Interval models of nonequilibrium physicochemical processes

The paper discusses the application of the adaptive interpolation algorithm to problems of chemical kinetics and gas dynamics with interval uncertainties in reaction rate constants. The values of the functions describing the reaction rate may differ considerably if they have been obtained by differe...

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Main Authors: Alexander Yu. Morozov, Dmitry L. Reviznikov, Vladimir Yu. Gidaspov
Format: Article
Language:English
Published: Peoples’ Friendship University of Russia (RUDN University) 2025-07-01
Series:Discrete and Continuous Models and Applied Computational Science
Subjects:
Online Access:https://journals.rudn.ru/miph/article/viewFile/45256/25142
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author Alexander Yu. Morozov
Dmitry L. Reviznikov
Vladimir Yu. Gidaspov
author_facet Alexander Yu. Morozov
Dmitry L. Reviznikov
Vladimir Yu. Gidaspov
author_sort Alexander Yu. Morozov
collection DOAJ
description The paper discusses the application of the adaptive interpolation algorithm to problems of chemical kinetics and gas dynamics with interval uncertainties in reaction rate constants. The values of the functions describing the reaction rate may differ considerably if they have been obtained by different researchers. The difference may reach tens or hundreds of times. Interval uncertainties are proposed to account for these differences in models. Such problems with interval parameters are solved using the previously developed adaptive interpolation algorithm. On the example of modelling the combustion of a hydrogen-oxygen mixture, the effect of uncertainties on the reaction process is demonstrated. One-dimensional nonequilibrium flow in a rocket engine nozzle with different nozzle shapes, including a nozzle with two constrictions, in which a standing detonation wave can arise, is simulated. A numerical study of the effect of uncertainties on the structure of the detonation wave, as well as on steadyystate flow parameters, such as the ignition delay time and the concentration of harmful substances at the nozzle exit, is performed.
format Article
id doaj-art-1962a1fafcdb44278ee28174089b93ff
institution Kabale University
issn 2658-4670
2658-7149
language English
publishDate 2025-07-01
publisher Peoples’ Friendship University of Russia (RUDN University)
record_format Article
series Discrete and Continuous Models and Applied Computational Science
spelling doaj-art-1962a1fafcdb44278ee28174089b93ff2025-08-20T03:58:44ZengPeoples’ Friendship University of Russia (RUDN University)Discrete and Continuous Models and Applied Computational Science2658-46702658-71492025-07-0133218419810.22363/2658-4670-2025-33-2-184-19821082Interval models of nonequilibrium physicochemical processesAlexander Yu. Morozov0https://orcid.org/0000-0003-0364-8665Dmitry L. Reviznikov1https://orcid.org/0000-0003-0998-7975Vladimir Yu. Gidaspov2https://orcid.org/0000-0002-5119-4488Federal Research Center Computer Science and Control of the Russian Academy of SciencesFederal Research Center Computer Science and Control of the Russian Academy of SciencesMoscow Aviation Institute (National Research University)The paper discusses the application of the adaptive interpolation algorithm to problems of chemical kinetics and gas dynamics with interval uncertainties in reaction rate constants. The values of the functions describing the reaction rate may differ considerably if they have been obtained by different researchers. The difference may reach tens or hundreds of times. Interval uncertainties are proposed to account for these differences in models. Such problems with interval parameters are solved using the previously developed adaptive interpolation algorithm. On the example of modelling the combustion of a hydrogen-oxygen mixture, the effect of uncertainties on the reaction process is demonstrated. One-dimensional nonequilibrium flow in a rocket engine nozzle with different nozzle shapes, including a nozzle with two constrictions, in which a standing detonation wave can arise, is simulated. A numerical study of the effect of uncertainties on the structure of the detonation wave, as well as on steadyystate flow parameters, such as the ignition delay time and the concentration of harmful substances at the nozzle exit, is performed.https://journals.rudn.ru/miph/article/viewFile/45256/25142chemical kineticsgas dynamicsinterval parametersinterval velocity constantsnozzlerocket enginestanding detonation waveadaptive interpolation algorithm
spellingShingle Alexander Yu. Morozov
Dmitry L. Reviznikov
Vladimir Yu. Gidaspov
Interval models of nonequilibrium physicochemical processes
Discrete and Continuous Models and Applied Computational Science
chemical kinetics
gas dynamics
interval parameters
interval velocity constants
nozzle
rocket engine
standing detonation wave
adaptive interpolation algorithm
title Interval models of nonequilibrium physicochemical processes
title_full Interval models of nonequilibrium physicochemical processes
title_fullStr Interval models of nonequilibrium physicochemical processes
title_full_unstemmed Interval models of nonequilibrium physicochemical processes
title_short Interval models of nonequilibrium physicochemical processes
title_sort interval models of nonequilibrium physicochemical processes
topic chemical kinetics
gas dynamics
interval parameters
interval velocity constants
nozzle
rocket engine
standing detonation wave
adaptive interpolation algorithm
url https://journals.rudn.ru/miph/article/viewFile/45256/25142
work_keys_str_mv AT alexanderyumorozov intervalmodelsofnonequilibriumphysicochemicalprocesses
AT dmitrylreviznikov intervalmodelsofnonequilibriumphysicochemicalprocesses
AT vladimiryugidaspov intervalmodelsofnonequilibriumphysicochemicalprocesses