Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence

The study based on the chemiluminescence (CL) reaction of potassium ferricyanide and luminol in sodium hydroxide medium, enrofloxacin (ENRO) could dramatically enhance CL intensities and incorporated with matrix solid-phase dispersion (MSPD) technique (Florisil used as dispersant, dichloromethane el...

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Main Authors: Xiaocui Duan, Pingping Zhang, Jing Feng, Ning Jiao
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2014/237359
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author Xiaocui Duan
Pingping Zhang
Jing Feng
Ning Jiao
author_facet Xiaocui Duan
Pingping Zhang
Jing Feng
Ning Jiao
author_sort Xiaocui Duan
collection DOAJ
description The study based on the chemiluminescence (CL) reaction of potassium ferricyanide and luminol in sodium hydroxide medium, enrofloxacin (ENRO) could dramatically enhance CL intensities and incorporated with matrix solid-phase dispersion (MSPD) technique (Florisil used as dispersant, dichloromethane eluted the target compounds). A simple flow injection chemiluminescence (FL-CL) method with MSPD technique for determination of ENRO in eggs was described. Under optimal conditions, the CL intensities were linearly related to ENRO concentration ranging from 4.0×10-8 g.L−1 to 5.0×10-5 g.L−1, with a correlation coefficient of 0.9989 and detection limit of 5.0×10-9 g.L−1. The relative standard deviation was 3.6% at an ENRO concentration of 2.0×10-6 g.L−1. Our testing technique can help ensure food safety, and thus, protect public health.
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institution Kabale University
issn 2090-9063
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language English
publishDate 2014-01-01
publisher Wiley
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series Journal of Chemistry
spelling doaj-art-187413868e5143cab45dff4323a0e6c02025-08-20T03:54:12ZengWileyJournal of Chemistry2090-90632090-90712014-01-01201410.1155/2014/237359237359Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection ChemiluminescenceXiaocui Duan0Pingping Zhang1Jing Feng2Ning Jiao3Hebei Key Lab of Laboratory Animal Department of Genetics, Hebei Medical University, Shijiazhuang 050017, ChinaInstitute of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, ChinaHebei Chemical and Pharmaceutical Vocational Technology College, Shijiazhuang 050031, ChinaPharmaceutical Preparation Section of the Third Hospital of Hebei Medical University, Shijiazhuang 050051, ChinaThe study based on the chemiluminescence (CL) reaction of potassium ferricyanide and luminol in sodium hydroxide medium, enrofloxacin (ENRO) could dramatically enhance CL intensities and incorporated with matrix solid-phase dispersion (MSPD) technique (Florisil used as dispersant, dichloromethane eluted the target compounds). A simple flow injection chemiluminescence (FL-CL) method with MSPD technique for determination of ENRO in eggs was described. Under optimal conditions, the CL intensities were linearly related to ENRO concentration ranging from 4.0×10-8 g.L−1 to 5.0×10-5 g.L−1, with a correlation coefficient of 0.9989 and detection limit of 5.0×10-9 g.L−1. The relative standard deviation was 3.6% at an ENRO concentration of 2.0×10-6 g.L−1. Our testing technique can help ensure food safety, and thus, protect public health.http://dx.doi.org/10.1155/2014/237359
spellingShingle Xiaocui Duan
Pingping Zhang
Jing Feng
Ning Jiao
Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence
Journal of Chemistry
title Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence
title_full Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence
title_fullStr Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence
title_full_unstemmed Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence
title_short Evaluation of Antibacterial Enrofloxacin in Eggs by Matrix Solid Phase Dispersion-Flow Injection Chemiluminescence
title_sort evaluation of antibacterial enrofloxacin in eggs by matrix solid phase dispersion flow injection chemiluminescence
url http://dx.doi.org/10.1155/2014/237359
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AT jingfeng evaluationofantibacterialenrofloxacinineggsbymatrixsolidphasedispersionflowinjectionchemiluminescence
AT ningjiao evaluationofantibacterialenrofloxacinineggsbymatrixsolidphasedispersionflowinjectionchemiluminescence