Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity

Abstract Background Carbon metabolism in plants involves biochemical processes such as photosynthesis, respiration, and carbon partitioning. This study aimed to elucidate the physiological and biochemical dynamics during the early development of pea seedlings (Pisum sativum) across five time points...

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Main Authors: Jong Sung Lee, Yu–Mi Shin, Ye Jin Kim, Sang Un Park, Sun-Hwa Ha, HanGyeol Lee, Ji-Eun Ra, Hyung Wook Kwon, Woo Duck Seo, Jae Kwang Kim
Format: Article
Language:English
Published: SpringerOpen 2025-07-01
Series:Chemical and Biological Technologies in Agriculture
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Online Access:https://doi.org/10.1186/s40538-025-00812-z
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author Jong Sung Lee
Yu–Mi Shin
Ye Jin Kim
Sang Un Park
Sun-Hwa Ha
HanGyeol Lee
Ji-Eun Ra
Hyung Wook Kwon
Woo Duck Seo
Jae Kwang Kim
author_facet Jong Sung Lee
Yu–Mi Shin
Ye Jin Kim
Sang Un Park
Sun-Hwa Ha
HanGyeol Lee
Ji-Eun Ra
Hyung Wook Kwon
Woo Duck Seo
Jae Kwang Kim
author_sort Jong Sung Lee
collection DOAJ
description Abstract Background Carbon metabolism in plants involves biochemical processes such as photosynthesis, respiration, and carbon partitioning. This study aimed to elucidate the physiological and biochemical dynamics during the early development of pea seedlings (Pisum sativum) across five time points (6, 9, 12, 15, and 18 days) and five cultivars (Dacheong, Daehyeop 1ho, Sanghyeop, Sacheol, and Cheongmi) using semi-targeted metabolic profiling. Furthermore, we investigated the interplay between photosynthetic activity and secondary metabolite accumulation by profiling the metabolic responses of Dacheong seedlings exposed to varying photosynthetic photon flux densities (PPFDs). Results A total of 83 metabolites were identified. Multivariate analysis revealed similar biochemical dynamics among the five cultivars during the early seedling stage. Metabolic shifts occurred in three distinct phases: (1) an early nitrogen-rich storage metabolism phase characterized by the accumulation of asparagine and raffinose, (2) an intermediate phase marked by the accumulation of branched-chain amino acids, flavonoids, and carotenoids, and (3) a late phase characterized by increased monosaccharides and chlorophylls. These findings suggest that seedling growth relies on the mobilization and conversion of carbohydrates stored in seeds prior to the development of photosynthetic organs. Notably, significant correlations were observed between the photosynthetic pigments and secondary metabolites. Among the cultivars, Dacheong (12 days) exhibited the highest total flavonoid content (33.40 ± 1.29 mg/g). The metabolic changes in Dacheong seedlings under varying PPFD conditions indicated that higher light intensity enhanced sucrose synthesis and chloroplast component composition. Additionally, carotenoid and flavonoid levels peaking at PPFD 400 µmol/m2·s suggested that this light intensity is the optimal condition for maximizing secondary metabolite accumulation through enhanced photosynthetic activity. Conclusions This study is the first to profile the transition from heterotrophic to autotrophic growth in pea seedlings and reveal significant correlations between photosynthetic pigments and secondary metabolites during the seedling period. These findings provide insights into metabolic reprogramming in pea seedlings and inform strategies for enhancing their growth and nutritional quality. Future studies should include hormone analyses to further understand the metabolic transition processes in seedlings. Graphical Abstract
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spelling doaj-art-1b5342039811495096cf5bc262a5f0d42025-08-20T03:46:00ZengSpringerOpenChemical and Biological Technologies in Agriculture2196-56412025-07-0112111710.1186/s40538-025-00812-zTemporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensityJong Sung Lee0Yu–Mi Shin1Ye Jin Kim2Sang Un Park3Sun-Hwa Ha4HanGyeol Lee5Ji-Eun Ra6Hyung Wook Kwon7Woo Duck Seo8Jae Kwang Kim9Division of Life Sciences, Incheon National UniversityDivision of Life Sciences, Incheon National UniversityDivision of Life Sciences, Incheon National UniversityDepartment of Crop Science, Chungnam National UniversityDepartment of Genetics and Biotechnology, Kyung Hee UniversityFood Tech Resources Research Division, National Institute of Crop and Food Science, Rural Development AdministrationFood Tech Resources Research Division, National Institute of Crop and Food Science, Rural Development AdministrationDivision of Life Sciences, Incheon National UniversityInternational Technology Cooperation Center, Rural Development AdministrationDivision of Life Sciences, Incheon National UniversityAbstract Background Carbon metabolism in plants involves biochemical processes such as photosynthesis, respiration, and carbon partitioning. This study aimed to elucidate the physiological and biochemical dynamics during the early development of pea seedlings (Pisum sativum) across five time points (6, 9, 12, 15, and 18 days) and five cultivars (Dacheong, Daehyeop 1ho, Sanghyeop, Sacheol, and Cheongmi) using semi-targeted metabolic profiling. Furthermore, we investigated the interplay between photosynthetic activity and secondary metabolite accumulation by profiling the metabolic responses of Dacheong seedlings exposed to varying photosynthetic photon flux densities (PPFDs). Results A total of 83 metabolites were identified. Multivariate analysis revealed similar biochemical dynamics among the five cultivars during the early seedling stage. Metabolic shifts occurred in three distinct phases: (1) an early nitrogen-rich storage metabolism phase characterized by the accumulation of asparagine and raffinose, (2) an intermediate phase marked by the accumulation of branched-chain amino acids, flavonoids, and carotenoids, and (3) a late phase characterized by increased monosaccharides and chlorophylls. These findings suggest that seedling growth relies on the mobilization and conversion of carbohydrates stored in seeds prior to the development of photosynthetic organs. Notably, significant correlations were observed between the photosynthetic pigments and secondary metabolites. Among the cultivars, Dacheong (12 days) exhibited the highest total flavonoid content (33.40 ± 1.29 mg/g). The metabolic changes in Dacheong seedlings under varying PPFD conditions indicated that higher light intensity enhanced sucrose synthesis and chloroplast component composition. Additionally, carotenoid and flavonoid levels peaking at PPFD 400 µmol/m2·s suggested that this light intensity is the optimal condition for maximizing secondary metabolite accumulation through enhanced photosynthetic activity. Conclusions This study is the first to profile the transition from heterotrophic to autotrophic growth in pea seedlings and reveal significant correlations between photosynthetic pigments and secondary metabolites during the seedling period. These findings provide insights into metabolic reprogramming in pea seedlings and inform strategies for enhancing their growth and nutritional quality. Future studies should include hormone analyses to further understand the metabolic transition processes in seedlings. Graphical Abstracthttps://doi.org/10.1186/s40538-025-00812-zPea seedlingCarotenoidsGrowth periodPhotosynthetic photon flux densityMetabolic profiling
spellingShingle Jong Sung Lee
Yu–Mi Shin
Ye Jin Kim
Sang Un Park
Sun-Hwa Ha
HanGyeol Lee
Ji-Eun Ra
Hyung Wook Kwon
Woo Duck Seo
Jae Kwang Kim
Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
Chemical and Biological Technologies in Agriculture
Pea seedling
Carotenoids
Growth period
Photosynthetic photon flux density
Metabolic profiling
title Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
title_full Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
title_fullStr Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
title_full_unstemmed Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
title_short Temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
title_sort temporal metabolomics of pea seedlings reveals primary and secondary metabolism dynamics under varying light intensity
topic Pea seedling
Carotenoids
Growth period
Photosynthetic photon flux density
Metabolic profiling
url https://doi.org/10.1186/s40538-025-00812-z
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