High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites

Hybrid asymmetric supercapacitors using distinct cathode/anode materials offer enhanced energy density by expanding operational potential windows compared to symmetric configurations. In this work rGO/α-Fe₂O₃ and rGO/TiO₂ nanocomposites were synthesized via hydrothermal method for hybrid asymmetric...

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Main Authors: Zeinab Abbasali KarajAbad, Adrine Malek Khachatourian, Mohammad Golmohammad, Ali Nemati
Format: Article
Language:English
Published: Iran University of Science & Technology 2025-03-01
Series:Iranian Journal of Materials Science and Engineering
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Online Access:http://ijmse.iust.ac.ir/article-1-3791-en.pdf
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author Zeinab Abbasali KarajAbad
Adrine Malek Khachatourian
Mohammad Golmohammad
Ali Nemati
author_facet Zeinab Abbasali KarajAbad
Adrine Malek Khachatourian
Mohammad Golmohammad
Ali Nemati
author_sort Zeinab Abbasali KarajAbad
collection DOAJ
description Hybrid asymmetric supercapacitors using distinct cathode/anode materials offer enhanced energy density by expanding operational potential windows compared to symmetric configurations. In this work rGO/α-Fe₂O₃ and rGO/TiO₂ nanocomposites were synthesized via hydrothermal method for hybrid asymmetric supercapacitors applications. Field emission scanning electron microscope (FESEM) revealed uniform distribution of spherical α-Fe₂O₃ and TiO₂ nanoparticles on rGO sheets. The X-ray diffractometry (XRD) analysis confirmed the presence of the hematite and anatase in the rGO/α-Fe2O3 and rGO/TiO2 nanocomposites, respectively. Additionally, in the XRD spectra of both nanocomposites, a broad peak corresponding to the (002) crystalline planes of rGO was observed. Electrochemical testing showed specific capacities of 130 F/g (rGO/α-Fe₂O₃) and 253 F/g (rGO/TiO₂) at 5 mV/s in 1M KOH. The assembled hybrid asymmetric supercapacitors (rGO/α-Fe₂O₃//rGO/TiO₂) achieved a 1.6 V operational potential window. Power density and energy density of 1066 W kg-1 and 9.7 Wh kg-1 were achieved at a current density of 1 A/g, respectively.
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publisher Iran University of Science & Technology
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spelling doaj-art-183ee9f31223401abea0beec6f46e8962025-08-20T03:06:09ZengIran University of Science & TechnologyIranian Journal of Materials Science and Engineering1735-08082383-38822025-03-0122199106High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 NanocompositesZeinab Abbasali KarajAbad0Adrine Malek Khachatourian1Mohammad Golmohammad2Ali Nemati3 Sharif University of Technology Sharif University of Technology Niroo Research Institute (NRI) Sharif University of Technology Hybrid asymmetric supercapacitors using distinct cathode/anode materials offer enhanced energy density by expanding operational potential windows compared to symmetric configurations. In this work rGO/α-Fe₂O₃ and rGO/TiO₂ nanocomposites were synthesized via hydrothermal method for hybrid asymmetric supercapacitors applications. Field emission scanning electron microscope (FESEM) revealed uniform distribution of spherical α-Fe₂O₃ and TiO₂ nanoparticles on rGO sheets. The X-ray diffractometry (XRD) analysis confirmed the presence of the hematite and anatase in the rGO/α-Fe2O3 and rGO/TiO2 nanocomposites, respectively. Additionally, in the XRD spectra of both nanocomposites, a broad peak corresponding to the (002) crystalline planes of rGO was observed. Electrochemical testing showed specific capacities of 130 F/g (rGO/α-Fe₂O₃) and 253 F/g (rGO/TiO₂) at 5 mV/s in 1M KOH. The assembled hybrid asymmetric supercapacitors (rGO/α-Fe₂O₃//rGO/TiO₂) achieved a 1.6 V operational potential window. Power density and energy density of 1066 W kg-1 and 9.7 Wh kg-1 were achieved at a current density of 1 A/g, respectively.http://ijmse.iust.ac.ir/article-1-3791-en.pdfhybrid asymmetric supercapacitorgraphene oxidergo/α-fe2o3rgo/tio2nanocomposite
spellingShingle Zeinab Abbasali KarajAbad
Adrine Malek Khachatourian
Mohammad Golmohammad
Ali Nemati
High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites
Iranian Journal of Materials Science and Engineering
hybrid asymmetric supercapacitor
graphene oxide
rgo/α-fe2o3
rgo/tio2
nanocomposite
title High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites
title_full High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites
title_fullStr High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites
title_full_unstemmed High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites
title_short High-Performance Hybrid Asymmetric Supercapacitors with rGO/α-Fe2O3 and rGO/TiO2 Nanocomposites
title_sort high performance hybrid asymmetric supercapacitors with rgo α fe2o3 and rgo tio2 nanocomposites
topic hybrid asymmetric supercapacitor
graphene oxide
rgo/α-fe2o3
rgo/tio2
nanocomposite
url http://ijmse.iust.ac.ir/article-1-3791-en.pdf
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AT adrinemalekkhachatourian highperformancehybridasymmetricsupercapacitorswithrgoafe2o3andrgotio2nanocomposites
AT mohammadgolmohammad highperformancehybridasymmetricsupercapacitorswithrgoafe2o3andrgotio2nanocomposites
AT alinemati highperformancehybridasymmetricsupercapacitorswithrgoafe2o3andrgotio2nanocomposites