Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes
Post-deposition calcination in the air of hybrid inorganic/organic layers is considered to remove the organic constituents and completely create a full inorganic membrane. This study aims to investigate to what extent such a removal occurs and the effect of remaining organic constituents on the phys...
Saved in:
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-06-01
|
| Series: | Open Ceramics |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666539525000628 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849334831056420864 |
|---|---|
| author | M.P. Nijboer H. Sondhi E. Makhoul M. Bechelany S. Gabrielli F. Roozeboom A. Nijmeijer A.Y. Kovalgin M.W.J. Luiten-Olieman |
| author_facet | M.P. Nijboer H. Sondhi E. Makhoul M. Bechelany S. Gabrielli F. Roozeboom A. Nijmeijer A.Y. Kovalgin M.W.J. Luiten-Olieman |
| author_sort | M.P. Nijboer |
| collection | DOAJ |
| description | Post-deposition calcination in the air of hybrid inorganic/organic layers is considered to remove the organic constituents and completely create a full inorganic membrane. This study aims to investigate to what extent such a removal occurs and the effect of remaining organic constituents on the physicochemical properties of the membrane layer.Three hybrid layers were deposited using trimethylaluminum, two aliphatic- (ethylene glycol and 1,6-hexanediol) and one aromatic alcohol (hydroquinone). The effects of the different calcination treatments on the physicochemical properties were investigated. Differential thermogravimetric analysis established that the maximum mass loss rate temperatures for the hybrid layers grown from the aliphatic alcohols are lower than those from the aromatic co-reactant. After 250 °C, water contact angles (WCAs) were between 46° - 92° and IR spectroscopy and XPS showed the presence of carbon. Calcination at 350 °C reduced the WCA to 0° - 25° and decreased carbon content. |
| format | Article |
| id | doaj-art-1679ace03c804589a3c758ea9e1ff696 |
| institution | Kabale University |
| issn | 2666-5395 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Open Ceramics |
| spelling | doaj-art-1679ace03c804589a3c758ea9e1ff6962025-08-20T03:45:28ZengElsevierOpen Ceramics2666-53952025-06-012210079510.1016/j.oceram.2025.100795Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranesM.P. Nijboer0H. Sondhi1E. Makhoul2M. Bechelany3S. Gabrielli4F. Roozeboom5A. Nijmeijer6A.Y. Kovalgin7M.W.J. Luiten-Olieman8Inorganic Membranes, University of Twente, PO Box 217, 7500 AE Enschede, the NetherlandsInorganic Membranes, University of Twente, PO Box 217, 7500 AE Enschede, the NetherlandsInstitut Européen des Membranes, IEM, UMR-5635, Université Montpellier, ENSCM, CNRS, Place Eugène Bataillon, 34095 Montpellier, FranceInstitut Européen des Membranes, IEM, UMR-5635, Université Montpellier, ENSCM, CNRS, Place Eugène Bataillon, 34095 Montpellier, France; Functional Materials Group, Gulf University for Science and Technology (GUST), Mubarak Al-Abdullah 32093, KuwaitSchool of Science & Technology - Chemistry Division, ChIP Building, Via Madonna delle Carceri, 62032, Camerino (MC) ItalyInorganic Membranes, University of Twente, PO Box 217, 7500 AE Enschede, the NetherlandsInorganic Membranes, University of Twente, PO Box 217, 7500 AE Enschede, the NetherlandsIntegrated Devices and Systems, University of Twente, PO Box 217, 7500 AE Enschede, the NetherlandsInorganic Membranes, University of Twente, PO Box 217, 7500 AE Enschede, the Netherlands; Corresponding author.Post-deposition calcination in the air of hybrid inorganic/organic layers is considered to remove the organic constituents and completely create a full inorganic membrane. This study aims to investigate to what extent such a removal occurs and the effect of remaining organic constituents on the physicochemical properties of the membrane layer.Three hybrid layers were deposited using trimethylaluminum, two aliphatic- (ethylene glycol and 1,6-hexanediol) and one aromatic alcohol (hydroquinone). The effects of the different calcination treatments on the physicochemical properties were investigated. Differential thermogravimetric analysis established that the maximum mass loss rate temperatures for the hybrid layers grown from the aliphatic alcohols are lower than those from the aromatic co-reactant. After 250 °C, water contact angles (WCAs) were between 46° - 92° and IR spectroscopy and XPS showed the presence of carbon. Calcination at 350 °C reduced the WCA to 0° - 25° and decreased carbon content.http://www.sciencedirect.com/science/article/pii/S2666539525000628Hybrid atomic/molecular layer depositionCeramic nanofiltration (nf) membranesCalcination temperatureStructural and physico-chemical propertiesTunable hydrophobicity |
| spellingShingle | M.P. Nijboer H. Sondhi E. Makhoul M. Bechelany S. Gabrielli F. Roozeboom A. Nijmeijer A.Y. Kovalgin M.W.J. Luiten-Olieman Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes Open Ceramics Hybrid atomic/molecular layer deposition Ceramic nanofiltration (nf) membranes Calcination temperature Structural and physico-chemical properties Tunable hydrophobicity |
| title | Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes |
| title_full | Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes |
| title_fullStr | Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes |
| title_full_unstemmed | Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes |
| title_short | Influence of calcination temperature on the physicochemical properties of atomic/molecular layer deposited hybrid inorganic/organic ceramic nanofiltration membranes |
| title_sort | influence of calcination temperature on the physicochemical properties of atomic molecular layer deposited hybrid inorganic organic ceramic nanofiltration membranes |
| topic | Hybrid atomic/molecular layer deposition Ceramic nanofiltration (nf) membranes Calcination temperature Structural and physico-chemical properties Tunable hydrophobicity |
| url | http://www.sciencedirect.com/science/article/pii/S2666539525000628 |
| work_keys_str_mv | AT mpnijboer influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT hsondhi influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT emakhoul influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT mbechelany influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT sgabrielli influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT froozeboom influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT anijmeijer influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT aykovalgin influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes AT mwjluitenolieman influenceofcalcinationtemperatureonthephysicochemicalpropertiesofatomicmolecularlayerdepositedhybridinorganicorganicceramicnanofiltrationmembranes |