Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance

A total of 31 compounds were isolated from the ethyl acetate and <i>n</i>-butanol fractions of <i>Anchusa italica</i> Retz., which contained one ursane triterpenoid, 2<i>α</i>,3<i>β</i>,19<i>α</i>-trihydroxy-23-formyl-urs-12-en-28,21<i&g...

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Main Authors: Linchuang Shen, Bingchen Han, Zhiliang Ma, Xianju Huang, Guangzhong Yang, Yanfeng Zeng, Maochuan Liao, Ruixi Gao, Jun Li
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Plants
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Online Access:https://www.mdpi.com/2223-7747/14/9/1385
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author Linchuang Shen
Bingchen Han
Zhiliang Ma
Xianju Huang
Guangzhong Yang
Yanfeng Zeng
Maochuan Liao
Ruixi Gao
Jun Li
author_facet Linchuang Shen
Bingchen Han
Zhiliang Ma
Xianju Huang
Guangzhong Yang
Yanfeng Zeng
Maochuan Liao
Ruixi Gao
Jun Li
author_sort Linchuang Shen
collection DOAJ
description A total of 31 compounds were isolated from the ethyl acetate and <i>n</i>-butanol fractions of <i>Anchusa italica</i> Retz., which contained one ursane triterpenoid, 2<i>α</i>,3<i>β</i>,19<i>α</i>-trihydroxy-23-formyl-urs-12-en-28,21<i>β-</i>olide (<b>1</b>), and five norisoprenoids: (2<i>R</i>,6<i>R</i>,9<i>S</i>)-9-hydroxy-4-megastigmen-3-one-2<i>-O-β-</i>D-glucopyranoside (<b>3</b>); (2<i>R</i>,6<i>S</i>,9<i>S</i>)-9-hydroxy-megastigman-4,7-dien-3-one-2<i>-O-β-</i>D-glucopyranoside (<b>4</b>); (+)-isololiolide <i>β-</i>D-glucopyranoside (<b>5</b>); (2<i>S</i>,8<i>R</i>)-loliolide <i>β-</i>D-glucopyranoside (<b>6a</b>); and (2<i>R</i>,8<i>S</i>)-loliolide <i>β-</i>D-glucopyranoside (<b>6b</b>). It also contained 25 known compounds (<b>2</b> and <b>7–30</b>). The chemical structures of the compounds, inclusive of their absolute configurations, were ascertained using spectroscopic methods such as NMR, HR-MS, and quantum chemical calculations (computational NMR and ECD), in combination with relevant literature data. Moreover, the chemotaxonomic significance of the isolated substances was discussed, with compounds <b>1</b>, <b>2</b>, and <b>7–13</b> potentially broadening the application of triterpenes as taxonomic markers for the classification of the genus <i>Anchusa</i>.
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spelling doaj-art-133d8fccfc144209aa268755f0f04b2b2025-08-20T03:52:57ZengMDPI AGPlants2223-77472025-05-01149138510.3390/plants14091385Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic SignificanceLinchuang Shen0Bingchen Han1Zhiliang Ma2Xianju Huang3Guangzhong Yang4Yanfeng Zeng5Maochuan Liao6Ruixi Gao7Jun Li8School of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaCollege of Life Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaSchool of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, ChinaA total of 31 compounds were isolated from the ethyl acetate and <i>n</i>-butanol fractions of <i>Anchusa italica</i> Retz., which contained one ursane triterpenoid, 2<i>α</i>,3<i>β</i>,19<i>α</i>-trihydroxy-23-formyl-urs-12-en-28,21<i>β-</i>olide (<b>1</b>), and five norisoprenoids: (2<i>R</i>,6<i>R</i>,9<i>S</i>)-9-hydroxy-4-megastigmen-3-one-2<i>-O-β-</i>D-glucopyranoside (<b>3</b>); (2<i>R</i>,6<i>S</i>,9<i>S</i>)-9-hydroxy-megastigman-4,7-dien-3-one-2<i>-O-β-</i>D-glucopyranoside (<b>4</b>); (+)-isololiolide <i>β-</i>D-glucopyranoside (<b>5</b>); (2<i>S</i>,8<i>R</i>)-loliolide <i>β-</i>D-glucopyranoside (<b>6a</b>); and (2<i>R</i>,8<i>S</i>)-loliolide <i>β-</i>D-glucopyranoside (<b>6b</b>). It also contained 25 known compounds (<b>2</b> and <b>7–30</b>). The chemical structures of the compounds, inclusive of their absolute configurations, were ascertained using spectroscopic methods such as NMR, HR-MS, and quantum chemical calculations (computational NMR and ECD), in combination with relevant literature data. Moreover, the chemotaxonomic significance of the isolated substances was discussed, with compounds <b>1</b>, <b>2</b>, and <b>7–13</b> potentially broadening the application of triterpenes as taxonomic markers for the classification of the genus <i>Anchusa</i>.https://www.mdpi.com/2223-7747/14/9/1385<i>Anchusa italica</i> Retz.structural elucidationursane triterpenenorisoprenoidchemotaxonomic significance
spellingShingle Linchuang Shen
Bingchen Han
Zhiliang Ma
Xianju Huang
Guangzhong Yang
Yanfeng Zeng
Maochuan Liao
Ruixi Gao
Jun Li
Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance
Plants
<i>Anchusa italica</i> Retz.
structural elucidation
ursane triterpene
norisoprenoid
chemotaxonomic significance
title Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance
title_full Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance
title_fullStr Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance
title_full_unstemmed Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance
title_short Ursane Triterpenes and Norisoprenoids from <i>Anchusa italica</i> Retz. and Their Chemotaxonomic Significance
title_sort ursane triterpenes and norisoprenoids from i anchusa italica i retz and their chemotaxonomic significance
topic <i>Anchusa italica</i> Retz.
structural elucidation
ursane triterpene
norisoprenoid
chemotaxonomic significance
url https://www.mdpi.com/2223-7747/14/9/1385
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