Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.

We have recently shown that the replication of rhinovirus, poliovirus and foot-and-mouth disease virus requires the co-translational N-myristoylation of viral proteins by human host cell N-myristoyltransferases (NMTs), and is inhibited by treatment with IMP-1088, an ultrapotent small molecule NMT in...

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Main Authors: Lalita Priyamvada, Wouter W Kallemeijn, Monica Faronato, Kimberly Wilkins, Cynthia S Goldsmith, Catherine A Cotter, Suany Ojeda, Roberto Solari, Bernard Moss, Edward W Tate, Panayampalli Subbian Satheshkumar
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2022-10-01
Series:PLoS Pathogens
Online Access:https://journals.plos.org/plospathogens/article/file?id=10.1371/journal.ppat.1010662&type=printable
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author Lalita Priyamvada
Wouter W Kallemeijn
Monica Faronato
Kimberly Wilkins
Cynthia S Goldsmith
Catherine A Cotter
Suany Ojeda
Roberto Solari
Bernard Moss
Edward W Tate
Panayampalli Subbian Satheshkumar
author_facet Lalita Priyamvada
Wouter W Kallemeijn
Monica Faronato
Kimberly Wilkins
Cynthia S Goldsmith
Catherine A Cotter
Suany Ojeda
Roberto Solari
Bernard Moss
Edward W Tate
Panayampalli Subbian Satheshkumar
author_sort Lalita Priyamvada
collection DOAJ
description We have recently shown that the replication of rhinovirus, poliovirus and foot-and-mouth disease virus requires the co-translational N-myristoylation of viral proteins by human host cell N-myristoyltransferases (NMTs), and is inhibited by treatment with IMP-1088, an ultrapotent small molecule NMT inhibitor. Here, we examine the importance of N-myristoylation during vaccinia virus (VACV) infection in primate cells and demonstrate the anti-poxviral effects of IMP-1088. N-myristoylated proteins from VACV and the host were metabolically labelled with myristic acid alkyne during infection using quantitative chemical proteomics. We identified VACV proteins A16, G9 and L1 to be N-myristoylated. Treatment with NMT inhibitor IMP-1088 potently abrogated VACV infection, while VACV gene expression, DNA replication, morphogenesis and EV formation remained unaffected. Importantly, we observed that loss of N-myristoylation resulted in greatly reduced infectivity of assembled mature virus particles, characterized by significantly reduced host cell entry and a decline in membrane fusion activity of progeny virus. While the N-myristoylation of VACV entry proteins L1, A16 and G9 was inhibited by IMP-1088, mutational and genetic studies demonstrated that the N-myristoylation of L1 was the most critical for VACV entry. Given the significant genetic identity between VACV, monkeypox virus and variola virus L1 homologs, our data provides a basis for further investigating the role of N-myristoylation in poxviral infections as well as the potential of selective NMT inhibitors like IMP-1088 as broad-spectrum poxvirus inhibitors.
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issn 1553-7366
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publishDate 2022-10-01
publisher Public Library of Science (PLoS)
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spelling doaj-art-1b85968db8404d64b270c818449b42132025-08-20T02:50:37ZengPublic Library of Science (PLoS)PLoS Pathogens1553-73661553-73742022-10-011810e101066210.1371/journal.ppat.1010662Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.Lalita PriyamvadaWouter W KallemeijnMonica FaronatoKimberly WilkinsCynthia S GoldsmithCatherine A CotterSuany OjedaRoberto SolariBernard MossEdward W TatePanayampalli Subbian SatheshkumarWe have recently shown that the replication of rhinovirus, poliovirus and foot-and-mouth disease virus requires the co-translational N-myristoylation of viral proteins by human host cell N-myristoyltransferases (NMTs), and is inhibited by treatment with IMP-1088, an ultrapotent small molecule NMT inhibitor. Here, we examine the importance of N-myristoylation during vaccinia virus (VACV) infection in primate cells and demonstrate the anti-poxviral effects of IMP-1088. N-myristoylated proteins from VACV and the host were metabolically labelled with myristic acid alkyne during infection using quantitative chemical proteomics. We identified VACV proteins A16, G9 and L1 to be N-myristoylated. Treatment with NMT inhibitor IMP-1088 potently abrogated VACV infection, while VACV gene expression, DNA replication, morphogenesis and EV formation remained unaffected. Importantly, we observed that loss of N-myristoylation resulted in greatly reduced infectivity of assembled mature virus particles, characterized by significantly reduced host cell entry and a decline in membrane fusion activity of progeny virus. While the N-myristoylation of VACV entry proteins L1, A16 and G9 was inhibited by IMP-1088, mutational and genetic studies demonstrated that the N-myristoylation of L1 was the most critical for VACV entry. Given the significant genetic identity between VACV, monkeypox virus and variola virus L1 homologs, our data provides a basis for further investigating the role of N-myristoylation in poxviral infections as well as the potential of selective NMT inhibitors like IMP-1088 as broad-spectrum poxvirus inhibitors.https://journals.plos.org/plospathogens/article/file?id=10.1371/journal.ppat.1010662&type=printable
spellingShingle Lalita Priyamvada
Wouter W Kallemeijn
Monica Faronato
Kimberly Wilkins
Cynthia S Goldsmith
Catherine A Cotter
Suany Ojeda
Roberto Solari
Bernard Moss
Edward W Tate
Panayampalli Subbian Satheshkumar
Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.
PLoS Pathogens
title Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.
title_full Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.
title_fullStr Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.
title_full_unstemmed Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.
title_short Inhibition of vaccinia virus L1 N-myristoylation by the host N-myristoyltransferase inhibitor IMP-1088 generates non-infectious virions defective in cell entry.
title_sort inhibition of vaccinia virus l1 n myristoylation by the host n myristoyltransferase inhibitor imp 1088 generates non infectious virions defective in cell entry
url https://journals.plos.org/plospathogens/article/file?id=10.1371/journal.ppat.1010662&type=printable
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