A Study of Substituted Aliphatic Sulphides on the Corrosion Behaviour of Zinc in Ammonium Chloride Solution

Sulphur containing organic compounds decreases the corrosion rate by increasing the hydrogen over potential on zinc metal due to their electron donating groups. Their inhibiting effect was found to be associated with their adsorption on the active centers of the metal. The inhibition efficiencies of...

Full description

Saved in:
Bibliographic Details
Main Authors: R. Venckatesh, P. S. Syed Shabudeen, S. Gopal
Format: Article
Language:English
Published: Wiley 2007-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2007/789135
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Sulphur containing organic compounds decreases the corrosion rate by increasing the hydrogen over potential on zinc metal due to their electron donating groups. Their inhibiting effect was found to be associated with their adsorption on the active centers of the metal. The inhibition efficiencies of some aliphatic sulphides in ammonium chloride solution have been studied by weight loss studies, polarization and impedance measurements. The effect of substituent groups is correlated with their inhibition performance. These studies due to their relevance in Zn-Manganese dry batteries assume their importance.
ISSN:0973-4945
2090-9810