Metallorganische Azidokomplexe von Elementen der III. und IV. Hauptgruppe
The complexes Me3SiN3AlMe3 and Me3GeN3GaMe3 are formed at low temperatures by reaction of the corresponding trimethyl-elementazides with the trimethylmetals of Al and Ga. At elevated temperatures the complexes decompose, whereby the species [Me2MN3]3 were obtained. [Me2InN3]3 was also prepared by a...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1974-07-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9151 |
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| Summary: | The complexes Me3SiN3AlMe3 and Me3GeN3GaMe3 are formed at low temperatures by reaction of the corresponding trimethyl-elementazides with the trimethylmetals of Al and Ga. At elevated temperatures the complexes decompose, whereby the species [Me2MN3]3 were obtained. [Me2InN3]3 was also prepared by an analogous route. The vibrational spectra of the trimeric azides with M = Ga, In were recorded and assigned.
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| ISSN: | 0009-4293 2673-2424 |