Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt

High silicon and molybdenum (SiMo) ductile irons present a metallic matrix composed principally of ferrite with little volume fraction of pearlite and carbides. In this work, two SiMo ductile irons with similar levels of silicon, 0.3% Mo (DI-0.3Mo) and 0.6% Mo with 0.8% Co (DI-0.6Mo-0.8Co), were eva...

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Main Authors: Eduardo Colin-García, Alejandro Cruz-Ramírez, Marisa Moreno-Ríos, Ricardo Gerardo Sánchez-Alvarado, José Antonio Romero-Serrano, Juan Cancio Jiménez-Lugos, Armando Irvin Martínez-Pérez, Edgar Ernesto Vera-Cárdenas
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Language:English
Published: MDPI AG 2025-03-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/15/3/278
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author Eduardo Colin-García
Alejandro Cruz-Ramírez
Marisa Moreno-Ríos
Ricardo Gerardo Sánchez-Alvarado
José Antonio Romero-Serrano
Juan Cancio Jiménez-Lugos
Armando Irvin Martínez-Pérez
Edgar Ernesto Vera-Cárdenas
author_facet Eduardo Colin-García
Alejandro Cruz-Ramírez
Marisa Moreno-Ríos
Ricardo Gerardo Sánchez-Alvarado
José Antonio Romero-Serrano
Juan Cancio Jiménez-Lugos
Armando Irvin Martínez-Pérez
Edgar Ernesto Vera-Cárdenas
author_sort Eduardo Colin-García
collection DOAJ
description High silicon and molybdenum (SiMo) ductile irons present a metallic matrix composed principally of ferrite with little volume fraction of pearlite and carbides. In this work, two SiMo ductile irons with similar levels of silicon, 0.3% Mo (DI-0.3Mo) and 0.6% Mo with 0.8% Co (DI-0.6Mo-0.8Co), were evaluated to determine the effect of molybdenum and cobalt on the microstructure, hardness, and wear performance at room temperature. The microstructural characterization of the ductile irons was performed using light microscopy and SEM-EDS. At the same time, mechanical characterization was carried out using Rockwell C hardness, and wear was evaluated using reciprocating ball-on-flat sliding wear tests. The result showed that DI-0.6Mo-0.8Co obtained the higher nodule count (247 nod/mm<sup>2</sup>), nodularity (86.69%), volume fraction of ferrite (78.15%), and molybdenum carbides (2.1%), while DI-0.3Mo presented a higher volume fraction of pearlite (12.8%) and free graphite (13.88%). The higher value of Rockwell C hardness with 21.29 HRC was obtained in DI-0.6Mo-0.8Co due to a higher amount of molybdenum carbides. The wear resistance shows that the DI-0.6Mo-0.8Co sample presented the highest wear resistance due to an adequate balance between a ferritic matrix reinforced by the molybdenum and cobalt addition and a high carbide content.
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spelling doaj-art-16d73caa348043859e4216b1e8669cda2025-08-20T02:11:01ZengMDPI AGCrystals2073-43522025-03-0115327810.3390/cryst15030278Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with CobaltEduardo Colin-García0Alejandro Cruz-Ramírez1Marisa Moreno-Ríos2Ricardo Gerardo Sánchez-Alvarado3José Antonio Romero-Serrano4Juan Cancio Jiménez-Lugos5Armando Irvin Martínez-Pérez6Edgar Ernesto Vera-Cárdenas7Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Unidad Profesional Adolfo López Mateos, Ciudad de México 07738, MexicoUnidad Profesional Interdisciplinaria de Ingeniería Campus Hidalgo, Instituto Politécnico Nacional, Carretera Pachuca-Actopan km 1-500, San Agustín Tlaxiaca 42162, MexicoDivisión de Estudios de Posgrado e Investigación, Tecnológico Nacional de México/Instituto Tecnológico de Pachuca, Pachuca 42080, MexicoEscuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Unidad Profesional Adolfo López Mateos, Ciudad de México 07738, MexicoEscuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Unidad Profesional Adolfo López Mateos, Ciudad de México 07738, MexicoEscuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Unidad Profesional Adolfo López Mateos, Ciudad de México 07738, MexicoDivisión de Estudios de Posgrado e Investigación, Tecnológico Nacional de México/Instituto Tecnológico de Pachuca, Pachuca 42080, MexicoDivisión de Estudios de Posgrado e Investigación, Tecnológico Nacional de México/Instituto Tecnológico de Pachuca, Pachuca 42080, MexicoHigh silicon and molybdenum (SiMo) ductile irons present a metallic matrix composed principally of ferrite with little volume fraction of pearlite and carbides. In this work, two SiMo ductile irons with similar levels of silicon, 0.3% Mo (DI-0.3Mo) and 0.6% Mo with 0.8% Co (DI-0.6Mo-0.8Co), were evaluated to determine the effect of molybdenum and cobalt on the microstructure, hardness, and wear performance at room temperature. The microstructural characterization of the ductile irons was performed using light microscopy and SEM-EDS. At the same time, mechanical characterization was carried out using Rockwell C hardness, and wear was evaluated using reciprocating ball-on-flat sliding wear tests. The result showed that DI-0.6Mo-0.8Co obtained the higher nodule count (247 nod/mm<sup>2</sup>), nodularity (86.69%), volume fraction of ferrite (78.15%), and molybdenum carbides (2.1%), while DI-0.3Mo presented a higher volume fraction of pearlite (12.8%) and free graphite (13.88%). The higher value of Rockwell C hardness with 21.29 HRC was obtained in DI-0.6Mo-0.8Co due to a higher amount of molybdenum carbides. The wear resistance shows that the DI-0.6Mo-0.8Co sample presented the highest wear resistance due to an adequate balance between a ferritic matrix reinforced by the molybdenum and cobalt addition and a high carbide content.https://www.mdpi.com/2073-4352/15/3/278ductile ironmicrostructuresiliconmolybdenumcobaltRockwell C hardness
spellingShingle Eduardo Colin-García
Alejandro Cruz-Ramírez
Marisa Moreno-Ríos
Ricardo Gerardo Sánchez-Alvarado
José Antonio Romero-Serrano
Juan Cancio Jiménez-Lugos
Armando Irvin Martínez-Pérez
Edgar Ernesto Vera-Cárdenas
Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt
Crystals
ductile iron
microstructure
silicon
molybdenum
cobalt
Rockwell C hardness
title Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt
title_full Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt
title_fullStr Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt
title_full_unstemmed Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt
title_short Microstructure and Reciprocating Sliding Wear Resistance Evaluation on SiMo Ductile Iron Low Alloyed with Cobalt
title_sort microstructure and reciprocating sliding wear resistance evaluation on simo ductile iron low alloyed with cobalt
topic ductile iron
microstructure
silicon
molybdenum
cobalt
Rockwell C hardness
url https://www.mdpi.com/2073-4352/15/3/278
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