Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland

Abstract The objective of this research was to evaluate the seasonal variation of the chemical composition of PM10 including polycyclic aromatic hydrocarbons (PAHs) and 1,3,5-triphenylbenzene (135TPB), which is a well known marker of plastic combustion. The presented work is a part of the project co...

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Main Authors: Przemysław Furman, Katarzyna Styszko, Alicja Skiba, Damian Zięba, Mirosław Zimnoch, Magdalena Kistler, Anne Kasper-Giebl, Stefania Gilardoni
Format: Article
Language:English
Published: Springer 2020-11-01
Series:Aerosol and Air Quality Research
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Online Access:https://doi.org/10.4209/aaqr.2020.05.0223
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author Przemysław Furman
Katarzyna Styszko
Alicja Skiba
Damian Zięba
Mirosław Zimnoch
Magdalena Kistler
Anne Kasper-Giebl
Stefania Gilardoni
author_facet Przemysław Furman
Katarzyna Styszko
Alicja Skiba
Damian Zięba
Mirosław Zimnoch
Magdalena Kistler
Anne Kasper-Giebl
Stefania Gilardoni
author_sort Przemysław Furman
collection DOAJ
description Abstract The objective of this research was to evaluate the seasonal variation of the chemical composition of PM10 including polycyclic aromatic hydrocarbons (PAHs) and 1,3,5-triphenylbenzene (135TPB), which is a well known marker of plastic combustion. The presented work is a part of the project concerning assessment of air quality of small cities around Krakow agglomeration. Monitoring campaign was conducted between February and October 2017 in Wadowice, a small city in Krakow agglomeration, South Poland. To widen the knowledge of Krakow’s agglomeration air quality, other aerosol chemical components were analyzed. Ion chromatography (IC) was used for analysis of cations and anions, while gas chromatography-mass spectrometry (GC-MS) was used for PAHs. Samples were also analyzed for OC/EC (organic/elemental carbon) by thermal-optical analysis with a Sunset Laboratory carbon analyzer, Sunset Inc. The co-combustion of plastic in addition to conventional fuels and the respective impact on air quality is evaluated via the concentration of the marker compound 135TPB. Co-combustion of plastics with fuels resulted in a higher abundance of fluorene and most of 4–6 ring PAHs, in agreement with recent literature. Authors proved that other sources besides plastic burning, including road transport, residential heating, residential combustion, industrial emissions, affect the air quality in South Poland. The modeling tool Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT), developed by NOAA’s Air Resources Laboratory, was used to define the possible areas outside Wadowice contributing to urban air pollution.
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institution Kabale University
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spelling doaj-art-1c5ff1fe047d4794a4615218d393ab052025-02-09T12:20:09ZengSpringerAerosol and Air Quality Research1680-85842071-14092020-11-0121312210.4209/aaqr.2020.05.0223Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South PolandPrzemysław Furman0Katarzyna Styszko1Alicja Skiba2Damian Zięba3Mirosław Zimnoch4Magdalena Kistler5Anne Kasper-Giebl6Stefania Gilardoni7Faculty of Physics and Applied Computer Science, Department of Applied Nuclear Physics, AGH University of Science and TechnologyFaculty of Energy and Fuels, Department of Coal Chemistry and Environmental Sciences, AGH UniversityFaculty of Physics and Applied Computer Science, Department of Applied Nuclear Physics, AGH University of Science and TechnologyFaculty of Physics and Applied Computer Science, Department of Applied Nuclear Physics, AGH University of Science and TechnologyFaculty of Physics and Applied Computer Science, Department of Applied Nuclear Physics, AGH University of Science and TechnologyTU Wien, Institute of Chemical Technologies and AnalyticsTU Wien, Institute of Chemical Technologies and AnalyticsInstitute of Polar Sciences-National Research CouncilAbstract The objective of this research was to evaluate the seasonal variation of the chemical composition of PM10 including polycyclic aromatic hydrocarbons (PAHs) and 1,3,5-triphenylbenzene (135TPB), which is a well known marker of plastic combustion. The presented work is a part of the project concerning assessment of air quality of small cities around Krakow agglomeration. Monitoring campaign was conducted between February and October 2017 in Wadowice, a small city in Krakow agglomeration, South Poland. To widen the knowledge of Krakow’s agglomeration air quality, other aerosol chemical components were analyzed. Ion chromatography (IC) was used for analysis of cations and anions, while gas chromatography-mass spectrometry (GC-MS) was used for PAHs. Samples were also analyzed for OC/EC (organic/elemental carbon) by thermal-optical analysis with a Sunset Laboratory carbon analyzer, Sunset Inc. The co-combustion of plastic in addition to conventional fuels and the respective impact on air quality is evaluated via the concentration of the marker compound 135TPB. Co-combustion of plastics with fuels resulted in a higher abundance of fluorene and most of 4–6 ring PAHs, in agreement with recent literature. Authors proved that other sources besides plastic burning, including road transport, residential heating, residential combustion, industrial emissions, affect the air quality in South Poland. The modeling tool Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT), developed by NOAA’s Air Resources Laboratory, was used to define the possible areas outside Wadowice contributing to urban air pollution.https://doi.org/10.4209/aaqr.2020.05.0223Atmospheric aerosolsPAHs1,3,5-triphenylbenzeneIonsOC/EC
spellingShingle Przemysław Furman
Katarzyna Styszko
Alicja Skiba
Damian Zięba
Mirosław Zimnoch
Magdalena Kistler
Anne Kasper-Giebl
Stefania Gilardoni
Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland
Aerosol and Air Quality Research
Atmospheric aerosols
PAHs
1,3,5-triphenylbenzene
Ions
OC/EC
title Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland
title_full Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland
title_fullStr Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland
title_full_unstemmed Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland
title_short Seasonal Variability of PM10 Chemical Composition Including 1,3,5-triphenylbenzene, Marker of Plastic Combustion and Toxicity in Wadowice, South Poland
title_sort seasonal variability of pm10 chemical composition including 1 3 5 triphenylbenzene marker of plastic combustion and toxicity in wadowice south poland
topic Atmospheric aerosols
PAHs
1,3,5-triphenylbenzene
Ions
OC/EC
url https://doi.org/10.4209/aaqr.2020.05.0223
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