Detection of Adulterants in Herbal Weight Loss Supplements

The growing popularity and consumption of herbal slimming supplements can be attributed to their perception as natural products that lack side effects. However, the composition and ingredient quality listed on their labels often undergo insufficient control. As a result, some manufacturers add undec...

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Main Authors: Oana Ramona Cătălina Gheorghiu, Anne Marie Ciobanu, Claudia Maria Guțu, George-Mădălin Dănilă, Gabriela Viorela Nițescu, Ștefan Rohnean, Daniela Luiza Baconi
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Journal of Mind and Medical Sciences
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Online Access:https://www.mdpi.com/2392-7674/12/1/23
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author Oana Ramona Cătălina Gheorghiu
Anne Marie Ciobanu
Claudia Maria Guțu
George-Mădălin Dănilă
Gabriela Viorela Nițescu
Ștefan Rohnean
Daniela Luiza Baconi
author_facet Oana Ramona Cătălina Gheorghiu
Anne Marie Ciobanu
Claudia Maria Guțu
George-Mădălin Dănilă
Gabriela Viorela Nițescu
Ștefan Rohnean
Daniela Luiza Baconi
author_sort Oana Ramona Cătălina Gheorghiu
collection DOAJ
description The growing popularity and consumption of herbal slimming supplements can be attributed to their perception as natural products that lack side effects. However, the composition and ingredient quality listed on their labels often undergo insufficient control. As a result, some manufacturers add undeclared synthetic pharmaceuticals to enhance weight loss effects. The synthetic adulterants, particularly the anorectic stimulants, have been associated with increased risks of cardiovascular adverse effects, posing significant health risks to consumers. This study aimed to analyze various weight loss supplements marketed as “natural” products to detect possible adulterants. A new high-performance thin-layer chromatography (HPTLC) method was used for initial screening, while gas chromatography coupled with mass spectrometry (GC–MS) served as a confirmation tool. Additionally, high-performance liquid chromatography (HPLC) was employed to analyze phenolphthalein. A total of 34 supplements acquired online or from specialty stores were analyzed. It was found that most of them contain caffeine from herbal ingredients included in the products’ formulation. Some products list the added caffeine, but the measured levels significantly exceeded the labeled values. The most commonly detected adulterants were sibutramine and phenolphthalein. These results highlighted the inadequacies and inconsistencies in labeling, as all herbal supplements were declared “natural” despite containing adulterants. Furthermore, they highlighted the suitability of the HPTLC method as an effective and cost-effective screening tool for detecting adulterants in dietary supplements.
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spelling doaj-art-1d0ca3c3d7b8498aa4b96073d30754012025-08-20T03:27:37ZengMDPI AGJournal of Mind and Medical Sciences2392-76742025-04-011212310.3390/jmms12010023Detection of Adulterants in Herbal Weight Loss SupplementsOana Ramona Cătălina Gheorghiu0Anne Marie Ciobanu1Claudia Maria Guțu2George-Mădălin Dănilă3Gabriela Viorela Nițescu4Ștefan Rohnean5Daniela Luiza Baconi6Department of Toxicology, Carol Davila University of Medicine and Pharmacy, 37 Dionisie Lupu Street, Sector 2, 20021 Bucharest, RomaniaDepartment of Drug Analysis, Carol Davila University of Medicine and Pharmacy, 37 Dionisie Lupu Street, Sector 2, 20021 Bucharest, RomaniaDepartment of Toxicology, Carol Davila University of Medicine and Pharmacy, 37 Dionisie Lupu Street, Sector 2, 20021 Bucharest, RomaniaSCIENT—Instrumental Analysis Research Center, Petre Ispirescu 1, 077167 Tâncăbești, RomaniaDiscipline of Pediatrics, Faculty of Dentistry, Carol Davila University of Medicine and Pharmacy, 17–23 Plevnei Road, 010221 Bucharest, RomaniaNational Anti-Doping Agency, 37–39 Basarabia Blvd, Sector 2, 022103 Bucharest, RomaniaDepartment of Toxicology, Carol Davila University of Medicine and Pharmacy, 37 Dionisie Lupu Street, Sector 2, 20021 Bucharest, RomaniaThe growing popularity and consumption of herbal slimming supplements can be attributed to their perception as natural products that lack side effects. However, the composition and ingredient quality listed on their labels often undergo insufficient control. As a result, some manufacturers add undeclared synthetic pharmaceuticals to enhance weight loss effects. The synthetic adulterants, particularly the anorectic stimulants, have been associated with increased risks of cardiovascular adverse effects, posing significant health risks to consumers. This study aimed to analyze various weight loss supplements marketed as “natural” products to detect possible adulterants. A new high-performance thin-layer chromatography (HPTLC) method was used for initial screening, while gas chromatography coupled with mass spectrometry (GC–MS) served as a confirmation tool. Additionally, high-performance liquid chromatography (HPLC) was employed to analyze phenolphthalein. A total of 34 supplements acquired online or from specialty stores were analyzed. It was found that most of them contain caffeine from herbal ingredients included in the products’ formulation. Some products list the added caffeine, but the measured levels significantly exceeded the labeled values. The most commonly detected adulterants were sibutramine and phenolphthalein. These results highlighted the inadequacies and inconsistencies in labeling, as all herbal supplements were declared “natural” despite containing adulterants. Furthermore, they highlighted the suitability of the HPTLC method as an effective and cost-effective screening tool for detecting adulterants in dietary supplements.https://www.mdpi.com/2392-7674/12/1/23adulterantsdietary supplementssibutraminecaffeinephenolphthaleinHPTLC
spellingShingle Oana Ramona Cătălina Gheorghiu
Anne Marie Ciobanu
Claudia Maria Guțu
George-Mădălin Dănilă
Gabriela Viorela Nițescu
Ștefan Rohnean
Daniela Luiza Baconi
Detection of Adulterants in Herbal Weight Loss Supplements
Journal of Mind and Medical Sciences
adulterants
dietary supplements
sibutramine
caffeine
phenolphthalein
HPTLC
title Detection of Adulterants in Herbal Weight Loss Supplements
title_full Detection of Adulterants in Herbal Weight Loss Supplements
title_fullStr Detection of Adulterants in Herbal Weight Loss Supplements
title_full_unstemmed Detection of Adulterants in Herbal Weight Loss Supplements
title_short Detection of Adulterants in Herbal Weight Loss Supplements
title_sort detection of adulterants in herbal weight loss supplements
topic adulterants
dietary supplements
sibutramine
caffeine
phenolphthalein
HPTLC
url https://www.mdpi.com/2392-7674/12/1/23
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