Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential

In the Amazon region, the choice and study of caranan fiber (Mauritiella armata) is justified by its potential being scarcely investigated and explored. This work aims to characterize the tensile mechanical properties, to evaluate their chemical compositions via Fourier Transform Infrared Spectrosco...

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Main Authors: Luciano Monteiro Almeida, Alisson Clay Rios da Silva, Felipe Perissé Duarte Lopes, Noan Tonini Simonassi, Sérgio Neves Monteiro, Verônica Scarpini Candido
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424030369
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author Luciano Monteiro Almeida
Alisson Clay Rios da Silva
Felipe Perissé Duarte Lopes
Noan Tonini Simonassi
Sérgio Neves Monteiro
Verônica Scarpini Candido
author_facet Luciano Monteiro Almeida
Alisson Clay Rios da Silva
Felipe Perissé Duarte Lopes
Noan Tonini Simonassi
Sérgio Neves Monteiro
Verônica Scarpini Candido
author_sort Luciano Monteiro Almeida
collection DOAJ
description In the Amazon region, the choice and study of caranan fiber (Mauritiella armata) is justified by its potential being scarcely investigated and explored. This work aims to characterize the tensile mechanical properties, to evaluate their chemical compositions via Fourier Transform Infrared Spectroscopy (FTIR) and Raman Spectroscopy, as well as the morphologies via Scanning Electron Microscopy (SEM) of the composites with the incorporation of 0, 10, 20, and 30 vol% of non-functionalized and 0.5%p/v functionalized caranan fibers. For tensile properties, the composites showed decreases of 9.68% and 10.62% for the composites with 10 and 30 vol% of functionalized fibers, respectively, compared to the pure matrix, and an increase of 7.41% for the composite with 20 vol% of functionalized fibers. The flexural properties showed an increase with the incorporation of 10 vol% of functionalized caranan fibers compared to the pure polyester matrix. The impact test provided an increase of 169.88% for the composites with 30 vol% by volume of natural fibers and 152% for those with 30 vol% of fibers functionalized with graphene oxide compared to the pure polyester matrix. FTIR showed the presence of specific functional groups for the pure polyester matrix, graphene oxide, and with the addition of functionalized fibers for the composites. For the evaluation of Raman spectroscopy after the functionalization process, the presence of the D, G, and 2D bands was evident. The SEM indicated the main failure mechanisms that led the composite to fracture: porosities, river marks, fiber pull-out.
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spelling doaj-art-14de968de241491ab3dd87f2745827192025-01-19T06:25:54ZengElsevierJournal of Materials Research and Technology2238-78542025-01-013422322252Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potentialLuciano Monteiro Almeida0Alisson Clay Rios da Silva1Felipe Perissé Duarte Lopes2Noan Tonini Simonassi3Sérgio Neves Monteiro4Verônica Scarpini Candido5Engineering of Natural Resources of the Amazon Program, Federal University of Para, Belem, PA, 67030-007, BrazilMaterials Science and Engineering Program, Federal University of Pará, Ananindeua, PA, 67130-660, BrazilAdvanced Materials Laboratory, State University of Northern Rio de Janeiro. Av. Alberto Lamego, 2000, Pq. California, Campos dos Goytacazes/ Rio de Janeiro, 28013-602, BrazilAdvanced Materials Laboratory, State University of Northern Rio de Janeiro. Av. Alberto Lamego, 2000, Pq. California, Campos dos Goytacazes/ Rio de Janeiro, 28013-602, BrazilDepartment of Materials Science, Military Institute of Engineering, Rio de Janeiro, RJ, 22290-270, BrazilMaterials Science and Engineering Program, Federal University of Pará, Ananindeua, PA, 67130-660, Brazil; Corresponding author.In the Amazon region, the choice and study of caranan fiber (Mauritiella armata) is justified by its potential being scarcely investigated and explored. This work aims to characterize the tensile mechanical properties, to evaluate their chemical compositions via Fourier Transform Infrared Spectroscopy (FTIR) and Raman Spectroscopy, as well as the morphologies via Scanning Electron Microscopy (SEM) of the composites with the incorporation of 0, 10, 20, and 30 vol% of non-functionalized and 0.5%p/v functionalized caranan fibers. For tensile properties, the composites showed decreases of 9.68% and 10.62% for the composites with 10 and 30 vol% of functionalized fibers, respectively, compared to the pure matrix, and an increase of 7.41% for the composite with 20 vol% of functionalized fibers. The flexural properties showed an increase with the incorporation of 10 vol% of functionalized caranan fibers compared to the pure polyester matrix. The impact test provided an increase of 169.88% for the composites with 30 vol% by volume of natural fibers and 152% for those with 30 vol% of fibers functionalized with graphene oxide compared to the pure polyester matrix. FTIR showed the presence of specific functional groups for the pure polyester matrix, graphene oxide, and with the addition of functionalized fibers for the composites. For the evaluation of Raman spectroscopy after the functionalization process, the presence of the D, G, and 2D bands was evident. The SEM indicated the main failure mechanisms that led the composite to fracture: porosities, river marks, fiber pull-out.http://www.sciencedirect.com/science/article/pii/S2238785424030369CarananGraphene oxideCompositesSpectroscopyMicroscopy
spellingShingle Luciano Monteiro Almeida
Alisson Clay Rios da Silva
Felipe Perissé Duarte Lopes
Noan Tonini Simonassi
Sérgio Neves Monteiro
Verônica Scarpini Candido
Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
Journal of Materials Research and Technology
Caranan
Graphene oxide
Composites
Spectroscopy
Microscopy
title Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
title_full Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
title_fullStr Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
title_full_unstemmed Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
title_short Caranan fibers (Mauritiella armata) and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
title_sort caranan fibers mauritiella armata and new reinforcements of polyester composites with natural fibers functionalized with graphene oxide and their application potential
topic Caranan
Graphene oxide
Composites
Spectroscopy
Microscopy
url http://www.sciencedirect.com/science/article/pii/S2238785424030369
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