Silver Molybdate and Silver Tungstate Nanocomposites with Enhanced Photoluminescence

Silver Molybdate and Silver Tungstate Nanocomposites with Enhanced Photoluminescence

Silver molybdate (Ag2MoO4) and silver tungstate (Ag2WO4) nanomaterials were prepared using two complementary methods, microwave assisted hydrothermal synthesis (MAH) (pH 7, 140 °C) and coprecipitation (pH 4, 70 °C), and were then used to prepare two core/shell composites, namely α-Ag2WO4/β-Ag2MoO4 (...

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Bibliographic Details
Main Authors: Yuri V. B. De Santana, José Ernane Cardoso Gomes, Leandro Matos, Guilherme Henrique Cruvinel, André Perrin, Christiane Perrin, Juan Andrès, José A. Varela, Elson Longo
Format: Article
Language:English
Published: Wiley 2014-08-01
Series:Nanomaterials and Nanotechnology
Subjects:
Silver Molybdate
Silver Tungstate
Photoluminescence
Decorated System
Online Access:http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/silver-molybdate-and-silver-tungstate-nanocomposites-with-enhanced-photoluminescence
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Summary:Silver molybdate (Ag2MoO4) and silver tungstate (Ag2WO4) nanomaterials were prepared using two complementary methods, microwave assisted hydrothermal synthesis (MAH) (pH 7, 140 °C) and coprecipitation (pH 4, 70 °C), and were then used to prepare two core/shell composites, namely α-Ag2WO4/β-Ag2MoO4 (MAH, pH 4, 140 °C) and β-Ag2MoO4/β-Ag2WO4 (coprecipitation, pH 4, 70 °C). The shape and size of the microcrystals were observed by field emission scanning electron microscopy (FE-SEM), different morphologies such as balls and nanorods. These powders were characterized by X-ray powder diffraction and UV-vis (diffuse reflectance and photoluminescence). X-ray diffraction patterns showed that the Ag2MoO4 samples obtained by the two methods were single-phased and belonged to the β-Ag2MoO4 structure (spinel type). In contrast, the Ag2WO4 obtained in the two syntheses were structurally different: MAH exhibited the well-known tetrameric stable structure α-Ag2WO4, while coprecipitation afforded the metastable β-Ag2WO4 allotrope, coexisting with a weak amount of the α-phase. The optical gap of β-Ag2WO4 (3.3 eV) was evaluated for the first time. In contrast to β-Ag2MoO4/β-Ag2WO4, the α- Ag2WO4/β-Ag2MoO4 exhibited strongly-enhanced photoluminescence in the low-energy band (650 nm), tentatively explained by the creation of a large density of local defects (distortions) at the core-shell interface, due to the presence of two different types of MOx polyhedra in the two structures.
ISSN:1847-9804

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