Synthesis of new derivatives of protoporphyrin IX

In the course of searching new highly active substances which are prospective for treating tumors and some other types of widespread diseases the synthesis of protoporphyrin IX bearing the benzodiazepine residue, was performed. It was found that the use of porphyrins containing acetylacetonate resid...

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Main Authors: V. Yu. Pavlov, А. Е. Stepanov, V. I. Shvets
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2010-10-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/935
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author V. Yu. Pavlov
А. Е. Stepanov
V. I. Shvets
author_facet V. Yu. Pavlov
А. Е. Stepanov
V. I. Shvets
author_sort V. Yu. Pavlov
collection DOAJ
description In the course of searching new highly active substances which are prospective for treating tumors and some other types of widespread diseases the synthesis of protoporphyrin IX bearing the benzodiazepine residue, was performed. It was found that the use of porphyrins containing acetylacetonate residues in the heterocyclic synthesis leads to ketone splitting of the acetylacetonate moiety under the mild conditions of regioselective synthesis of benzodiazepine in addition to the formation of porphyrin-benzodiazepines.
format Article
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institution DOAJ
issn 2410-6593
2686-7575
language Russian
publishDate 2010-10-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-163c2be510e54150b8ef38ce10a2d9802025-08-20T03:23:19ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752010-10-01558287929Synthesis of new derivatives of protoporphyrin IXV. Yu. Pavlov0А. Е. Stepanov1V. I. Shvets2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571In the course of searching new highly active substances which are prospective for treating tumors and some other types of widespread diseases the synthesis of protoporphyrin IX bearing the benzodiazepine residue, was performed. It was found that the use of porphyrins containing acetylacetonate residues in the heterocyclic synthesis leads to ketone splitting of the acetylacetonate moiety under the mild conditions of regioselective synthesis of benzodiazepine in addition to the formation of porphyrin-benzodiazepines.https://www.finechem-mirea.ru/jour/article/view/935protoporphyrin ixphotodynamic therapyphotosensitizer
spellingShingle V. Yu. Pavlov
А. Е. Stepanov
V. I. Shvets
Synthesis of new derivatives of protoporphyrin IX
Тонкие химические технологии
protoporphyrin ix
photodynamic therapy
photosensitizer
title Synthesis of new derivatives of protoporphyrin IX
title_full Synthesis of new derivatives of protoporphyrin IX
title_fullStr Synthesis of new derivatives of protoporphyrin IX
title_full_unstemmed Synthesis of new derivatives of protoporphyrin IX
title_short Synthesis of new derivatives of protoporphyrin IX
title_sort synthesis of new derivatives of protoporphyrin ix
topic protoporphyrin ix
photodynamic therapy
photosensitizer
url https://www.finechem-mirea.ru/jour/article/view/935
work_keys_str_mv AT vyupavlov synthesisofnewderivativesofprotoporphyrinix
AT aestepanov synthesisofnewderivativesofprotoporphyrinix
AT vishvets synthesisofnewderivativesofprotoporphyrinix