CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite

The role of the CTAB concentration (0.0 M, NS; 5x10-4 M, ½CMC; 2x10-3 M, 2CMC) and the residence time on the composition, morphology and magnetic properties for the nickel nanoferrite formation by hydrolytic stripping (33% v/v naphthenic/kerosene) at 200°C were studied. X-ray, SEM/EDS, FTIR, VSM, an...

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Main Authors: Jiménez Muñiz Adrián, Verdejo Palacios Alejandra, Palacios Beas Elia Guadalupe
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2025-05-01
Series:Materials Research
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Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392025000100243&lng=en&tlng=en
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author Jiménez Muñiz Adrián
Verdejo Palacios Alejandra
Palacios Beas Elia Guadalupe
author_facet Jiménez Muñiz Adrián
Verdejo Palacios Alejandra
Palacios Beas Elia Guadalupe
author_sort Jiménez Muñiz Adrián
collection DOAJ
description The role of the CTAB concentration (0.0 M, NS; 5x10-4 M, ½CMC; 2x10-3 M, 2CMC) and the residence time on the composition, morphology and magnetic properties for the nickel nanoferrite formation by hydrolytic stripping (33% v/v naphthenic/kerosene) at 200°C were studied. X-ray, SEM/EDS, FTIR, VSM, and ICP/OES were used to characterise solids and solutions. Regardless of the experimental conditions, all samples present nickel spinel ferrite as the only phase, with similar Fe/Ni molar ratio. However, those precipitates in the presence of CTAB show more homogeneous morphology than in its absence. CTAB at high concentration (2CMC) increases the discharge rate, reaching 100% at 40 min; 14.79 nm average size nanoparticles were obtained, with better magnetic properties (Ms=53.02 emu/g and Hc=35.59 Oe) than those achieved at low concentration (½CMC) and in the absence of CTAB.
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institution DOAJ
issn 1516-1439
language English
publishDate 2025-05-01
publisher Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
record_format Article
series Materials Research
spelling doaj-art-158f2040d8df4f6c977824c42f8dfea32025-08-20T03:07:26ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392025-05-012810.1590/1980-5373-mr-2025-0169CTAB Influence on the Hydrolytic Stripping of Nickel FerriteJiménez Muñiz Adriánhttps://orcid.org/0009-0006-4904-6386Verdejo Palacios AlejandraPalacios Beas Elia GuadalupeThe role of the CTAB concentration (0.0 M, NS; 5x10-4 M, ½CMC; 2x10-3 M, 2CMC) and the residence time on the composition, morphology and magnetic properties for the nickel nanoferrite formation by hydrolytic stripping (33% v/v naphthenic/kerosene) at 200°C were studied. X-ray, SEM/EDS, FTIR, VSM, and ICP/OES were used to characterise solids and solutions. Regardless of the experimental conditions, all samples present nickel spinel ferrite as the only phase, with similar Fe/Ni molar ratio. However, those precipitates in the presence of CTAB show more homogeneous morphology than in its absence. CTAB at high concentration (2CMC) increases the discharge rate, reaching 100% at 40 min; 14.79 nm average size nanoparticles were obtained, with better magnetic properties (Ms=53.02 emu/g and Hc=35.59 Oe) than those achieved at low concentration (½CMC) and in the absence of CTAB.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392025000100243&lng=en&tlng=enNickel nanoferritesCTABHydrolytic strippingSurfactantMagnetization
spellingShingle Jiménez Muñiz Adrián
Verdejo Palacios Alejandra
Palacios Beas Elia Guadalupe
CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite
Materials Research
Nickel nanoferrites
CTAB
Hydrolytic stripping
Surfactant
Magnetization
title CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite
title_full CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite
title_fullStr CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite
title_full_unstemmed CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite
title_short CTAB Influence on the Hydrolytic Stripping of Nickel Ferrite
title_sort ctab influence on the hydrolytic stripping of nickel ferrite
topic Nickel nanoferrites
CTAB
Hydrolytic stripping
Surfactant
Magnetization
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392025000100243&lng=en&tlng=en
work_keys_str_mv AT jimenezmunizadrian ctabinfluenceonthehydrolyticstrippingofnickelferrite
AT verdejopalaciosalejandra ctabinfluenceonthehydrolyticstrippingofnickelferrite
AT palaciosbeaseliaguadalupe ctabinfluenceonthehydrolyticstrippingofnickelferrite