Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells

This study presents a microbial sensing device that employs a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) matrix to immobilize viable and metabolically <i>Escherichia coli</i> cells. This device enables the monitoring of microorganism metabolic activity in response...

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Main Authors: N. Vigués, C. Cantallops-Vilà, J. Mas
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Chemosensors
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Online Access:https://www.mdpi.com/2227-9040/13/6/211
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author N. Vigués
C. Cantallops-Vilà
J. Mas
author_facet N. Vigués
C. Cantallops-Vilà
J. Mas
author_sort N. Vigués
collection DOAJ
description This study presents a microbial sensing device that employs a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) matrix to immobilize viable and metabolically <i>Escherichia coli</i> cells. This device enables the monitoring of microorganism metabolic activity in response to external stimuli such as variations in carbon sources or exposure to inhibitory or toxic compounds. PEDOT:PSS, a conductive and chemically stable polymer, was electrodeposited onto screen-printed electrodes, successfully entrapping approximately 1.26 × 10<sup>7</sup> cells per electrode. The confocal microscopy of Live/Dead-stained samples confirmed a uniform cell distribution and an average viability of ~78%. Ferricyanide respirometry validated the metabolic activity of the immobilized cells. The biosensor’s performance was evaluated using 3,5-dichlorophenol (3,5-DCP) as a reference toxicant. The observed inhibition of microbial activity correlated with 3,5-DCP concentration, yielding a half-maximal effective concentration (EC<sub>50</sub>) of 9 ppm, consistent with the literature values.
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spelling doaj-art-1545d7efd45f49dd9a01c32da247b3262025-08-20T02:24:34ZengMDPI AGChemosensors2227-90402025-06-0113621110.3390/chemosensors13060211Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized CellsN. Vigués0C. Cantallops-Vilà1J. Mas2Department of Genetics and Microbiology, Universitat Autònoma de Barcelona, 08193 Bellaterra, SpainDepartment of Genetics and Microbiology, Universitat Autònoma de Barcelona, 08193 Bellaterra, SpainDepartment of Genetics and Microbiology, Universitat Autònoma de Barcelona, 08193 Bellaterra, SpainThis study presents a microbial sensing device that employs a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) matrix to immobilize viable and metabolically <i>Escherichia coli</i> cells. This device enables the monitoring of microorganism metabolic activity in response to external stimuli such as variations in carbon sources or exposure to inhibitory or toxic compounds. PEDOT:PSS, a conductive and chemically stable polymer, was electrodeposited onto screen-printed electrodes, successfully entrapping approximately 1.26 × 10<sup>7</sup> cells per electrode. The confocal microscopy of Live/Dead-stained samples confirmed a uniform cell distribution and an average viability of ~78%. Ferricyanide respirometry validated the metabolic activity of the immobilized cells. The biosensor’s performance was evaluated using 3,5-dichlorophenol (3,5-DCP) as a reference toxicant. The observed inhibition of microbial activity correlated with 3,5-DCP concentration, yielding a half-maximal effective concentration (EC<sub>50</sub>) of 9 ppm, consistent with the literature values.https://www.mdpi.com/2227-9040/13/6/211PEDOT:PSScell immobilization<i>Escherichia coli</i>metabolic activitymicrobial activityferricyanide respirometry
spellingShingle N. Vigués
C. Cantallops-Vilà
J. Mas
Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells
Chemosensors
PEDOT:PSS
cell immobilization
<i>Escherichia coli</i>
metabolic activity
microbial activity
ferricyanide respirometry
title Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells
title_full Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells
title_fullStr Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells
title_full_unstemmed Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells
title_short Electrochemical Assessment of Microbial Activity Using PEDOT:PSS-Immobilized Cells
title_sort electrochemical assessment of microbial activity using pedot pss immobilized cells
topic PEDOT:PSS
cell immobilization
<i>Escherichia coli</i>
metabolic activity
microbial activity
ferricyanide respirometry
url https://www.mdpi.com/2227-9040/13/6/211
work_keys_str_mv AT nvigues electrochemicalassessmentofmicrobialactivityusingpedotpssimmobilizedcells
AT ccantallopsvila electrochemicalassessmentofmicrobialactivityusingpedotpssimmobilizedcells
AT jmas electrochemicalassessmentofmicrobialactivityusingpedotpssimmobilizedcells