Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
The trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared co...
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2004-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2004/405086 |
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author | Deepti Joshi T. K. Joshi |
author_facet | Deepti Joshi T. K. Joshi |
author_sort | Deepti Joshi |
collection | DOAJ |
description | The trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared compounds generally obtained as coloured solids and amongst them those containing isopropoxy groups were found to be hygroscopic. All these compound were characterized by azeotrope and elemental analysis as well as by IR, PMR and mass spectral measurements. These spectral data have facilitated in elucidating the mode of bonding of the said metals and non-metals in these compounds with 2-hydroxy-1-naphthoic acid. |
format | Article |
id | doaj-art-19bd58a4b8e44aee935a23a23bf41ceb |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2004-01-01 |
publisher | Wiley |
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series | E-Journal of Chemistry |
spelling | doaj-art-19bd58a4b8e44aee935a23a23bf41ceb2025-02-03T01:02:12ZengWileyE-Journal of Chemistry0973-49452090-98102004-01-011211011410.1155/2004/405086Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic AcidDeepti Joshi0T. K. Joshi1Chemical Laboratories, DSB Campus, Kumaun University, Nainital-263002, Uttranchal, IndiaChemistry Department.CBS&H, G.B.Pant.University of Agriculture and Technology, Pantnagar, IndiaThe trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared compounds generally obtained as coloured solids and amongst them those containing isopropoxy groups were found to be hygroscopic. All these compound were characterized by azeotrope and elemental analysis as well as by IR, PMR and mass spectral measurements. These spectral data have facilitated in elucidating the mode of bonding of the said metals and non-metals in these compounds with 2-hydroxy-1-naphthoic acid.http://dx.doi.org/10.1155/2004/405086 |
spellingShingle | Deepti Joshi T. K. Joshi Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid E-Journal of Chemistry |
title | Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid |
title_full | Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid |
title_fullStr | Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid |
title_full_unstemmed | Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid |
title_short | Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid |
title_sort | synthesis and characterization of some trivalent and tetravalent derivatives of 2 hydroxy 1 naphthoic acid |
url | http://dx.doi.org/10.1155/2004/405086 |
work_keys_str_mv | AT deeptijoshi synthesisandcharacterizationofsometrivalentandtetravalentderivativesof2hydroxy1naphthoicacid AT tkjoshi synthesisandcharacterizationofsometrivalentandtetravalentderivativesof2hydroxy1naphthoicacid |