Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method

Nanocrystals of CdSe have been produced in SiOx matrix layer and in ZnSe heterostructure layer by thermal evaporation method. Structural studies were done by X-ray diffractometer. Quantum confinement effect of CdSe nanocrystals was analyzed from optical studies. Bulk CdSe has band-gap energy of 1.75...

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Main Authors: M. Melvin David Kumar, Suganthi Devadason, S. Rajesh
Format: Article
Language:English
Published: Sumy State University 2012-06-01
Series:Журнал нано- та електронної фізики
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Online Access:http://jnep.sumdu.edu.ua/download/numbers/2012/2/articles/jnep_2012_V4_02021.pdf
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author M. Melvin David Kumar
Suganthi Devadason
S. Rajesh
author_facet M. Melvin David Kumar
Suganthi Devadason
S. Rajesh
author_sort M. Melvin David Kumar
collection DOAJ
description Nanocrystals of CdSe have been produced in SiOx matrix layer and in ZnSe heterostructure layer by thermal evaporation method. Structural studies were done by X-ray diffractometer. Quantum confinement effect of CdSe nanocrystals was analyzed from optical studies. Bulk CdSe has band-gap energy of 1.756 eV that can be shifted to larger values by reducing the crystal size to dimensions smaller than the Bohr radius of the exciton. Experimentally measured band-gap shifts with respect to the bulk value for quantum dot thin films are compared with the predictions of the effective mass approximation model (i.e., Brus model) and Quantum mechanical model. Sizes of the crystallites calculated from both models were coincident with each other.
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publisher Sumy State University
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series Журнал нано- та електронної фізики
spelling doaj-art-1cd20a5708d740cea3fa323fe5ba5b812025-08-20T03:54:51ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722012-06-0142020211Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition MethodM. Melvin David KumarSuganthi DevadasonS. RajeshNanocrystals of CdSe have been produced in SiOx matrix layer and in ZnSe heterostructure layer by thermal evaporation method. Structural studies were done by X-ray diffractometer. Quantum confinement effect of CdSe nanocrystals was analyzed from optical studies. Bulk CdSe has band-gap energy of 1.756 eV that can be shifted to larger values by reducing the crystal size to dimensions smaller than the Bohr radius of the exciton. Experimentally measured band-gap shifts with respect to the bulk value for quantum dot thin films are compared with the predictions of the effective mass approximation model (i.e., Brus model) and Quantum mechanical model. Sizes of the crystallites calculated from both models were coincident with each other.http://jnep.sumdu.edu.ua/download/numbers/2012/2/articles/jnep_2012_V4_02021.pdfMultilayer thin filmsQuantum ConfinementCdSeZnSeSiO
spellingShingle M. Melvin David Kumar
Suganthi Devadason
S. Rajesh
Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method
Журнал нано- та електронної фізики
Multilayer thin films
Quantum Confinement
CdSe
ZnSe
SiO
title Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method
title_full Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method
title_fullStr Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method
title_full_unstemmed Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method
title_short Quantum Confinement in Cadmium Selenide Multilayer Thin Films Using Physical Vapour Deposition Method
title_sort quantum confinement in cadmium selenide multilayer thin films using physical vapour deposition method
topic Multilayer thin films
Quantum Confinement
CdSe
ZnSe
SiO
url http://jnep.sumdu.edu.ua/download/numbers/2012/2/articles/jnep_2012_V4_02021.pdf
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AT suganthidevadason quantumconfinementincadmiumselenidemultilayerthinfilmsusingphysicalvapourdepositionmethod
AT srajesh quantumconfinementincadmiumselenidemultilayerthinfilmsusingphysicalvapourdepositionmethod