The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin

The mechanical stability and deformability of erythrocytes are vital for their function as they traverse capillaries, where shear stress can reach up to 10 Pa under physiological conditions. Human serum albumin (HSA) is known to help maintain erythrocyte stability by influencing cell shape, membrane...

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Main Authors: Ivana Pajic-Lijakovic, Milan Milivojevic, Gregory Barshtein, Alexander Gural
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Cells
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Online Access:https://www.mdpi.com/2073-4409/14/15/1139
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author Ivana Pajic-Lijakovic
Milan Milivojevic
Gregory Barshtein
Alexander Gural
author_facet Ivana Pajic-Lijakovic
Milan Milivojevic
Gregory Barshtein
Alexander Gural
author_sort Ivana Pajic-Lijakovic
collection DOAJ
description The mechanical stability and deformability of erythrocytes are vital for their function as they traverse capillaries, where shear stress can reach up to 10 Pa under physiological conditions. Human serum albumin (HSA) is known to help maintain erythrocyte stability by influencing cell shape, membrane integrity, and resistance to hemolysis. However, the precise mechanisms by which albumin exerts these effects remain debated, with some studies indicating a stabilizing role and others suggesting the opposite. This review highlights that under high shear rates, albumin molecules may undergo unfolding due to normal stress differences. Such structural changes can significantly alter albumin’s interactions with the erythrocyte membrane, thereby affecting cell mechanical stability. We discuss two potential scenarios explaining how albumin influences erythrocyte mechanics under shear stress, considering both the viscoelastic properties of blood and those of the erythrocyte membrane. Based on theoretical analyses and experimental evidence from the literature, we propose that albumin’s effect on erythrocyte mechanical stability depends on (i) the transition between unfolded and folded states of the protein and (ii) the impact of shear stress on the erythrocyte membrane’s ζ-potential. Understanding these factors is essential for elucidating the complex relationship between albumin and erythrocyte mechanics in physiological and pathological conditions.
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spelling doaj-art-17957556a6c84554845c7d26490b0cbc2025-08-20T04:00:54ZengMDPI AGCells2073-44092025-07-011415113910.3390/cells14151139The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of AlbuminIvana Pajic-Lijakovic0Milan Milivojevic1Gregory Barshtein2Alexander Gural3Faculty of Technology and Metallurgy, University of Belgrade, 11000 Belgrade, SerbiaFaculty of Technology and Metallurgy, University of Belgrade, 11000 Belgrade, SerbiaDepartment of Biochemistry, The Faculty of Medicine, Hebrew University, Jerusalem 91120, IsraelBlood Bank, Hadassah-Hebrew University Medical Center, Jerusalem 91120, IsraelThe mechanical stability and deformability of erythrocytes are vital for their function as they traverse capillaries, where shear stress can reach up to 10 Pa under physiological conditions. Human serum albumin (HSA) is known to help maintain erythrocyte stability by influencing cell shape, membrane integrity, and resistance to hemolysis. However, the precise mechanisms by which albumin exerts these effects remain debated, with some studies indicating a stabilizing role and others suggesting the opposite. This review highlights that under high shear rates, albumin molecules may undergo unfolding due to normal stress differences. Such structural changes can significantly alter albumin’s interactions with the erythrocyte membrane, thereby affecting cell mechanical stability. We discuss two potential scenarios explaining how albumin influences erythrocyte mechanics under shear stress, considering both the viscoelastic properties of blood and those of the erythrocyte membrane. Based on theoretical analyses and experimental evidence from the literature, we propose that albumin’s effect on erythrocyte mechanical stability depends on (i) the transition between unfolded and folded states of the protein and (ii) the impact of shear stress on the erythrocyte membrane’s ζ-potential. Understanding these factors is essential for elucidating the complex relationship between albumin and erythrocyte mechanics in physiological and pathological conditions.https://www.mdpi.com/2073-4409/14/15/1139unfolding of albuminextensional flowdiscocyte-to-stomatocyte transitionelectrostatic interactionshydrophobic interactionsblood viscoelasticity
spellingShingle Ivana Pajic-Lijakovic
Milan Milivojevic
Gregory Barshtein
Alexander Gural
The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin
Cells
unfolding of albumin
extensional flow
discocyte-to-stomatocyte transition
electrostatic interactions
hydrophobic interactions
blood viscoelasticity
title The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin
title_full The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin
title_fullStr The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin
title_full_unstemmed The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin
title_short The Mechanical Properties of Erythrocytes Are Influenced by the Conformational State of Albumin
title_sort mechanical properties of erythrocytes are influenced by the conformational state of albumin
topic unfolding of albumin
extensional flow
discocyte-to-stomatocyte transition
electrostatic interactions
hydrophobic interactions
blood viscoelasticity
url https://www.mdpi.com/2073-4409/14/15/1139
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