Thermodynamics of solid and liquid aluminium
Based on thermodynamic calculations, it is shown that in the temperature range of 298–1273 K, heating and cooling of aluminum are thermodynamically equilibrium processes. When aluminum is heated, the molar volume energy of Gibbs decreases and the molar boundary energy of nanocrystals increases. When...
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| Format: | Article |
| Language: | English |
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Belarusian National Technical University
2021-09-01
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| Series: | Литьë и металлургия |
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| Online Access: | https://lim.bntu.by/jour/article/view/3360 |
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| author | E. I. Marukovich V. Yu. Stetsenko A. V. Stetsenko |
| author_facet | E. I. Marukovich V. Yu. Stetsenko A. V. Stetsenko |
| author_sort | E. I. Marukovich |
| collection | DOAJ |
| description | Based on thermodynamic calculations, it is shown that in the temperature range of 298–1273 K, heating and cooling of aluminum are thermodynamically equilibrium processes. When aluminum is heated, the molar volume energy of Gibbs decreases and the molar boundary energy of nanocrystals increases. When aluminum is cooled, the molar volume energy of Gibbs increases and the molar boundary energy of nanocrystals decreases. Liquid aluminum is a nanostructured system. Dendritic microcrystals are formed from nanocrystals. They play a large role in the processes of changing the structure of aluminum during its heating and cooling. |
| format | Article |
| id | doaj-art-18cc9e8a73e44e5d9828445a4b138544 |
| institution | DOAJ |
| issn | 1683-6065 2414-0406 |
| language | English |
| publishDate | 2021-09-01 |
| publisher | Belarusian National Technical University |
| record_format | Article |
| series | Литьë и металлургия |
| spelling | doaj-art-18cc9e8a73e44e5d9828445a4b1385442025-08-20T02:55:17ZengBelarusian National Technical UniversityЛитьë и металлургия1683-60652414-04062021-09-0103747710.21122/1683-6065-2021-3-74-773248Thermodynamics of solid and liquid aluminiumE. I. Marukovich0V. Yu. Stetsenko1A. V. Stetsenko2Institute of Technology of Metals of National Academy of Sciences of BelarusInstitute of Technology of Metals of National Academy of Sciences of BelarusBelarusian‑Russian UniversityBased on thermodynamic calculations, it is shown that in the temperature range of 298–1273 K, heating and cooling of aluminum are thermodynamically equilibrium processes. When aluminum is heated, the molar volume energy of Gibbs decreases and the molar boundary energy of nanocrystals increases. When aluminum is cooled, the molar volume energy of Gibbs increases and the molar boundary energy of nanocrystals decreases. Liquid aluminum is a nanostructured system. Dendritic microcrystals are formed from nanocrystals. They play a large role in the processes of changing the structure of aluminum during its heating and cooling.https://lim.bntu.by/jour/article/view/3360aluminumnanocrystalscrystallizationthermodynamicsgibbs energyboundary energyenthalpyentropy |
| spellingShingle | E. I. Marukovich V. Yu. Stetsenko A. V. Stetsenko Thermodynamics of solid and liquid aluminium Литьë и металлургия aluminum nanocrystals crystallization thermodynamics gibbs energy boundary energy enthalpy entropy |
| title | Thermodynamics of solid and liquid aluminium |
| title_full | Thermodynamics of solid and liquid aluminium |
| title_fullStr | Thermodynamics of solid and liquid aluminium |
| title_full_unstemmed | Thermodynamics of solid and liquid aluminium |
| title_short | Thermodynamics of solid and liquid aluminium |
| title_sort | thermodynamics of solid and liquid aluminium |
| topic | aluminum nanocrystals crystallization thermodynamics gibbs energy boundary energy enthalpy entropy |
| url | https://lim.bntu.by/jour/article/view/3360 |
| work_keys_str_mv | AT eimarukovich thermodynamicsofsolidandliquidaluminium AT vyustetsenko thermodynamicsofsolidandliquidaluminium AT avstetsenko thermodynamicsofsolidandliquidaluminium |