The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution

In this work the electrochemical deposition of ternary Zn-Ni-Co alloy coatings on steel from sulfate, additive-free electrolyte, was investigated. The ratio of metal cations [Co2+]/[Ni2+] in the plating solution was analysed, as well as the influence of deposition current densities on the chemical c...

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Main Authors: Miroslav B. Jokić, Jelena B. Bajat
Format: Article
Language:English
Published: Engineering Society for Corrosion, Belgrade, Serbia 2016-03-01
Series:Zaštita Materijala
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Online Access:https://www.zastita-materijala.org/index.php/home/article/view/733
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author Miroslav B. Jokić
Jelena B. Bajat
author_facet Miroslav B. Jokić
Jelena B. Bajat
author_sort Miroslav B. Jokić
collection DOAJ
description In this work the electrochemical deposition of ternary Zn-Ni-Co alloy coatings on steel from sulfate, additive-free electrolyte, was investigated. The ratio of metal cations [Co2+]/[Ni2+] in the plating solution was analysed, as well as the influence of deposition current densities on the chemical content and corrosion stability of ternary coatings. Coatings were deposited at 25 °C. On the basis of the results obtained it was shown that the cobalt to nickel ratio is alloy coatings is significantly higher as compared to their ratio in the plating electrolyte, indicating beneficial effect of Ni and Co codeposition. Deposition of Zn-Ni-Co alloy coatings from both plating electrolytes analysed in this work was anomalous. The optimal parameters for electrodeposition of ternary Zn-Ni-Co alloy coatings with increased corrosion stability are metal ion ratio [Co2+]:[Ni2+] = 0,46 in the plating bath and deposition at current densities of 3 i 6 A dm-2.
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publisher Engineering Society for Corrosion, Belgrade, Serbia
record_format Article
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spelling doaj-art-1d400c2373314b4197ee6ab60eeb79872024-12-09T16:49:32ZengEngineering Society for Corrosion, Belgrade, SerbiaZaštita Materijala0351-94652466-25852016-03-0157116617210.5937/ZasMat1601166T732The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solutionMiroslav B. Jokić0Jelena B. Bajat1University of East Sarajevo, Faculty of Technology, Zvornik, Republic of Srpska, B&HUniversity of Belgrade, Faculty of Technology and Metallurgy, SerbiaIn this work the electrochemical deposition of ternary Zn-Ni-Co alloy coatings on steel from sulfate, additive-free electrolyte, was investigated. The ratio of metal cations [Co2+]/[Ni2+] in the plating solution was analysed, as well as the influence of deposition current densities on the chemical content and corrosion stability of ternary coatings. Coatings were deposited at 25 °C. On the basis of the results obtained it was shown that the cobalt to nickel ratio is alloy coatings is significantly higher as compared to their ratio in the plating electrolyte, indicating beneficial effect of Ni and Co codeposition. Deposition of Zn-Ni-Co alloy coatings from both plating electrolytes analysed in this work was anomalous. The optimal parameters for electrodeposition of ternary Zn-Ni-Co alloy coatings with increased corrosion stability are metal ion ratio [Co2+]:[Ni2+] = 0,46 in the plating bath and deposition at current densities of 3 i 6 A dm-2.https://www.zastita-materijala.org/index.php/home/article/view/733electrochemical depositionzn-ni-co alloyscorrosion stabilityeis
spellingShingle Miroslav B. Jokić
Jelena B. Bajat
The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution
Zaštita Materijala
electrochemical deposition
zn-ni-co alloys
corrosion stability
eis
title The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution
title_full The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution
title_fullStr The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution
title_full_unstemmed The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution
title_short The characterization of ternary Zn-Ni-Co alloy coatings electrochemically deposited on steel from sulfate solution
title_sort characterization of ternary zn ni co alloy coatings electrochemically deposited on steel from sulfate solution
topic electrochemical deposition
zn-ni-co alloys
corrosion stability
eis
url https://www.zastita-materijala.org/index.php/home/article/view/733
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