Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells

A novel ultrasonic spray pyrolysis for high-quality ZnO films based on zinc-ammonia solution was achieved in air. To investigate the structural and optical properties as well as the performance of polymer solar cells (PSCs), ZnO films at different substrate temperatures and thicknesses were prepared...

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Main Authors: Jiang Cheng, Rong Hu, Qi Wang, Chengxi Zhang, Zhou Xie, Zhangwen Long, Xin Yang, Lu Li
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2015/201472
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author Jiang Cheng
Rong Hu
Qi Wang
Chengxi Zhang
Zhou Xie
Zhangwen Long
Xin Yang
Lu Li
author_facet Jiang Cheng
Rong Hu
Qi Wang
Chengxi Zhang
Zhou Xie
Zhangwen Long
Xin Yang
Lu Li
author_sort Jiang Cheng
collection DOAJ
description A novel ultrasonic spray pyrolysis for high-quality ZnO films based on zinc-ammonia solution was achieved in air. To investigate the structural and optical properties as well as the performance of polymer solar cells (PSCs), ZnO films at different substrate temperatures and thicknesses were prepared. The performance of poly(3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester (P3HT:PCBM) based PSC was found to be improved due to the ZnO films. The crystal structure and roughness of the ZnO films fabricated at different temperatures were found to affect the performance of PSCs. The optimized power conversion efficiency was found to be maximum for PSCs with ZnO films prepared at 200°C. The growth process of these ZnO films is very simple, cost-effective, and compatible for larger-scale PSC preparation. The precursor used for spray pyrolysis is environmentally friendly and helps to achieve ZnO film preparation at a relative low temperature.
format Article
id doaj-art-193fc42b4d5146a3848cbd6506092c5e
institution OA Journals
issn 1110-662X
1687-529X
language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-193fc42b4d5146a3848cbd6506092c5e2025-08-20T02:02:06ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2015-01-01201510.1155/2015/201472201472Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar CellsJiang Cheng0Rong Hu1Qi Wang2Chengxi Zhang3Zhou Xie4Zhangwen Long5Xin Yang6Lu Li7New Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaNew Materials Technology Institute, Co-Innovation Center for Micro/Nano Optoelectronic Materials and Devices, Chongqing University of Arts and Sciences, Chongqing 402160, ChinaA novel ultrasonic spray pyrolysis for high-quality ZnO films based on zinc-ammonia solution was achieved in air. To investigate the structural and optical properties as well as the performance of polymer solar cells (PSCs), ZnO films at different substrate temperatures and thicknesses were prepared. The performance of poly(3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester (P3HT:PCBM) based PSC was found to be improved due to the ZnO films. The crystal structure and roughness of the ZnO films fabricated at different temperatures were found to affect the performance of PSCs. The optimized power conversion efficiency was found to be maximum for PSCs with ZnO films prepared at 200°C. The growth process of these ZnO films is very simple, cost-effective, and compatible for larger-scale PSC preparation. The precursor used for spray pyrolysis is environmentally friendly and helps to achieve ZnO film preparation at a relative low temperature.http://dx.doi.org/10.1155/2015/201472
spellingShingle Jiang Cheng
Rong Hu
Qi Wang
Chengxi Zhang
Zhou Xie
Zhangwen Long
Xin Yang
Lu Li
Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells
International Journal of Photoenergy
title Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells
title_full Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells
title_fullStr Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells
title_full_unstemmed Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells
title_short Substrate Temperature Effect on Charge Transport Performance of ZnO Electron Transport Layer Prepared by a Facile Ultrasonic Spray Pyrolysis in Polymer Solar Cells
title_sort substrate temperature effect on charge transport performance of zno electron transport layer prepared by a facile ultrasonic spray pyrolysis in polymer solar cells
url http://dx.doi.org/10.1155/2015/201472
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