SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM

Distillers grains are a huge secondary raw material resource, prospective for different fields, including pharmaceutical use, because of a rich content of biologically active compounds. The purpose of this paper was to estimate possibilities of the pharmaceutical use of distillers grains as the addi...

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Main Authors: N. S. Kaisheva, A. S. Kaishev
Format: Article
Language:Russian
Published: Volgograd State Medical University, Pyatigorsk Medical and Pharmaceutical Institute 2016-03-01
Series:Фармация и фармакология (Пятигорск)
Subjects:
Online Access:https://www.pharmpharm.ru/jour/article/view/190
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author N. S. Kaisheva
A. S. Kaishev
author_facet N. S. Kaisheva
A. S. Kaishev
author_sort N. S. Kaisheva
collection DOAJ
description Distillers grains are a huge secondary raw material resource, prospective for different fields, including pharmaceutical use, because of a rich content of biologically active compounds. The purpose of this paper was to estimate possibilities of the pharmaceutical use of distillers grains as the additive agent by means of surface-active properties of distillers grains study as well as pectins, isolated from them. We have established the surface-active properties of the liquid phase of the distillers wheat grains by means of higher pressure of air bubbles with the use of Rehbinder’s apparatus. It contained 6.67 mol/m3 pectins, and pectins isolated from a solid phase of the same distillers grains: surface activity 11.67 and 7.54, saturated surface excess amounted to 1.28×10-5 and 6.25×10-5 mol/m2, critical concentration of micelle formation amounted to 1.32 mol/m3 and 1.48 mol/m3 respectively. Surface-active characteristics of distillers grains and isolated pectins are comparable with well-known natural polysaccharides (sodium alginate, polygalacturonic acid, beet bin pectin), which are used as additive agents in technology of medicinal plants. We have determined the sizes of pectins molecules from distillers grains in the unsaturated adsorption layers, which differed from the well-known polysaccharides by lesser square (2.658 Å2), radius (0.920 Å), diameter of cross-section (1.840 Å) and the volume (2727 Å3) at the bigger mass per surface unit (1.031×10-4 кг) and a length (1026 Å). The data obtained by the sizes of pectin molecules are the favorable factor, which conduced their high biological availability.
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spelling doaj-art-149514b936e04579b19ddaa139aba4a62025-08-20T03:01:04ZrusVolgograd State Medical University, Pyatigorsk Medical and Pharmaceutical InstituteФармация и фармакология (Пятигорск)2307-92662413-22412016-03-0141(14)728410.19163/2307-9266-2016-4-1(14)-72-84189SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEMN. S. Kaisheva0A. S. Kaishev1Pyatigorsk Medical and Pharmaceutical Institute – branch of Volgograd State Medical University of the Ministry of Health of Russia, PyatigorskInterregional department of Russian Alcohol Control in the Northern Caucasus Federal DistrictDistillers grains are a huge secondary raw material resource, prospective for different fields, including pharmaceutical use, because of a rich content of biologically active compounds. The purpose of this paper was to estimate possibilities of the pharmaceutical use of distillers grains as the additive agent by means of surface-active properties of distillers grains study as well as pectins, isolated from them. We have established the surface-active properties of the liquid phase of the distillers wheat grains by means of higher pressure of air bubbles with the use of Rehbinder’s apparatus. It contained 6.67 mol/m3 pectins, and pectins isolated from a solid phase of the same distillers grains: surface activity 11.67 and 7.54, saturated surface excess amounted to 1.28×10-5 and 6.25×10-5 mol/m2, critical concentration of micelle formation amounted to 1.32 mol/m3 and 1.48 mol/m3 respectively. Surface-active characteristics of distillers grains and isolated pectins are comparable with well-known natural polysaccharides (sodium alginate, polygalacturonic acid, beet bin pectin), which are used as additive agents in technology of medicinal plants. We have determined the sizes of pectins molecules from distillers grains in the unsaturated adsorption layers, which differed from the well-known polysaccharides by lesser square (2.658 Å2), radius (0.920 Å), diameter of cross-section (1.840 Å) and the volume (2727 Å3) at the bigger mass per surface unit (1.031×10-4 кг) and a length (1026 Å). The data obtained by the sizes of pectin molecules are the favorable factor, which conduced their high biological availability.https://www.pharmpharm.ru/jour/article/view/190distillers grainspectinssurface- active propertiessuperficial tensionsuperficial activitysuperficial excesscritical concentrationmicelle formationsadsorption layer.
spellingShingle N. S. Kaisheva
A. S. Kaishev
SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM
Фармация и фармакология (Пятигорск)
distillers grains
pectins
surface- active properties
superficial tension
superficial activity
superficial excess
critical concentration
micelle formations
adsorption layer.
title SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM
title_full SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM
title_fullStr SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM
title_full_unstemmed SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM
title_short SURFACE-ACTIVE PROPERTIES OF THE DISTILLERS GRAINS AND THE PECTINS ISOLATED FROM THEM
title_sort surface active properties of the distillers grains and the pectins isolated from them
topic distillers grains
pectins
surface- active properties
superficial tension
superficial activity
superficial excess
critical concentration
micelle formations
adsorption layer.
url https://www.pharmpharm.ru/jour/article/view/190
work_keys_str_mv AT nskaisheva surfaceactivepropertiesofthedistillersgrainsandthepectinsisolatedfromthem
AT askaishev surfaceactivepropertiesofthedistillersgrainsandthepectinsisolatedfromthem