Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal

In order to analyze the influence of supercritical CO2 on pore structure and desorption characteristics of tectonic coal, a high-temperature and high-pressure geological environment simulation system was used to treat primary coal and tectonic coal with supercritical CO2, and then mercury injection...

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Main Authors: Fanfan NIU, Erlei SU, Jiaqi WEI, Xinyu ZHU
Format: Article
Language:zho
Published: Editorial Office of Safety in Coal Mines 2025-06-01
Series:Meikuang Anquan
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Online Access:https://www.mkaqzz.com/cn/article/doi/10.13347/j.cnki.mkaq.20240950
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author Fanfan NIU
Erlei SU
Jiaqi WEI
Xinyu ZHU
author_facet Fanfan NIU
Erlei SU
Jiaqi WEI
Xinyu ZHU
author_sort Fanfan NIU
collection DOAJ
description In order to analyze the influence of supercritical CO2 on pore structure and desorption characteristics of tectonic coal, a high-temperature and high-pressure geological environment simulation system was used to treat primary coal and tectonic coal with supercritical CO2, and then mercury injection method and coal sample desorption experimental system were used to quantitatively characterize the pore structure and desorption characteristics of coal. The results show that the total pore volume of coal samples increases after supercritical CO2 treatment, and the pore expansion effect of supercritical CO2 on tectonic coal is more obvious. Due to the extraction and dissolution effect of supercritical CO2, the pore size of structural coal increases to a certain extent, and the changes of small hole and large hole are the most obvious. The increment of hysteresis loop of treated tectonic coal is significantly higher than that of primary coal, indicating that the pore network of treated structural coal is more developed and the connectivity is better. At equilibrium pressures of 0.74 MPa and 3.00 MPa, the increase in the desorption capacity of tectonic coal after supercritical CO2 treatment is significantly higher than that of primary coal, which is caused by the increase in the total pore volume of tectonic coal after supercritical CO2 treatment.
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issn 1003-496X
language zho
publishDate 2025-06-01
publisher Editorial Office of Safety in Coal Mines
record_format Article
series Meikuang Anquan
spelling doaj-art-142337120faa4b689c6621fbf413bfc32025-08-20T03:21:22ZzhoEditorial Office of Safety in Coal MinesMeikuang Anquan1003-496X2025-06-01566273210.13347/j.cnki.mkaq.20240950lyMKAQ20240950Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coalFanfan NIU0Erlei SU1Jiaqi WEI2Xinyu ZHU3School of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, ChinaSchool of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, ChinaSchool of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, ChinaSchool of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, ChinaIn order to analyze the influence of supercritical CO2 on pore structure and desorption characteristics of tectonic coal, a high-temperature and high-pressure geological environment simulation system was used to treat primary coal and tectonic coal with supercritical CO2, and then mercury injection method and coal sample desorption experimental system were used to quantitatively characterize the pore structure and desorption characteristics of coal. The results show that the total pore volume of coal samples increases after supercritical CO2 treatment, and the pore expansion effect of supercritical CO2 on tectonic coal is more obvious. Due to the extraction and dissolution effect of supercritical CO2, the pore size of structural coal increases to a certain extent, and the changes of small hole and large hole are the most obvious. The increment of hysteresis loop of treated tectonic coal is significantly higher than that of primary coal, indicating that the pore network of treated structural coal is more developed and the connectivity is better. At equilibrium pressures of 0.74 MPa and 3.00 MPa, the increase in the desorption capacity of tectonic coal after supercritical CO2 treatment is significantly higher than that of primary coal, which is caused by the increase in the total pore volume of tectonic coal after supercritical CO2 treatment.https://www.mkaqzz.com/cn/article/doi/10.13347/j.cnki.mkaq.20240950supercritical co2carbon sequestrationpore structuredesorption characteristicstectonic coalcoalbed methane recovery
spellingShingle Fanfan NIU
Erlei SU
Jiaqi WEI
Xinyu ZHU
Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal
Meikuang Anquan
supercritical co2
carbon sequestration
pore structure
desorption characteristics
tectonic coal
coalbed methane recovery
title Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal
title_full Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal
title_fullStr Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal
title_full_unstemmed Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal
title_short Effect of supercritical CO2 on pore structure and desorption characteristics of tectonic coal
title_sort effect of supercritical co2 on pore structure and desorption characteristics of tectonic coal
topic supercritical co2
carbon sequestration
pore structure
desorption characteristics
tectonic coal
coalbed methane recovery
url https://www.mkaqzz.com/cn/article/doi/10.13347/j.cnki.mkaq.20240950
work_keys_str_mv AT fanfanniu effectofsupercriticalco2onporestructureanddesorptioncharacteristicsoftectoniccoal
AT erleisu effectofsupercriticalco2onporestructureanddesorptioncharacteristicsoftectoniccoal
AT jiaqiwei effectofsupercriticalco2onporestructureanddesorptioncharacteristicsoftectoniccoal
AT xinyuzhu effectofsupercriticalco2onporestructureanddesorptioncharacteristicsoftectoniccoal