Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions

This paper determines the controlling factors that influence the metals’ behavior water-sediment interaction facies and distribution of elemental content (75As, 111Cd, 59Co, 52Cr, 60Ni, and 208Pb) in water and sediment samples in order to assess the metal pollution status in the Langat River. A tota...

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Main Authors: Wan Ying Lim, Ahmad Zaharin Aris, Mohamad Pauzi Zakaria
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1100/2012/652150
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author Wan Ying Lim
Ahmad Zaharin Aris
Mohamad Pauzi Zakaria
author_facet Wan Ying Lim
Ahmad Zaharin Aris
Mohamad Pauzi Zakaria
author_sort Wan Ying Lim
collection DOAJ
description This paper determines the controlling factors that influence the metals’ behavior water-sediment interaction facies and distribution of elemental content (75As, 111Cd, 59Co, 52Cr, 60Ni, and 208Pb) in water and sediment samples in order to assess the metal pollution status in the Langat River. A total of 90 water and sediment samples were collected simultaneously in triplicate at 30 sampling stations. Selected metals were analyzed using ICP-MS, and the metals’ concentration varied among stations. Metal concentrations of water ranged between 0.08–24.71 μg/L for As, <0.01–0.53 μg/L for Cd, 0.06–6.22 μg/L for Co, 0.32–4.67 μg/L for Cr, 0.80–24.72 μg/L for Ni, and <0.005–6.99 μg/L for Pb. Meanwhile, for sediment, it ranged between 4.47–30.04 mg/kg for As, 0.02–0.18 mg/kg for Cd, 0.87–4.66 mg/kg for Co, 4.31–29.04 mg/kg for Cr, 2.33–8.25 mg/kg for Ni and 5.57–55.71 mg/kg for Pb. The average concentration of studied metals in the water was lower than the Malaysian National Standard for Drinking Water Quality proposed by the Ministry of Health. The average concentration for As in sediment was exceeding ISQG standards as proposed by the Canadian Sediment Quality Guidelines. Statistical analyses revealed that certain metals (As, Co, Ni, and Pb) were generally influenced by pH and conductivity. These results are important when making crucial decisions in determining potential hazardous levels of these metals toward humans.
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spelling doaj-art-19d91ab52b17464cadae8b664c13a29d2025-02-03T06:06:58ZengWileyThe Scientific World Journal1537-744X2012-01-01201210.1100/2012/652150652150Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment InteractionsWan Ying Lim0Ahmad Zaharin Aris1Mohamad Pauzi Zakaria2Centre of Excellence for Environmental Forensics, Faculty of Environmental Studies, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaCentre of Excellence for Environmental Forensics, Faculty of Environmental Studies, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaCentre of Excellence for Environmental Forensics, Faculty of Environmental Studies, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, MalaysiaThis paper determines the controlling factors that influence the metals’ behavior water-sediment interaction facies and distribution of elemental content (75As, 111Cd, 59Co, 52Cr, 60Ni, and 208Pb) in water and sediment samples in order to assess the metal pollution status in the Langat River. A total of 90 water and sediment samples were collected simultaneously in triplicate at 30 sampling stations. Selected metals were analyzed using ICP-MS, and the metals’ concentration varied among stations. Metal concentrations of water ranged between 0.08–24.71 μg/L for As, <0.01–0.53 μg/L for Cd, 0.06–6.22 μg/L for Co, 0.32–4.67 μg/L for Cr, 0.80–24.72 μg/L for Ni, and <0.005–6.99 μg/L for Pb. Meanwhile, for sediment, it ranged between 4.47–30.04 mg/kg for As, 0.02–0.18 mg/kg for Cd, 0.87–4.66 mg/kg for Co, 4.31–29.04 mg/kg for Cr, 2.33–8.25 mg/kg for Ni and 5.57–55.71 mg/kg for Pb. The average concentration of studied metals in the water was lower than the Malaysian National Standard for Drinking Water Quality proposed by the Ministry of Health. The average concentration for As in sediment was exceeding ISQG standards as proposed by the Canadian Sediment Quality Guidelines. Statistical analyses revealed that certain metals (As, Co, Ni, and Pb) were generally influenced by pH and conductivity. These results are important when making crucial decisions in determining potential hazardous levels of these metals toward humans.http://dx.doi.org/10.1100/2012/652150
spellingShingle Wan Ying Lim
Ahmad Zaharin Aris
Mohamad Pauzi Zakaria
Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions
The Scientific World Journal
title Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions
title_full Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions
title_fullStr Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions
title_full_unstemmed Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions
title_short Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions
title_sort spatial variability of metals in surface water and sediment in the langat river and geochemical factors that influence their water sediment interactions
url http://dx.doi.org/10.1100/2012/652150
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AT mohamadpauzizakaria spatialvariabilityofmetalsinsurfacewaterandsedimentinthelangatriverandgeochemicalfactorsthatinfluencetheirwatersedimentinteractions