Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid

The trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared co...

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Main Authors: Deepti Joshi, T. K. Joshi
Format: Article
Language:English
Published: Wiley 2004-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2004/405086
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author Deepti Joshi
T. K. Joshi
author_facet Deepti Joshi
T. K. Joshi
author_sort Deepti Joshi
collection DOAJ
description The trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared compounds generally obtained as coloured solids and amongst them those containing isopropoxy groups were found to be hygroscopic. All these compound were characterized by azeotrope and elemental analysis as well as by IR, PMR and mass spectral measurements. These spectral data have facilitated in elucidating the mode of bonding of the said metals and non-metals in these compounds with 2-hydroxy-1-naphthoic acid.
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publishDate 2004-01-01
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series E-Journal of Chemistry
spelling doaj-art-19bd58a4b8e44aee935a23a23bf41ceb2025-02-03T01:02:12ZengWileyE-Journal of Chemistry0973-49452090-98102004-01-011211011410.1155/2004/405086Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic AcidDeepti Joshi0T. K. Joshi1Chemical Laboratories, DSB Campus, Kumaun University, Nainital-263002, Uttranchal, IndiaChemistry Department.CBS&H, G.B.Pant.University of Agriculture and Technology, Pantnagar, IndiaThe trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared compounds generally obtained as coloured solids and amongst them those containing isopropoxy groups were found to be hygroscopic. All these compound were characterized by azeotrope and elemental analysis as well as by IR, PMR and mass spectral measurements. These spectral data have facilitated in elucidating the mode of bonding of the said metals and non-metals in these compounds with 2-hydroxy-1-naphthoic acid.http://dx.doi.org/10.1155/2004/405086
spellingShingle Deepti Joshi
T. K. Joshi
Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
E-Journal of Chemistry
title Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
title_full Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
title_fullStr Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
title_full_unstemmed Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
title_short Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid
title_sort synthesis and characterization of some trivalent and tetravalent derivatives of 2 hydroxy 1 naphthoic acid
url http://dx.doi.org/10.1155/2004/405086
work_keys_str_mv AT deeptijoshi synthesisandcharacterizationofsometrivalentandtetravalentderivativesof2hydroxy1naphthoicacid
AT tkjoshi synthesisandcharacterizationofsometrivalentandtetravalentderivativesof2hydroxy1naphthoicacid