for Arsenic were found to be 0.9 μg dm-3 and 2.7 μg dm-3, respectively. A linear response range was observed in the concentration range of 1 to 300 μg dm-3 for sample volumes of 4 mL. The repeatability and reproducibility were found to be 2.9% and 5.2%, respectively. The linear response range for cadmium was found to be 0.5 to 60 g/L. The method was tested on samples from a cadmium production plant. |
| format | Article |
| id | doaj-art-1d79bc558b38476b8542cc6539bc62f5 |
| institution | OA Journals |
| issn | 2090-8865 2090-8873 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Analytical Methods in Chemistry |
| spelling | doaj-art-1d79bc558b38476b8542cc6539bc62f52025-08-20T02:01:40ZengWileyJournal of Analytical Methods in Chemistry2090-88652090-88732012-01-01201210.1155/2012/814983814983Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger SeparationFrantisek Cacho0Lukas Lauko1Alena Manova2Jan Dzurov3Ernest Beinrohr4Institute of Analytical Chemistry, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, SlovakiaInstitute of Analytical Chemistry, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, SlovakiaInstitute of Analytical Chemistry, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, SlovakiaIstran Ltd., Zitna 42, 831 06 Bratislava, SlovakiaInstitute of Analytical Chemistry, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, SlovakiaFlow-through stripping chronopotentiometry with a gold wire electrode was used for the determination of total arsenic and cadmium in cadmium sulphate solutions for cadmium production. The analysis is based on the online separation of arsenic as arsenate anion from cadmium cations by means of a cation exchanger. On measuring arsenate in the effluent, the trapped cadmium is eluted by sodium chloride solution and determined in a small segment of the effluent by making use of the same electrode. The elaborated protocol enables a full automatic measurement of both species in the same sample solution. The accuracy of the results was confirmed by atomic absorption spectrometry. The LOD and LOQ for Arsenic were found to be 0.9 μg dm-3 and 2.7 μg dm-3, respectively. A linear response range was observed in the concentration range of 1 to 300 μg dm-3 for sample volumes of 4 mL. The repeatability and reproducibility were found to be 2.9% and 5.2%, respectively. The linear response range for cadmium was found to be 0.5 to 60 g/L. The method was tested on samples from a cadmium production plant.http://dx.doi.org/10.1155/2012/814983 |
| spellingShingle | Frantisek Cacho Lukas Lauko Alena Manova Jan Dzurov Ernest Beinrohr Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation Journal of Analytical Methods in Chemistry |
| title | Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation |
| title_full | Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation |
| title_fullStr | Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation |
| title_full_unstemmed | Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation |
| title_short | Sequential Determination of Total Arsenic and Cadmium in Concentrated Cadmium Sulphate Solutions by Flow-Through Stripping Chronopotentiometry after Online Cation Exchanger Separation |
| title_sort | sequential determination of total arsenic and cadmium in concentrated cadmium sulphate solutions by flow through stripping chronopotentiometry after online cation exchanger separation |
| url | http://dx.doi.org/10.1155/2012/814983 |
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