Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities
In this study, the impact of typical contaminants—metal carbonates, metal sulfates, and metal acetates with M = Li, Ni, Mn, and Co—on the degradation of the commercial LP30 electrolyte is systematically investigated. Using a combination of electrochemical methods, inductively coupled plasma optical...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-06-01
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| Series: | ChemElectroChem |
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| Online Access: | https://doi.org/10.1002/celc.202500017 |
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| author | Ulf Breddemann Krum Banov Miriam Khodeir Petr Novák |
| author_facet | Ulf Breddemann Krum Banov Miriam Khodeir Petr Novák |
| author_sort | Ulf Breddemann |
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| description | In this study, the impact of typical contaminants—metal carbonates, metal sulfates, and metal acetates with M = Li, Ni, Mn, and Co—on the degradation of the commercial LP30 electrolyte is systematically investigated. Using a combination of electrochemical methods, inductively coupled plasma optical emission spectroscopy, nuclear magnetic resonance spectroscopy, and thermodynamic analyses, the solubility of these impurities, their influence on electrolyte decomposition, and their effect on NMC 811‐based positive electrodes are assessed. Our results indicate that the presence of transition metal contaminants accelerates electrolyte aging, leading to the formation of decomposition products such as HF, OPF2(OH), and OPF(OCH3)2). Electrochemical impedance spectroscopy and galvanostatic cycling reveal that these impurities contribute to increased charge transfer resistance and capacity fading. Notably, nickel‐based contaminants exhibit the strongest impact, likely due to their catalytic activity in side reactions. A detailed thermodynamic analysis further elucidates the reaction pathways responsible for the formation of these degradation products. This study highlights the complex interplay between electrolyte contamination, aging processes, and electrochemical performance, providing valuable insights into the stability of lithium‐ion battery electrolytes and the necessity of impurity control in battery recycling and material purification. |
| format | Article |
| id | doaj-art-1a8313ce2f704b8da2bcced733ec10dd |
| institution | OA Journals |
| issn | 2196-0216 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemElectroChem |
| spelling | doaj-art-1a8313ce2f704b8da2bcced733ec10dd2025-08-20T02:23:11ZengWiley-VCHChemElectroChem2196-02162025-06-011212n/an/a10.1002/celc.202500017Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of ImpuritiesUlf Breddemann0Krum Banov1Miriam Khodeir2Petr Novák3Institute of Energy and Process Systems Engineering (InES) Technische Universität Braunschweig 38106 Braunschweig GermanyInstitute of Energy and Process Systems Engineering (InES) Technische Universität Braunschweig 38106 Braunschweig GermanyInstitute of Energy and Process Systems Engineering (InES) Technische Universität Braunschweig 38106 Braunschweig GermanyInstitute of Energy and Process Systems Engineering (InES) Technische Universität Braunschweig 38106 Braunschweig GermanyIn this study, the impact of typical contaminants—metal carbonates, metal sulfates, and metal acetates with M = Li, Ni, Mn, and Co—on the degradation of the commercial LP30 electrolyte is systematically investigated. Using a combination of electrochemical methods, inductively coupled plasma optical emission spectroscopy, nuclear magnetic resonance spectroscopy, and thermodynamic analyses, the solubility of these impurities, their influence on electrolyte decomposition, and their effect on NMC 811‐based positive electrodes are assessed. Our results indicate that the presence of transition metal contaminants accelerates electrolyte aging, leading to the formation of decomposition products such as HF, OPF2(OH), and OPF(OCH3)2). Electrochemical impedance spectroscopy and galvanostatic cycling reveal that these impurities contribute to increased charge transfer resistance and capacity fading. Notably, nickel‐based contaminants exhibit the strongest impact, likely due to their catalytic activity in side reactions. A detailed thermodynamic analysis further elucidates the reaction pathways responsible for the formation of these degradation products. This study highlights the complex interplay between electrolyte contamination, aging processes, and electrochemical performance, providing valuable insights into the stability of lithium‐ion battery electrolytes and the necessity of impurity control in battery recycling and material purification.https://doi.org/10.1002/celc.202500017electrochemical degradationselectrolyte contaminationslithium‐ion batteriesnuclear magnetic resonance spectroscopytransition metals |
| spellingShingle | Ulf Breddemann Krum Banov Miriam Khodeir Petr Novák Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities ChemElectroChem electrochemical degradations electrolyte contaminations lithium‐ion batteries nuclear magnetic resonance spectroscopy transition metals |
| title | Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities |
| title_full | Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities |
| title_fullStr | Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities |
| title_full_unstemmed | Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities |
| title_short | Electrolytes for Lithium‐Ion Batteries: Chemical Changes over Time and in the Presence of Impurities |
| title_sort | electrolytes for lithium ion batteries chemical changes over time and in the presence of impurities |
| topic | electrochemical degradations electrolyte contaminations lithium‐ion batteries nuclear magnetic resonance spectroscopy transition metals |
| url | https://doi.org/10.1002/celc.202500017 |
| work_keys_str_mv | AT ulfbreddemann electrolytesforlithiumionbatterieschemicalchangesovertimeandinthepresenceofimpurities AT krumbanov electrolytesforlithiumionbatterieschemicalchangesovertimeandinthepresenceofimpurities AT miriamkhodeir electrolytesforlithiumionbatterieschemicalchangesovertimeandinthepresenceofimpurities AT petrnovak electrolytesforlithiumionbatterieschemicalchangesovertimeandinthepresenceofimpurities |